Silyl Rearrangements in Gold‐Catalyzed Transformations
The synergy between the exceptional ability of gold catalysts to activate unsaturated substrates and the inherent tendency of organosilicon reagents to undergo silyl‐group rearrangements has unlocked a range of novel transformations, enabling access to otherwise challenging molecular architectures.
Patricia García‐Martínez +1 more
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Hidden in plain sight: commonly used copper N-heterocyclic carbene catalysts gain stabilization from anagostic Cu⋯H-C interactions. [PDF]
Yan C +5 more
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Radical C─H-Aroylation of Allenes via Cooperative Photoredox and N-Heterocyclic Carbene Catalysis. [PDF]
Banjare SK, Lezius L, Studer A.
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It may seem counterintuitive to first target a ruthenium alkylidyne when Grubbs‐type ruthenium carbene complexes are the actual goal. In the end, however, this tactic pays valuable dividends in terms of practicality, atom economy, flexibility as well as safety: the new route provides ready access to a large assortment of catalysts for alkene metathesis
Mingxu Cui, Alois Fürstner
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Pd(II)-NHC (NHC = N-Heterocyclic Carbene)-Catalyzed Alkylation of Primary Amides by Site-Selective N─C(O) Activation. [PDF]
Lei P +8 more
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Comparison of Alkyl-Bridged Bis(N-Heterocyclic Carbene) Nickel Precatalysts: Structure and Catalytic Activity in the Reductive Cleavage and Suzuki-Miyaura Reactions. [PDF]
Zhang CS +6 more
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Fluoro substituted N-heterocyclic carbene derivatives
XI ABSTRACT FLUORO SUBSTITUTED N-HETEROCYCLIC CARBENE DERIVATIVES Süleyman GÜLCEMAL Master Thesis in Chemistry Supervisor: Prof. Dr. Bekir ÇETİNKAYA 24.08.2005, 81 pages This thesis consists of three parts. The first part is a concise review on JV-heterocyclic carbene (NHC) ligands and their complexes. In part II the experimental details were explained.
openaire +2 more sources
An in‐depth survey dealing with the aromatic C—H bond functionalization of biologically‐relevant scaffolds featuring the indolinone and indanone core is discussed as they are unique aromatic scaffolds that are 1,2‐doubly fused with small five‐membered rings.
Vanessa Delahaye +3 more
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Impact of Chelation on Reactivity and Cytotoxicity of Hemilabile Biphenyl Gold(III) N-Heterocyclic Carbene Complexes. [PDF]
Lacoma T +6 more
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Acid‐Catalyzed Synthesis of Si‐Stereogenic Silanes
Si‐stereogenic silanes are important structural motifs in chemical synthesis, medicinal chemistry, and materials science. However, their catalytic enantioselective synthesis has largely relied on transition‐metal catalysts. Recently, Brønsted acids have been developed as promising alternatives.
Jung Tae Han, Benjamin List
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