Results 171 to 180 of about 13,631,199 (274)

Unlocking the Potential of Organoaluminum Reagents for Versatile C─C Couplings Using YPhos‐Pd Catalysts

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
A general C─C cross‐coupling method employing earth‐abundant organoaluminium nucleophiles is enabled by electronically highly donating and sterically demanding ylide‐substituted phosphine (YPhos) ligands under Pd catalysis. This protocol represents an organoaluminium cross‐coupling that operates with a single catalyst system across all carbon ...
Nicolas Kaiser   +3 more
wiley   +1 more source

Kinetically Stable Boron‐Heteroatom Bonds

open access: yesAngewandte Chemie, Volume 138, Issue 38, 14 September 2026.
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova   +8 more
wiley   +2 more sources

N-Heterocyclic Carbene Stabilized Bisacylgermylenes. [PDF]

open access: yesChemistry
Paris M   +3 more
europepmc   +1 more source

Influence of the Size of the Metallacycle of P‐NHC Mn Complexes for the Hydrogenation of Esters

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 18, 19 September 2026.
Does ring size matter? For manganese‐catalyzed ester hydrogenation, expanding the P‐NHC chelate ring from five to seven members unlocks superior activity at half the catalyst loading, shorter reaction times, and broader substrate scope, including the complete depolymerization of poly(ε‐caprolactone).
Romane Pointis   +8 more
wiley   +1 more source

Role of Binders on the Performance of SnO2‐Based Gas Diffusion Electrodes for Electrochemical CO2 Reduction to Formic Acid

open access: yesChemElectroChem, Volume 13, Issue 18, 19 September 2026.
Highlights Ionomers (PIL1‐d, Nafion, Sustainion XA9 & PTFE) have a significant effect on the performance of SnO2‐based gas diffusion electrodes (GDE) for eCO2RR. PIL1‐d effectively stabilizes SnO2 catalyst nanoparticles in spray‐coating inks and enhances eCO2RR towards formic acid.
Andrea Loi   +10 more
wiley   +1 more source

Organocatalytic Formal (3+2+1)‐Cycloaddition of Allenoates, Michael Acceptors, and Carbaldehydes

open access: yesChemistry – A European Journal, Volume 32, Issue 35, 19 September 2026.
The use of secondary amine Lewis base organocatalysts allows for the unprecedented activation of allenoates for formal (3+2+1)‐cycloadditions with Michael acceptors and aromatic carbaldehydes. ABSTRACT Employing secondary amines as covalently interacting Lewis basic organocatalysts allows for the activation of electron‐deficient allenes (allenoates ...
David Naderer   +5 more
wiley   +1 more source

Umpolung Activation of Bicyclobutanes via N-Heterocyclic Carbene Catalysis. [PDF]

open access: yesAngew Chem Int Ed Engl
Chang YC   +5 more
europepmc   +1 more source

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