Results 21 to 30 of about 1,422,910 (361)

Molecular Recognition and Assembly. [PDF]

open access: yesActa Chemica Scandinavica, 1996
The synthesis and characterization of a series of self-assembling capsules is described. Assembly takes place as a result of the self-complementary hydrogen bonding patterns on the subunit pieces and dimerization occurs in such a manner that the concave surfaces of the two subunits are directed at one another.
Julius Rebek, Jr.   +10 more
openaire   +2 more sources

Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation

open access: yesNature Communications, 2016
Formation of vicinal, quaternary stereocentres is challenging, but such products are commonly encountered in nature. Here, the authors report a palladium catalysed process to form vicinal quaternary carbons via propargylation, including in enantiopure ...
Xin Huang   +5 more
doaj   +1 more source

Lectin ligands: New insights into their conformations and their dynamic behavior and the discovery of conformer selection by lectins [PDF]

open access: yes, 1998
The mysteries of the functions of complex glycoconjugates have enthralled scientists over decades. Theoretical considerations have ascribed an enormous capacity to store information to oligosaccharides, In the interplay with lectins sugar-code words of ...
Bovin, N. V.   +11 more
core   +4 more sources

Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes

open access: yesNature Communications, 2019
Highly enantioselective synthesis of allenes has been relying, so far, on the steric hindrance of substrates. Here the authors achieve excellent stereocontrol in the synthesis of chiral allenes with a palladium-DTBM-SEGPHOS catalytic system in a non ...
Shihua Song   +3 more
doaj   +1 more source

Reinforced molecular recognition as an alternative to rigid receptors [PDF]

open access: yes, 2006
In theory, a perfectly rigid receptor will probably be an unbeatable binder. However, rigidity may not be easy to achieve in practice and it is certainly not Nature’s method to realise high affinity. In many proteins binding affinity is increased through
Otto, Sijbren,
core   +1 more source

Differential regulation of the Epr3 receptor coordinates membrane-restricted rhizobial colonization of root nodule primordia

open access: yesNature Communications, 2017
TheLotus japonicus LysM receptor kinase EPR3 perceives rhizobial exopolysaccharides to initiate infection of the root epidermis. Here the authors show that EPR3 also mediates infection thread progression in the root cortex and show that key transcription
Yasuyuki Kawaharada   +10 more
doaj   +1 more source

Molecular recognition on acoustic wave devices [PDF]

open access: yes, 1992
Microporous thin films composed either of zeolite crystals embedded in sol-gel derived glass or of a molecular coupling layer, zeolite crystals and a porous silica overlayer, were formed on the gold electrodes of Quartz Crystal Microbalances (QCM). The
Bein, Thomas   +4 more
core   +1 more source

Gold-catalyzed stereoselective cycloisomerization of allenoic acids for two types of common natural γ-butyrolactones

open access: yesNature Communications, 2018
Gamma-butyrolactones are widespread in Nature, however direct catalytic methods to access them are limited. Here, the authors report a gold-catalyzed cycloisomerization of allenoic acids to acces γ-butyrolactones and apply it to the asymmetric synthesis ...
Jing Zhou, Chunling Fu, Shengming Ma
doaj   +1 more source

Microparticles as Viral RNA Carriers from Stool for Stable and Sensitive Surveillance

open access: yesDiagnostics, 2023
Since its discovery, polymerase chain reaction (PCR) has emerged as an important technology for the diagnosis and identification of infectious diseases.
Emmanuel George Kifaro   +8 more
doaj   +1 more source

Bioinspired tetraamino-bisthiourea chiral macrocycles in catalyzing decarboxylative Mannich reactions

open access: yesBeilstein Journal of Organic Chemistry, 2022
A series of tetraamino-bisthiourea chiral macrocycles containing two diarylthiourea and two chiral diamine units were synthesized by a fragment-coupling approach in high yields.
Hao Guo   +3 more
doaj   +1 more source

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