Results 31 to 40 of about 71,210 (340)

Isobaric Vapour Liquid Equilibrium at 101.3 kPa for the Binary Mixtures 2-Methyl-2-Butene / Methanol and Isopentane / Methanol

open access: yesChemical Engineering Transactions, 2013
Due to the increased interest for using tertiary ethers as fuel additives (such as TAME – tert-amyl-methyl-ether synthesis), the research intensified to study its thermodynamic aspects.
M. Bernabeu Diaz   +4 more
doaj   +1 more source

Transition-metal-free formal cross-coupling of aryl methyl sulfoxides and alcohols via nucleophilic activation of C-S bond

open access: yesNature Communications, 2020
Cross-coupling processes without the use of transition metals are challenging to achieve. Here, the authors show a transition-metal-free cross-coupling utilizing aryl(heteroaryl) methyl sulfoxides and alcohols to afford alkyl aryl(heteroaryl) ethers and ...
Guolin Li   +7 more
doaj   +1 more source

Poly(2-oxazolines) in biological and biomedical application contexts. [PDF]

open access: yes, 2007
Polyoxazolines of various architectures and chemical functionalities can be prepared in a living and therefore controlled manner via cationic ring-opening polymerisation.
Adams, Nico, Schubert, Ulrich S
core   +1 more source

Cyanovinylation of Aldehydes: Organocatalytic Multicomponent Synthesis of Conjugated Cyanomethyl Vinyl Ethers

open access: yesMolecules, 2021
A novel organocatalytic multicomponent cyanovinylation of aldehydes was designed for the synthesis of conjugated cyanomethyl vinyl ethers. The reaction was implemented for the synthesis of a 3-substituted 3-(cyanomethoxy)acrylates, using aldehydes as ...
Samuel Delgado-Hernández   +2 more
doaj   +1 more source

Bile acids. OV. 2,2-Dimethoxypropane: an esterifying agent preferred to diazomethane for chenodeoxycholic acid.

open access: yesJournal of Lipid Research, 1978
Artifacts formed by methylation of chenodeoxycholic acid with diazomethane are identical to the synthetic 3alpha- and 7 alpha-monomethyl ethers of methyl chenodeoxycholate. The extent of formation of these artifacts with time has been studied.
R Shaw, W H Elliott
doaj   +1 more source

High turnover in electro-oxidation of alcohols and ethers with a glassy carbon-supported phenanthroimidazole mediator. [PDF]

open access: yes, 2017
Glassy carbon electrodes covalently modified with a phenanthroimidazole mediator promote electrochemical alcohol and ether oxidation: three orders of magnitude increase in TON, to ∼15 000 in each case, was observed compared with homogeneous mediated ...
Berben, Louise A   +3 more
core   +1 more source

Heterogeneous acidic catalysts for the tetrahydropyranylation of alcohols and phenols in green ethereal solvents

open access: yesBeilstein Journal of Organic Chemistry, 2018
The application of heterogeneous catalysis and green solvents to the set up of widely employed reactions is a challenge in contemporary organic chemistry. We applied such an approach to the synthesis and further conversion of tetrahydropyranyl ethers, an
Ugo Azzena   +4 more
doaj   +1 more source

Final Report on the Safety Assessment of PPG-2 Methyl Ether, PPG-3 Methyl Ether, and PPG-2 Methyl Ether Acetate [PDF]

open access: yesInternational Journal of Toxicology, 2009
PPG-2 methyl ether, PPG-3 methyl ether, and PPG-2 methyl ether acetate are used in cosmetics as fragrance ingredients and/or solvents at concentrations of 0.4% to 2%. Propylene glycol ethers are rapidly absorbed and distributed throughout the body when introduced by inhalation or oral exposure, but the inhalation toxicity of PPG-2 methyl ether vapor ...
James G. Marks   +8 more
openaire   +3 more sources

Rate constants and Arrhenius parameters for the reactions of OH radicals and Cl atoms with CF3CH2OCHF2, CF3CHClOCHF2 and CF3CH2OCClF2, using the discharge-flow/resonance fluorescence method [PDF]

open access: yes, 2001
Rate constants have been determined for the reactions of OH radicals and Cl atoms with the three partially halogenated methyl-ethyl ethers, CF\(_3\)CH\(_2\)OCHF\(_2\), CF\(_3\)CHClOCHF\(_2\) and CF\(_3\)CH\(_2\)OCClF\(_2\), using discharge-flow ...
Beach, S. D.   +3 more
core   +1 more source

4‐nitrobenzoate inhibits 4‐hydroxybenzoate polyprenyltransferase in malaria parasites and enhances atovaquone efficacy

open access: yesFEBS Letters, EarlyView.
Atovaquone is an antimalarial requiring potentiation for sufficient efficacy. We pursued strategies to enhance its activity, showing that 4‐nitrobenzoate inhibits 4‐hydroxybenzoate polyprenyltransferase, decreasing ubiquinone biosynthesis. Since atovaquone competes with ubiquinol in mitochondria, 4‐nitrobenzoate facilitates its action, potentiating ...
Ignasi Bofill Verdaguer   +7 more
wiley   +1 more source

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