Results 141 to 150 of about 13,631,199 (274)

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo, Vincenzo Patamia, Chiara Zagni, Antonio Rescifina, Giuseppe Floresta   +4 more
wiley   +1 more source

Molecular Modification Strategies for CO2 Electroreduction to C2+ Products: Classifications, Mechanisms, Advances, and Perspectives

EcoEnergy, EarlyView.
This review comprehensively outlines molecular modification strategies for steering CO2 electroreduction toward C2+ products, including the classification of diverse molecular structures, elucidation of their roles in microenvironment regulation, dissection of C–C coupling pathway engineering, and forward‐looking perspectives on machine learning and ...
Lingling Peng, Hanwen Liu, Tianyou Peng
wiley   +1 more source

Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles

European Journal of Organic Chemistry, EarlyView.
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu, Mauro Uras, Angelo Frongia   +2 more
wiley   +1 more source

The Expanding Role of Diazirines in Synthetic Methodology

European Journal of Organic Chemistry, EarlyView.
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic, Dominik Schnalzer, Marko D. Mihovilovic, Michael Schnürch   +3 more
wiley   +1 more source

Selective N‐Functionalization of Pyrazoles

European Journal of Organic Chemistry, EarlyView.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek, Matthias Schrader, Christopher J. Teskey   +2 more
wiley   +1 more source

Practical One‐Pot Synthesis of Cyclic Conjugated Amides From Ketones

European Journal of Organic Chemistry, EarlyView.
Cyclic conjugated amides from simple ketones: a one‐pot bromoform‐mediated homologation/amidation sequence provides direct access to 20 conjugated amides, including functionalized and linear examples, in up to 91% yield. Conjugated amides are valuable building blocks in organic synthesis; however, general access to cyclic conjugated amides remains ...
Maximilian Voigtländer, Johannes F. Teichert   +1 more
wiley   +1 more source

University teaching of mass spectrometry as a key practical technique within the context of a fully integrated, spiral curriculum

Rapid Communications in Mass Spectrometry, EarlyView.
Rationale Mass spectrometry (MS) is introduced to high school students in the UK in many pre‐university course syllabi. As such, we have identified the use of MS as a key technique that should be taught practically to undergraduates from the outset of their studies.
Andrew F. Worrall, Craig D. Campbell, Megan O. Midson, Malcolm I. Stewart   +3 more
wiley   +1 more source

The crystalline radical anion salt of a free N-heterocyclic carbene. [PDF]

Chem Sci
Smits P, Pecaut J, Philouze C, Fortage J, Tomás-Mendivil E, Martin D.   +5 more
europepmc   +1 more source

Super‐Electron‐Donor Polymers: From Monomer Design to Redox Functionality

Small, EarlyView.
2,2'‐Bipyridinylidenes are known for their “super‐electron‐donor” properties and have therefore been used beyond the field of organic synthesis. Their two‐electron redox process at a low potential of 1.8 V vs. Li/Li+ makes them attractive negative p‐type electrode‐active materials.
Luisa Rzesny, Aswadh Shyma Sajeevan, Caroline Schmidt, Johannes Lahr, Christoph Lorenz, Mathias Hermann, Nicolas Dupré, Stéven Renault, Philippe Poizot, Birgit Esser   +9 more
wiley   +1 more source

Chiral N-Heterocyclic Carbene On-Surface Induced Electronic Spin Filtration. [PDF]

J Am Chem Soc
Sasmal HS, Gupta A, Nalop A, Bhowmick DK, Schwab D, Tyler BJ, Doltsinis N, Naaman R, Glorius F.   +8 more
europepmc   +1 more source