Electrospun PAN‐MXene nanofibers and yarns integrate enhanced thermal conductivity, photothermal conversion, and triboelectric energy harvesting within a flexible architecture. Interconnected MXene networks promote efficient phonon transport, while their surface chemistry strengthens tribo‐negative behavior, enabling a high power density of 432.7 mW m ...
Ahmadreza Moradi +2 more
wiley +1 more source
Tunable Sensitivity in PAN/CNF/PEDOT:PSS Nanofiber‐Based Piezocapacitive Sensors
This study demonstrates highly tunable, flexible pressure sensors made from a nanofibrous composite of polyacrylonitrile (PAN) and carbon nanofibers (CNF) or poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS). By adjusting filler type, concentration, and mat thickness, the sensors achieve large sensitivity improvements, stable ...
Alireza Gholamhoseini +4 more
wiley +1 more source
Biochemical characterization of two Brassica oleracea nitrile-specifier proteins
Brassica oleracea vegetables (e. g. cabbages) form bioactive isothiocyanates (ITCs) from glucosinolate (GLS) hydrolysis. However, enzymatic activity, acidic pH (below pH 5), and ferrous ions (Fe2+) can promote nitrile release, reducing the ITC amount. In
Kudzai Gracious Mbudu +7 more
doaj +1 more source
Conversion of Alcohols into Amides Using Alumina-Methanesulfonic Acid (AMA) in Nitrile Solvents [PDF]
The reaction of tertiary, secondary and benzylic alcohols with different nitriles in the presence of alumina-methanesulfonic acid (AMA) as a new reagent affords the corresponding amides in good yields (Table 1, 2).
Hashem Sharghi, Khodabakhsh Niknam
doaj
Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard +7 more
wiley +1 more source
Momentum Transfer Rate Constants for Collision of Cl-with Trans-Dichloroethylene and Para-Difluorobenzene [PDF]
A classical theory is developed which calculates the momentum transfer rate constant between an ion and a non-polar molecule. The model takes into consideration the effect of diffraction outside the capture limit on the rate constants. The theory is used
Sadreddin Hosseini, Timothy Su
doaj
Electrochemistry of 2,2'-Bipyridine Complexes of Cobalt in the Presence of Acrylonitrile [PDF]
The previously claimed (1) catalysis of the electroreduction of acrylonitrile by means of a complex of Co(I) and 2,2′‐bipyridine is shown to be erroneous. The “catalytic currents” result instead from the two‐electron reduction of a mixed complex of Co(I)
Anson, Fred C. +2 more
core
A soft robotic simulator is developed to replicate the digital removal of feces (DRF), a sensitive yet essential nursing procedure. Integrating soft actuators, sensors, and a realistic rectal model, the simulator balances functional fidelity with perceptual realism. Engineering evaluations and nurse feedback confirm its potential to enhance training in
Shoko Miyagawa +10 more
wiley +1 more source
Dynamic dielectric properties and the γ transition of bromine doped polyacrylonitrile
Based on monitoring the γ process (the lowest temperature-relaxation) in polyacrylonitrile (PAN) by dynamic dielectric spectroscopy, new evidence for the formation of a charge transfer complex between bromine dopants and nitrile groups is presented.
doaj +1 more source
Multiple States of Nitrile Hydratase from Rhodococcus equi TG328-2: Structural and Mechanistic Insights from Electron Paramagnetic Resonance and Density Functional Theory Studies [PDF]
Iron-type nitrile hydratases (NHases) contain an Fe(III) ion coordinated in a characteristic “claw setting” by an axial cysteine thiolate, two equatorial peptide nitrogens, the sulfur atoms of equatorial cysteine-sulfenic and cysteine-sulfinic acids, and
Stein, Natalia +9 more
core +1 more source

