A solution‐processable sub‐nanocrystal of metal coordinated conjugated reticular oligomer with spin polarization functionality is employed as an active layer in planar photoelectrochemical water splitting. The rapid recombination of photo‐generated carriers remains a critical challenge limiting the photo‐electrocatalytic water splitting performance in ...
Ruijuan Zhang +6 more
wiley +1 more source
CyPLOS, novel synthetic ionophores based on amphiphilic disaccharide macrocycles [PDF]
C. COPPOLA +5 more
core
The Missing Element in the World of Macrocycles─<i>p</i>-Pyriporphyrin. [PDF]
Kamyszek J +8 more
europepmc +1 more source
During coffee bean and cherry washing, contaminants are released into water, making this process a major source of water pollution. Chlorogenic acid can be efficiently detected using hybrid zeolite–porphyrin materials by measuring fluorescence quenching, achieving detection limits lower than current regulatory thresholds.
João Otávio Donizette Malafatti +10 more
wiley +1 more source
Redox- and protonation-driven Baird and Clar aromaticity in asymmetric multicyclic octaphyrins. [PDF]
Ali MA +6 more
europepmc +1 more source
Metal‐Free Ligand‐Centered Radical Scavenging in Pyridine‐Modified Tetraaza Macrocycles
Ligand‐centered hydrogen‐atom transfer in pyridinophane macrocycles generates delocalized radicals, with Py2N2 enabling cooperative captodative stabilization and enhanced DPPH• quenching. Pyridine‐modified tetraaza macrocycles are widely studied as ligand platforms for metal coordination, yet their intrinsic redox and radical reactivity in the absence ...
Christina Mantsorov +9 more
wiley +1 more source
Synthesis and LCMS Characterization of a 1275-Member Library of 24-Atom Triazine Macrocycles Derived from Quantitative Dimerization Occurring with >99.9% Fidelity. [PDF]
Claton LE +15 more
europepmc +1 more source
Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley +1 more source
CO<sub>2</sub> Adsorption Capabilities of Functionalized Dyn[4]arenes. [PDF]
Alektoridis K, Rauls E.
europepmc +1 more source
Infrared Irradiation‐Assisted Pd/Cu Catalysis for Sustainable C–N Cross‐Coupling Reactions
A combined Pd/Cu catalytic system is demonstrated to be highly effective in promoting infrared irradiation‐assisted Buchwald–Hartwig aminations under nonanhydrous and open‐air conditions, using only a stoichiometric amount of a green reaction solvent.
Ambra M. Fiore +4 more
wiley +1 more source

