Results 71 to 80 of about 11,207 (210)

Double role of metalloporphyrins in catalytic bioinspired supramolecular metal–organic frameworks (SMOFs)

open access: yesIUCrJ, 2018
Heterogeneous catalysts are of great interest in many industrial processes for environmental reasons and, during recent years, a great effort has been devoted to obtain metal–organic frameworks (MOFs) with improved catalytic behaviour. Few supramolecular
Arkaitz Fidalgo-Marijuan   +7 more
doaj   +1 more source

Hydride Transfer Limits Hydrogen Evolution Efficiency With Zn Porphyrin Photocatalysts [PDF]

open access: yesChem Asian J
The mechanism of photocatalytic hydrogen evolution catalyzed by a Zn‐based metalloporphyrin, using water and a cheap sacrificial donor, is studied computationally. The efficiency of hydrogen formation is limited by the competition with hydrogenation of the porphyrin, which leads to a reduced macrocycle.
El Bakouri O, Clausing S, Blancafort L.
europepmc   +2 more sources

Monoclonal antibodies against metalloporphyrins. Specificity of interaction with structurally different metalloporphyrins

open access: yesFEBS Letters, 1994
Monoclonal antibodies against Pd‐coproporphyrin I have been obtained. The antibody specificity for free as well as for conjugated Pd‐coproporphyrin I is characterized. Affinity constants are estimated for 3 monoclonal antibodies effectively interacting with free Pd‐coproporphyrin I.
Savitsky, Alexander P.   +3 more
openaire   +2 more sources

Heme oxygenase-1 as a modulator of intestinal inflammation development and progression [PDF]

open access: yes, 2018
Indexación: Scopus.Heme Oxygenase 1 (HMOX1) is an enzyme that catalyzes the reaction that degrades the heme group contained in several important proteins, such as hemoglobin, myoglobin, and cytochrome p450.
Alexis M. Kalergis   +12 more
core   +2 more sources

Metalloporphyrin‐Based Cathode for Rechargeable Magnesium‐Ion Batteries: Copper Leaching and Interphase Formation

open access: yesChemSusChem, EarlyView.
The initial cycling of [5,15‐bis(ethynyl)‐10,20‐diphenylporphinato]copper(II) electrodes in rechargeable Mg‐ion batteries is studied using electrochemical, spectroscopic, microscopic, and spectrometric methods such as total reflection X‐ray fluorescence spectrometry and time‐of‐flight secondary ion mass spectrometry .
Tom Philipp   +13 more
wiley   +1 more source

A Route to Surface-bound Metalloporphyrins as Models for Oxygen Reduction Catalysts [PDF]

open access: yes, 2017
The attachment nonmetal and magnesium ethynyl terminated porphyrin (TEPP and MgTEPP) to glassy carbon electrode was achieved through voltammetry. These attached porphyrins were studied by cyclic voltammetry (CV) and UV-visible spectroscopy. Surface-bound
Van Wyck, Stephen J
core   +1 more source

Engineered Metal–Organic Frameworks‐Based Materials for Environmental Detection

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Engineered metal–organic frameworks (MOFs) regulated by various material modification strategies are discussed for environmental contaminant detection under different sensing mechanisms, providing future improvements of MOFs in environmental detection. Sensitive and selective detection of contaminants is crucial for environmental protection.
Pan Gao   +3 more
wiley   +1 more source

Structural Design of MOF‐Based and MOF‐Derived Composites for Oxygen Evolution Electrocatalysis: Materials Innovation for Energy and Environmental Sustainability

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review provides an overview of recent developments in metal organic framework (MOF)‐based and MOF‐derived composites for efficient oxygen evolution reaction. This review also emphasizes the structural design of electrocatalyst, active site optimization, and emerging prospects of their use in practical electrolyzer systems.
Bhagyashri B. Kamble   +7 more
wiley   +1 more source

A Review of Metal–Organic Framework (MOF) Based Active Food Packaging: Materials Selection, Cellulose Matrices Current Advances, Synthesis and Characterizations

open access: yesPackaging Technology and Science, EarlyView.
Active packaging offers an effective approach to extending food shelf life. This review summarizes the past decade of progress in metal‐organic framework (MOF)‐based active food packaging, highlighting material selection, characterization, challenges, and future prospects.
Belladini Lovely   +4 more
wiley   +1 more source

Metallic Axial Asymmetry in Dome‐Like Iron Porphyrins Boosts Advanced Oxidation Processes: Implication of Allosteric Effect of Heme Peroxidases

open access: yesSmall Structures, EarlyView.
A structure–activity relationship between dome‐deformation‐induced metallic axial asymmetry and catalytic efficiency in iron porphyrins was established, providing a molecular blueprint for designing high‐performance enzyme‐mimetic catalysts. The remarkable catalytic activity of heme enzymes originates from distinctive allosteric effects mediated by ...
Junhao Gao   +8 more
wiley   +1 more source

Home - About - Disclaimer - Privacy