Sulfur-to-Metal Single-Atom Editing of a Thiourea Self-Assembled Monolayer into an Adatom-Bound N-Heterocyclic Carbene Monolayer on Coinage Metal Surfaces. [PDF]
Han X +9 more
europepmc +1 more source
A general C─C cross‐coupling method employing earth‐abundant organoaluminium nucleophiles is enabled by electronically highly donating and sterically demanding ylide‐substituted phosphine (YPhos) ligands under Pd catalysis. This protocol represents an organoaluminium cross‐coupling that operates with a single catalyst system across all carbon ...
Nicolas Kaiser +3 more
wiley +1 more source
Kinetically Stable Boron‐Heteroatom Bonds
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova +8 more
wiley +2 more sources
N-Heterocyclic Carbene Stabilized Bisacylgermylenes. [PDF]
Paris M +3 more
europepmc +1 more source
Influence of the Size of the Metallacycle of P‐NHC Mn Complexes for the Hydrogenation of Esters
Does ring size matter? For manganese‐catalyzed ester hydrogenation, expanding the P‐NHC chelate ring from five to seven members unlocks superior activity at half the catalyst loading, shorter reaction times, and broader substrate scope, including the complete depolymerization of poly(ε‐caprolactone).
Romane Pointis +8 more
wiley +1 more source
N‑Heterocyclic Carbene Stabilized Aluminum Alkyls and Their Reactivity toward NHC-Alanes. [PDF]
Burnett S, Kennedy AR, Weetman CE.
europepmc +1 more source
Highlights Ionomers (PIL1‐d, Nafion, Sustainion XA9 & PTFE) have a significant effect on the performance of SnO2‐based gas diffusion electrodes (GDE) for eCO2RR. PIL1‐d effectively stabilizes SnO2 catalyst nanoparticles in spray‐coating inks and enhances eCO2RR towards formic acid.
Andrea Loi +10 more
wiley +1 more source
Single-Atom Ru on N-Heterocyclic Carbene-Functionalized Hypercrosslinked Polymers for N-Formylation of Amines with CO<sub>2</sub> and H<sub>2</sub>. [PDF]
Dang L, Gao Y, Wan Y, Li Q, Lei Y.
europepmc +1 more source
Organocatalytic Formal (3+2+1)‐Cycloaddition of Allenoates, Michael Acceptors, and Carbaldehydes
The use of secondary amine Lewis base organocatalysts allows for the unprecedented activation of allenoates for formal (3+2+1)‐cycloadditions with Michael acceptors and aromatic carbaldehydes. ABSTRACT Employing secondary amines as covalently interacting Lewis basic organocatalysts allows for the activation of electron‐deficient allenes (allenoates ...
David Naderer +5 more
wiley +1 more source
Umpolung Activation of Bicyclobutanes via N-Heterocyclic Carbene Catalysis. [PDF]
Chang YC +5 more
europepmc +1 more source

