Results 151 to 160 of about 36,419 (269)

Facile Access to N‐Substituted Pyridyl Ligands

Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
A modular, robust, and versatile Buchwald–Hartwig amination protocol that enables the rapid synthesis of bipyridine, phenanthroline, terpyridine, and pybox ligands bearing dialkylamine, diarylamine, and heteroaromatic N‐substituents. Pyridyl motifs equipped with N‐substituents can be powerful ligands for catalysis, yet their broader adoption is limited
Adam Petrik, Aleksander R. Bena, Haralds Baunis, Riley M. Kelch, Tehshik P. Yoon, Bartholomäus Pieber   +5 more
wiley   +1 more source

Transition Metal‐Catalyzed Functionalization of Nonallylic Alkenyl Alcohols via Chain‐Walking Strategies

Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
This minireview outlines recent advances in chain‐walking reactions of nonallylic alkenyl alcohols catalyzed by various transition metals, including palladium, ruthenium, rhodium, iridium, and nickel. Furthermore, the corresponding reaction mechanisms are discussed.
Yong Huang, Chong Liu, Jasmine X. Yan, Md Sajib Joardar, Ke Yang, Haibo Ge   +5 more
wiley   +1 more source

Photoinduced Selective Construction of Densely Functionalized Spirocyclic Ethers With Carbyne Equivalents

Angewandte Chemie, Volume 138, Issue 18, 27 April 2026.
A reactivity programmed cascade between carbyne equivalents and allylic benzoates was developed that sequentially orchestrates all three reactivity modes of carbyne equivalents, enabling the rapid installation of three σ‐bonds at a single carbon center and providing efficient, scalable access to structurally diverse spirocyclic ethers. ABSTRACT Carbyne
Jianke Su, Chu Wang, Zhongping Cai, Jiale Wu, Xu Yan Chen, Jie Wu   +5 more
wiley   +2 more sources

Advances in Catalysis Using N-Heterocyclic Carbene Platinum Complexes. [PDF]

Molecules
Smoczyńska A, Ostrowska S, Pietraszuk C.   +2 more
europepmc   +1 more source

Recent Progress in Homogeneous and Heterogeneous Pd Catalyst Systems for Suzuki‐Miyaura Coupling in the Absence of Added Base

ChemCatChem, Volume 18, Issue 9, 14 May 2026.
Suzuki–Miyaura coupling (SMC) is a powerful C─C bond forming method, but stoichiometric bases cause salt byproducts and protodeboronation. Base free SMC overcomes these issues and expands the range of compatible substrates. ABSTRACT Suzuki‐Miyaura coupling reaction (SMC) is an efficient method for constructing C─C bonds.
Mariko Honda, Ken Motokura
wiley   +1 more source

Acceptorless Dehydrogenative Polymerization

Angewandte Chemie, Volume 138, Issue 18, 27 April 2026.
Acceptor‐less dehydrogenative polymerization (ADP) enables the atom‐economic step‐growth synthesis of different type of polymers directly from simple alcohols, releasing H2 as the sole by‐product. This review outlines the mechanistic foundations, catalytic systems, and emerging polymer architectures of ADP, highlighting its potential as a sustainable ...
Xin Liu, Jessica L. Lathrop, Garret M. Miyake   +2 more
wiley   +2 more sources

N‑Heterocyclic Carbene Stabilized Aluminum Alkyls and Their Reactivity toward NHC-Alanes. [PDF]

Organometallics
Burnett S, Kennedy AR, Weetman CE.
europepmc   +1 more source

Reversible Dihydrogen Splitting and Diradical Reactivity of 1,4‐Digermabenzene‐1,4‐diide

ChemistryEurope, Volume 4, Issue 5, May 2026.
The diradical reactivity of the 1,4‐digermabenzene‐1,4‐diide, [(ADC)Ge]2, has been demonstrated with a range of substrates. Notably, it undergoes reversible dihydrogen splitting and radical coupling with TEMPO (2,2,6,6‐tetramethylpiperidinyloxyl = RO), forming [(ADC)GeH]2 and [(ADC)Ge(OR)]2, respectively.
Falk Ebeler, Yury V. Vishnevskiy, Jan‐Hendrik Lamm, Beate Neumann, Hans‐Georg Stammler, Rajendra S. Ghadwal   +5 more
wiley   +1 more source

Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds

Angewandte Chemie, Volume 138, Issue 18, 27 April 2026.
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +2 more sources

N-Heterocyclic Carbene Stabilized Bisacylgermylenes. [PDF]

Chemistry
Paris M, Fischer RC, Kelterer AM, Haas M.   +3 more
europepmc   +1 more source