Results 91 to 100 of about 76,223 (304)

Developing Quasi‐Solid‐State Ether‐Based Electrolytes with Trifluorotoluylation Ionic Liquids for High Voltage Lithium Metal Batteries

open access: yesAdvanced Materials, EarlyView.
This study proposes molecular design strategies to develop trifluorotoluylation ILs that enable quasi‐solid‐state ether‐based electrolytes for high‐voltage LMBs. The designed ILs greatly enhance the oxidative stability of the electrolyte and effectively suppress the dissolution of transition metal ions, facilitating the formation of a LiF‐rich ...
Jin Li   +9 more
wiley   +1 more source

Synthesis of diversely functionalised 2,2-disubstituted oxetanes: fragment motifs in new chemical space [PDF]

open access: yes, 2015
Novel oxetane motifs incorporating diverse functional groups on the ring are readily accessed by an O–H insertion/cyclisation strategy.
Bull, JA, Croft, RA, Davis, OA
core   +1 more source

Mussel‐Inspired Molecular Strategies for Fabricating Functional Materials With Underwater Adhesion and Self‐Healing Properties

open access: yesAdvanced Materials, EarlyView.
This review systematically examines the nanomechanical mechanisms of mussel‐inspired molecular interactions, primarily investigated by direct force measurement techniques such as surface forces apparatus and atomic force microscopy. The macroscopic adhesive and self‐healing performances of mussel‐inspired functional materials, including coacervates ...
Pan Huang, Hongjian Zhang, Hongbo Zeng
wiley   +1 more source

Homoallylic amines by reductive inter- and intramolecular coupling of allenes and nitriles

open access: yesBeilstein Journal of Organic Chemistry, 2011
The one-pot hydrozirconation of allenes and nitriles followed by an in situ transmetalation of the allylzirconocene with dimethylzinc or zinc chloride provides functionalized homoallylic amines.
Peter Wipf, Marija D. Manojlovic
doaj   +1 more source

Synthesis, Crystal Structures, and DFT Calculations of Three New Cyano(phenylsulfonyl)indoles and a Key Synthetic Precursor Compound

open access: yesCrystals, 2015
Three cyano-1-(phenylsulfonyl)indole derivatives, 3-cyano-1-(phenylsulfonyl) indole, (I), 2-cyano-1-(phenylsulfonyl)indole, (II), and 2,3-dicyano-1-(phenylsulfonyl) indole, (III), and a key synthetic precursor 1-(phenylsulfonyl)-1-(1,1-dimethylethyl ...
William L. Montgomery   +3 more
doaj   +1 more source

Reduction of the sulfoxide in glucoraphanin and sulforaphane by E. coli VL11 and BL21 (DE3) [PDF]

open access: yesSongklanakarin Journal of Science and Technology (SJST), 2016
Sulfoxide reductase activity of two Escherichia coli strains VL11 from human feces and BL21(DE3) from a molecular cloning host was expressed upon glucoraphanin induction for 16 hrs at 37°C under aerobic conditions.
Vijitra Luang-In   +1 more
doaj   +1 more source

Trimerization of aromatic nitriles [PDF]

open access: yes, 1977
Triazine compounds and cross-linked polymer compositions were made by heating aromatic nitriles to a temperature in the range of about 100 C to about 700 C, in the presence of a catalyst or mixture of catalysts.
Hsu, L. C.
core   +1 more source

2-Diphenylphosphanyl-4-pyridyl(dimethyl) amine as an effective ligand for the ruthenium(II) complex catalyzed homogeneous hydration of nitriles under neutral conditions [PDF]

open access: yes, 2011
New homogeneous catalyst comprised of [Ru(methallyl)(2)(cod)] (cod = 1,5-cyclooctadiene) (1) and 2-diphenylphosphanyl-4-pyridyl(dimethyl) amine (2) is shown to efficiently catalyze the hydration of various nitriles under neutral conditions. The hydration
Akisanya   +65 more
core   +1 more source

Unperceivable Designs of Wearable Electronics

open access: yesAdvanced Materials, EarlyView.
Unperceivable wearable technologies seamlessly integrate into everyone's daily life, for healthcare and Internet‐of‐Things applications. By remaining completely unnoticed both visually and tactilely, by the user and others, they ensure medical privacy and allow natural social interactions.
Yijun Liu   +2 more
wiley   +1 more source

The Iron-Type Nitrile Hydratase Activator Protein Is A GTPase [PDF]

open access: yes, 2017
The Fe-type nitrile hydratase activator protein from Rhodococcus equi TG328-2 (ReNHase TG328-2) was successfully expressed and purified. Sequence analysis and homology modeling suggest that it is a G3E P-loop guanosine triphosphatase (GTPase) within the ...
Bennett, Brian   +3 more
core   +1 more source

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