Results 131 to 140 of about 13,257 (251)

Outer‐Sphere Tuning of Synthetic Iron–Sulfur Clusters Within Nanoscale Cage Frameworks

Small, EarlyView.
Noncovalent encapsulation of a synthetic iron–sulfur cluster within hydrophobic, naphthalenediimide (NDI)‐paneled cages is shown to lead to dramatic changes in the electronic structure and covalency of the Fe─S core. ABSTRACT As atomic‐scale archetypes for multi‐electron transfer, iron–sulfur clusters are compelling candidates for the design of redox ...
Rupal Baliyan, Shelby T. Davis, Jan‐Niklas Boyn, Gwendolyn A. Bailey   +3 more
wiley   +1 more source

Redox- and protonation-driven Baird and Clar aromaticity in asymmetric multicyclic octaphyrins. [PDF]

Chem Sci
Ali MA, Kim JH, Kim Y, Nam Y, Oh J, Jang WD, Kim D.   +6 more
europepmc   +1 more source

Photocatalytic Hydrogen Evolution From Self‐Assembled Stacks of Pd–TCPP and Pt–TCPP

Small, EarlyView.
ABSTRACT The present work demonstrates that surfactant‐free precipitation of Pd– and Pt–TCPP in MeOH/H2O yields well‐defined supramolecular architectures (µm‐long nanorods) whose photocatalytic function tracks their metal‐dependent photophysics and stacking.
Jihyeon Kim, Lukas Zdrazil, Xin Zhou, Patrik Schmuki   +3 more
wiley   +1 more source

Tuning Circular Dichroism and Circularly Polarised Luminescence in Single Crystals of a Perylene Diimide Macrocycle. [PDF]

Angew Chem Int Ed Engl
Hartmann D, Penty SE, Krimovs A, Pal R, Gianga TM, Siligardi G, Barendt TA.   +6 more
europepmc   +1 more source

Polysulfide Immobilization and Sulfur Conversion Kinetics Promotion via a Tetrathiafulvalene–Crown Ether COF@Graphene Layer for High‐Rate Lithium–Sulfur Batteries

Small, EarlyView.
A polysulfide‐regulating covalent organic framework (TUS‐44) integrating tetrathiafulvalene and crown‐ether linkers forms an electron‐delocalized, ion‐coordinative network that synergistically mediates Li–S redox chemistry. When interfaced with graphene, the TUS‐44@G layer functions as a catalytic and chemisorptive interface, enabling efficient ...
Kai Sun, Tsukasa Irie, Samim Reza, Kohki Sasaki, Mika Nozaki, Tokuhisa Kawawaki, Yujun Fu, Dequan Liu, Ranjit Thapa, Saikat Das, Deyan He, Yuichi Negishi   +11 more
wiley   +1 more source

Synthesis of bacteriochlorophyll <i>a</i>. [PDF]

Chem Sci
Chung DTM, Nguyen KC, Liu Y, Lindsey JS.
europepmc   +1 more source

White light emitting molecular logic gates

Smart Molecules, EarlyView.
White light emitting smart molecules with Boolean logic computing ability are surveyed. Abstract White light emitting (WLE) materials are of considerable interest with commercial and societal applications in video displays and lighting devices. A characteristic property of WLE materials is the luminescence profile spanning from 380 to 700 nm.
Davide Benedetto Tiz, Massimo Catania, David C. Magri   +2 more
wiley   +1 more source

Simplified synthesis of anti-oxidant small molecule ^OHPyN₃. [PDF]

MethodsX
Mingle D, Kumar N, Green KN.
europepmc   +1 more source

Unraveling the effect of topological structures of B/N‐doped conjugated macrocycles on spectral properties: A computational study

Smart Molecules, EarlyView.
Herein, we constructed a series of fully B‐doped, fully N‐doped and hybrid B/N‐doped conjugated macrocycles considering three key topological factors. At a fixed ring size, the spectra initially redshift then blueshift with varying B/N ratio, while ring size exhibits negligible impact on spectra.
Wen‐Yu Guo, Yi Zeng, Yu‐Meng Xu, Pang‐Kuan Chen, Xiao‐Yan Zheng   +4 more
wiley   +1 more source

A dual-responsive cationic acridinium nanohoop: redox activity and acid/base-controlled reversible guest capture and release. [PDF]

Chem Sci
Ming J, Zhang J, Hu Y, Lan K, Zhang D, Li P, Miao J, Jiang J, Zhang X, Zhong H, Yu P, Cheng C.   +11 more
europepmc   +1 more source