EPR Studies on the Mono- and Dicobalt(II)-Substituted Forms of the Aminopeptidase from \u3cem\u3eAeromonas proteolytica\u3c/em\u3e. Insight into the Catalytic Mechanism of Dinuclear Hydrolases [PDF]
The structure and function of the prototypical dinuclear hydrolase, namely, the aminopeptidase from Aeromonas proteolytica (AAP), was probed by EPR spectroscopy of the mono- and dicobalt(II)-substituted derivatives.
Bennett, Brian, Holz, Richard C.
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Zinc (Zn) is a vital trace element that plays a pivotal role in protein synthesis, cellular growth, and differentiation and is involved as a cofactor of metalloenzymes, performing a wide variety of metabolic, immune, and synthesis roles.
Mansour Al Qurashi +7 more
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Transition metal-radical complexes and their catalytic reactivity [PDF]
by Chandan MukherjeePaderborn, Univ., Diss ...
Mukherjee, Chandan
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Synthesis of Homo- and Heterobimetallic Ni\u3csup\u3eII\u3c/sup\u3e–M\u3csup\u3eII\u3c/sup\u3e (M = Fe, Co, Ni, Zn) Complexes Based on an Unsymmetric Ligand Framework: Structures, Spectroscopic Features, and Redox Properties [PDF]
Several homo- and heterobimetallic NiII–MII complexes (MII = Fe, Co, Ni, Zn) supported by an unsymmetric polydentate ligand (L13−) are reported (L13− is the trianion of 2-[bis(2-hydroxy-3,5-tert-butylphenyl)aminomethyl]-4-methyl-6-[(2-pyridylmethyl ...
Fiedler, Adam T. +2 more
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Soft x-ray absorption spectroscopy of metalloproteins and high-valent metal-complexes at room temperature using free-electron lasers [PDF]
X-ray absorption spectroscopy at the L-edge of 3d transition metals provides unique information on the local metal charge and spin states by directly probing 3d-derived molecular orbitals through 2p-3d transitions.
Agapie, Theodor +5 more
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New "Cats" in the House: Chemistry Meets Biology in Artificial Metalloenzymes and Repurposed Metalloenzymes. [PDF]
Hartwig, John F, Ward, Thomas R
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Effect of ELF e.m. fields on metalloprotein redox-active sites
The peculiarity of the distribution and geometry of metallic ions in enzymes pushed us to set the hypothesis that metallic ions in active-site act like tiny antennas able to pick up very feeble e.m. signals.
Badon, T. +6 more
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Herpes simplex viruses (HSV‐1 and HSV‐2) are highly prevalent and contagious, causing lifelong infections that cannot be eradicated with current therapies.
Sabina Andreu +12 more
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Editorial: Advances in the Development of Artificial Metalloenzymes
Tatjana N. Parac-Vogt +3 more
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