Results 181 to 190 of about 13,631,199 (274)

Ru Nanoparticles Ligated by an N-Heterocyclic Carbene Derived from Uracil Nucleoside as Selective Antimicrobial Agents. [PDF]

open access: yesInorg Chem
Sánchez A   +9 more
europepmc   +1 more source

Synthesis and One‐Electron Reduction of Donor‐Acceptor‐Stabilized SiII–EII–SiII Trimetallylenes (E = Ge, Sn, Pb)

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
The first isolable trimetallylenes (SiII)2EII (E = Ge, Sn, Pb) with pπ‐type silanylidenyl donors have been synthesized, having donor–acceptor electronic structures that give rise to near‐infrared absorption and enable access to bis(silanylidenyl)‐supported GeI and SnI radical anions upon one‐electron reduction with elemental potassium. ABSTRACT Herein,
Chaopeng Hu   +3 more
wiley   +2 more sources

Searching for new candidates for antimalarial therapy: physicochemical and in vitro evaluation of gold(I) and silver(I) N-heterocyclic carbene complexes. [PDF]

open access: yesMalar J
Castro W   +10 more
europepmc   +1 more source

Unraveling Terminal Cobalt–Antimony Double Bond: Breaking New Ground in Heavy Pnictogen Multiple Bonds

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
N‐heterocyclic carbenes (NHCs) function as “molecular scissors,” cleaving otherwise inert Sb═Sb bonds in distibenes to generate monomeric, zwitterionic stibinide species. These intermediates act as efficient stibinidene transfer reagents, granting access to a rare terminal cobalt–stibinidene complex.
Daniel Meleschko   +7 more
wiley   +2 more sources

N-Heterocyclic Carbene (NHC) Catalysis in Enzymatic Organic Synthesis. [PDF]

open access: yesCoord Chem Rev
Chen X   +9 more
europepmc   +1 more source

Catalytic C–F Bond Activation at Room Temperature: Enolate Cross‐Couplings Enabled by [Pd(1‐MeNAP)TFA]2 and LiHMDS

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 38, 14 September 2026.
Catalysts generated from the trifluoroacetate‐bridged methylnaphthyl‐palladium dimer [Pd(1‐MeNAP)TFA]2 and biarylphosphine ligands in combination with the base LiHMDS promote α‐arylation reactions of various enolates with non‐activated aryl fluorides at room temperature.
Nele Krüger   +4 more
wiley   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Changing N^C^O to C^N^O Coordination in Cyclometalated Pt(II) and Pd(II) Complexes Modulates Stability and Emission Characteristics: Toward Brighter Versatility

open access: yesChemistry – A European Journal, Volume 32, Issue 34, 11 September 2026.
A new class of cyclometalated metal complexes with pincer luminophores (C^N^O and N^C^O) is reported. They unite high photoluminescence efficiencies in liquid solutions at r.t. with tunable colors across the visible spectrum and convenient synthetic accessibility.
Joschua Lüke   +4 more
wiley   +1 more source

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