Results 61 to 70 of about 13,279 (251)

A Multi‐Stimuli Transformational Network of Benzil‐Based Pd(II) Assemblies

Angewandte Chemie, EarlyView.
Incorporation of a flexible and chemically reactive benzil backbone into the ligand structure allows it to access multiple conformations, enabling the formation of diverse homo‐ and heteroleptic Pd(II) assemblies with different nuclearities and topologies.
Zhiwei Zeng, A. Priscila Gia, Alexander S. Mikherdov, Mert Acar, Björn Schmidt, Guido H. Clever   +5 more
wiley   +2 more sources

Mechanically Interlocked Indigo Photoswitches

Angewandte Chemie, Volume 138, Issue 34, 17 August 2026.
By incorporating indigo photoswitches into the axle of a rotaxane, which features a hydrogen bonding macrocycle, we demonstrate improvement in activation wavelength, photostationary states and thermal reversion, an effect that is governed by topologically constrained supramolecular interactions.
Alexander M. Wilmshurst, Taegeun Jo, Rebecca L. Kerridge, Akanksha Ashok Sangolkar, Zhihao Ling, Alex Buchanan, Neil Wells, Yael Ben‐Tal, Stefano Crespi, George T. Williams   +9 more
wiley   +2 more sources

Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity

Angewandte Chemie, EarlyView.
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley   +2 more sources

Physiological and Biomechanical Evaluation of a Training Macrocycle in Children Swimmers

Sports, 2019
Physiological responses related to 400-m front crawl performance were examined in a 11-week training macrocycle in children 11.6 ± 1.2 years old. Fourteen girls and twenty-nine boys completed a maximum intensity 400-m test, at the beginning (&Tau ...
Sara Ferreira, Diogo Carvalho, Ana Sofia Monteiro, J. Arturo Abraldes, J. Paulo Vilas-Boas, Argyris Toubekis, Ricardo Fernandes   +6 more
doaj   +1 more source

Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture

Angewandte Chemie, EarlyView.
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka, Takumi Kuroda, Kota Masuda, Toshiki Nishitani, Masaki Enokido, Makoto Tsurui, Yuichi Kitagawa, Yasuchika Hasegawa, Keiichi Noguchi, Koji Nakano, Yoshimitsu Sagara   +10 more
wiley   +2 more sources

Cyclo[Tri(thiomethyl-1,2-phenylmethylene)]

Molbank
During the purification of a reported compound named 1,3-dihydrobenzo[c]thiophene, we isolated an unexpected molecule in one of the chromatography fractions by serendipity.
Pablo Simón Marqués, Nicolas Bréfuel, Claire Kammerer   +2 more
doaj   +1 more source

Natural Compounds as Guides for the Discovery of Drugs Targeting G-Protein-Coupled Receptors

Molecules, 2020
G protein-coupled receptors (GPCRs), which constitute the most populous family of the human proteome, are the target of 35–45% of approved therapeutic drugs. This review focuses on natural products (excluding peptides) that target GPCRs.
Joan Serrano-Marín, Irene Reyes-Resina, Eva Martínez-Pinilla, Gemma Navarro, Rafael Franco   +4 more
doaj   +1 more source

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

Angewandte Chemie, EarlyView.
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo, Maxence Urbani, Ana Barragán, Óscar Jover, Elena Pérez‐Elvira, Ilaria Tomei, Claudio Goletti, Alejandro Jiménez‐Martín, Aurelio Gallardo, Koen Lauwaet, David Écija, Diego Soler‐Polo, Marco Di Giovannantonio, Tomás Torres, José I. Urgel   +14 more
wiley   +2 more sources

Non‐Dilute Synthesis of Macrodiolides and Macrotetrolides Enabled by Confinement Catalysis

Angewandte Chemie, Volume 138, Issue 34, 17 August 2026.
Confinement catalysis within a hexameric resorcin[4]arene capsule enables macrolactonization under non‐dilute conditions (up to 0.1 M), overcoming the limitations of high‐dilution protocols (0.1–10 mM). This strategy provides direct access to 18–32‐membered macrodiolides and 26–32‐membered macrotetrolides in one pot and unlocks previously inaccessible ...
Feng‐Yuan Wang, Alessandro Prescimone, Daniel Häussinger, Konrad Tiefenbacher   +3 more
wiley   +2 more sources

5,15-Bis(4-pentyloxyphenyl)porphyrin

Acta Crystallographica Section E, 2013
In the title compound, C42H42N4O2, the complete molecule is generated by a crystallographic inversion centre. The porphyrin system exhibits a near planar macrocycle conformation with an average deviation from the least-squares plane of the 24 macrocycle ...
Mathias O. Senge
doaj   +1 more source