Computational Analysis of the Asymmetric Hydrogenation of γ-Ketoacids: Weak Interactions and Kinetics. [PDF]
Golovanov IS, Pospelov EV.
europepmc +1 more source
Switchable Magnesium Catalysis: Dehydrogenative Borylation Versus Hydroboration of Terminal Alkynes
Magnesium at the centre: A switchable magnesium catalyst enables selective dehydrogenative borylation or hydroboration of terminal alkynes. Organoboranes are key intermediates in modern synthetic chemistry, yet their preparation often relies on precious metal catalysts and multistep protocols.
Darakshan Parveen +4 more
wiley +1 more source
Iron tris-mesityl: a homoleptic iron(ii) ferrate species for directed C-H activation. [PDF]
Radović A +12 more
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A tetracarbonyl tungsten complex bearing a bis‐triazolylidene ligand exhibits excellent catalytic activity in the acceptorless dehydrogenative coupling of 1‐phenylethanol and 2‐aminobenzyl alcohol to form 2‐phenylquinoline with H2 evolution. Mechanistic investigations combining experimental and DFT studies reveal the unprecedented base‐promoted ...
Beatriz Garcia +2 more
wiley +1 more source
Square-Planar Ruthenium Alkylidyne Complexes Undergo Stepwise Rather Than Concerted [2 + 2] Cycloadditions with Alkynes. [PDF]
Cui M, Leutzsch M, Auer AA, Fürstner A.
europepmc +1 more source
Recent Progress on Giant Molecules: Synthesis, Assembly, and Applications
Giant molecules are molecules constructed by molecular nanoparticles with precise, rigid structure, have similar structures with small molecules and a large size as macromolecules. In this review, the constituent modules of giant molecules, as well as their synthesis, self‐assembly, applications in various fields and future developing prospect are ...
Haoyu Chen +7 more
wiley +1 more source
Lifecycle of dynamic covalent polar-olefin macrocycles via entropy-driven ring-opening polymerization and closed-loop chemical recycling. [PDF]
Li P, Li C, Lei M, Gu R, Tian H, Qu DH.
europepmc +1 more source
Advancements in 3D Printing of Self‐Healing Polymer Systems
This review provides an overview of the most common 3D printing technologies and summarizes the numerous methods to produce self‐healing materials. The challenges and strategies used to adapt these methods to 3D printing are then highlighted to provide a framework for future research in 3D printing self‐healing polymer systems.
Adam L. Bachmann, Bryan S. Beckingham
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Rotaxane synthesis <i>via</i> a dynamic [2]catenane-ring-opening, axle-cleaving double cross metathesis. [PDF]
Cetin MM +5 more
europepmc +1 more source
Guanidinium‐ and indole‐functionalized poly(glycidyl ether)s were developed as non‐viral gene delivery vectors with tunable hydrophilic–hydrophobic balance. All polymers formed stable DNA polyplexes, while moderate indole content yielded the highest transfection efficiency at low N/P ratios.
Markus Kötzsche +8 more
wiley +1 more source

