Results 121 to 130 of about 13,631,199 (274)
N-Heterocyclic Carbene Iron Silyl Hydride Complexes
, 2017 International audienceReaction of N-heterocyclic carbene iron(0) tetracarbonyl complexes with hydrosilanes (triphenylsilane, methyldiphenylsilane and diphenylsilane) under UV irradiation (350 nm) afforded the octahedral N-heterocyclic carbene iron(II ...
Roisnel, T. +17 more
core +1 more source
Well‐Defined Nickel Precatalysts: Form, Function, and Application
Chemistry – A European Journal, EarlyView.This review provides guidance on which nickel precatalysts to choose for a given application or which properties to prioritize in reaction development. A summary of the ease of synthesis, stability, diversity, accessibility, modularity, and general applicability is provided along with a related infographic.
Morgan E. John +3 more
wiley +1 more source
Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC)
, 2018 Rottschäfer D, Blomeyer S, Neumann B, Stammler H-G, Ghadwal R. Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC). Chemistry - A European Journal.
Blomeyer, Sebastian ; https://orcid.org/ +4 more
core +1 more source
Isolable ArInH2: Double Hydroindation Agent
Chemistry – A European Journal, EarlyView.Stable crystalline monomeric indium dihydride ArInH2 was isolated and completely characterized using effective support of the P,C,P‐pincer ligand (Ar = 2,6‐(tBu2PO)2C6H3). It serves as unparalleled hydroindation agent, thereby extending the family of known hydrometallation process relying on heavy p‐block metals.
Adam Hochmal +5 more
wiley +1 more source
Triphenylene-Based Tris(N-Heterocyclic Carbene) Ligand: Unexpected Catalytic Benefits
, 2013 Triple play: A novel triphenylene-based tris(N-heterocyclic carbene) ligand with D3h symmetry and a highly π-delocalized system has been prepared and coordinated to palladium and gold (see figure).
Macarena Poyatos +5 more
core +1 more source
Chemistry – A European Journal, EarlyView.A Pt(II) bis(NHC) complex is immobilized on mesoporous silica through directional F–Si interactions encoded in the ligand framework. Quantitative 19F{29Si} REDOR experiments and molecular dynamics simulations establish Å‐scale catalyst–support contacts and define the interfacial organization.
Alexander Bergen +10 more
wiley +1 more source
N‐Heterocyclic Carbenes and N‐Heterocycles as Synthetic Reagents and Building Blocks
Chemistry – A European JournalAbstractN‐Heterocyclic carbenes (NHCs) have become important tools in modern synthetic chemistry due to their versatility as organocatalysts and ligands in organometallic complexes. Since their first isolation and characterization, NHCs have demonstrated significant utility in various catalytic processes, offering advantages such as strong σ‐electron ...
Emily Jacobs, Thanh Vinh Nguyen
openaire +2 more sources
N‐Boron‐Functionalized Anionic N‐Heterocyclic Carbenes (NBA‐NHCs)—A Case Study
Chemistry – A European Journal, EarlyView.The synthesis and characterization of a new family of N‐boron‐functionalized anionic N‐heterocyclic carbenes (NBA‐NHCs), IiPrB(CN)3−, IiPr(C2F5)BF2−, IMesB(CN)3−, and IMes(C2F5)BF2−, is reported. ABSTRACT The synthesis and characterization of a new family of N‐boron‐functionalized anionic NHCs (NBA‐NHCs), IiPrB(CN)3− (5), IiPr(C2F5)BF2− (6), IMesB(CN)3−
Sophie Mann +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Understanding aromaticity has evolved from benzene‐centric concepts to a broad multidimensional framework spanning organic, inorganic, and excited‐state systems. This review highlights ambiguities between magnetic, electronic, geometric, and energetic descriptors, emphasizing the need for unified, multi‐criteria approaches.
Sílvia Escayola +2 more
wiley +1 more source