Results 51 to 60 of about 5,053 (210)
Pseudotetraivprolide is a new player among the Detoxin/Rimosamide‐like natural products! Its biosynthesis requires FabD from primary metabolism and a PipDFG complex for final‐step acetylation – unlocking its anti‐antibotic activity. Abstract Novel variants of known natural product (NP) classes can provide valuable insights into their biosynthesis ...
Edna Bode +13 more
wiley +1 more source
Mesoionic N‐Heterocyclic Olefins, Imines, Thiones, Phosphinidenes and Their Application in Catalysis
This minireview covers recent advances in the synthesis, reactivity, and metal‐free catalytic uses of mesoionic N‐heterocyclic olefins (mNHOs), imines (mNHIs), thiones (mNHTs), and phosphinidenes (mNHPs). Abstract Transition metal compounds are widely known for their ability to activate small molecules and are excellent catalysts for a wide range of ...
Subir Maji +3 more
wiley +1 more source
On‐line glucose and lactate monitoring in rat striatum: effect of malonate and correlation with histological damage [PDF]
Jane Skjoeth-Rasmussen +2 more
openalex +1 more source
Cyclopropenes in Photochemical Reactions
The photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
David Suárez‐García +2 more
wiley +1 more source
Malonate and Krebs Cycle Intermediates Utilization in the Presence of other Carbon Sources by Rhizobium japonicum and Soybean Bacteroids [PDF]
Dietrich Werner +2 more
openalex +1 more source
We synthesized a series of light to heavy fluorous Hoveyda–Grubbs precatalyst analogs modified in the alkoxybenzylidene part in positions 2 and 5 by long (fluorinated) ponytails and tested their activity in ring‐closing metathesis. The substitution mostly resulted in accelerated reaction but the precatalyst stability often decreased.
Pavlína Dundálková +4 more
wiley +1 more source
Die 4‐Cumarate‐Ligase (4CL1) aus Piper methysticum wurde mit einer nicht‐reduzierenden murinen Fettsäuresynthase verknüpft. Eine direkte Acylierung des ACP durch 4CL1 wurde beobachtet. Die Ketosynthase (KS) wurde so verändert, dass sie das nicht‐kanonische Zimtsäure‐Substrat akzeptiert.
Felix Lehmann +3 more
wiley +1 more source
Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate [PDF]
Rihanabanu +4 more
openalex +1 more source
A multienzyme was formed and evaluated by covalently linking 4‐coumarate ligase (4CL1) from Piper methysticum to a non‐reducing murine fatty acid synthase. 4CL1 acylates the acyl carrier protein (ACP). The ketosynthase (KS) was engineered to accept the non‐native cinnamoyl substrate, which is elongated by malonyl‐CoA loaded via the malonyl‐acetyl ...
Felix Lehmann +3 more
wiley +1 more source
Crystal structure of bis(4-methoxyphenyl) malonate [PDF]
H.C. Devarajegowda +4 more
openalex +1 more source

