Results 131 to 140 of about 116,978 (344)

Dynamic dielectric properties and the γ transition of bromine doped polyacrylonitrile

open access: yeseXPRESS Polymer Letters, 2007
Based on monitoring the γ process (the lowest temperature-relaxation) in polyacrylonitrile (PAN) by dynamic dielectric spectroscopy, new evidence for the formation of a charge transfer complex between bromine dopants and nitrile groups is presented.
doaj   +1 more source

Bioinspired Adaptive Sensors: A Review on Current Developments in Theory and Application

open access: yesAdvanced Materials, EarlyView.
This review comprehensively summarizes the recent progress in the design and fabrication of sensory‐adaptation‐inspired devices and highlights their valuable applications in electronic skin, wearable electronics, and machine vision. The existing challenges and future directions are addressed in aspects such as device performance optimization ...
Guodong Gong   +12 more
wiley   +1 more source

Multiple States of Nitrile Hydratase from Rhodococcus equi TG328-2: Structural and Mechanistic Insights from Electron Paramagnetic Resonance and Density Functional Theory Studies [PDF]

open access: yes, 2017
Iron-type nitrile hydratases (NHases) contain an Fe(III) ion coordinated in a characteristic “claw setting” by an axial cysteine thiolate, two equatorial peptide nitrogens, the sulfur atoms of equatorial cysteine-sulfenic and cysteine-sulfinic acids, and
Stein, Natalia   +9 more
core   +1 more source

From Carbon Nitrides to COFs: Opportunities and Prospects in Photocatalytic CO2 Reduction

open access: yesAdvanced Materials, EarlyView.
To underscore the potential of polymeric photocatalysts for CO2 photoreduction—from carbon nitrides to covalent organic frameworks—the table of contents graphic presents recent breakthroughs in the design of light‐responsive organic photocatalysts.
Wei Che   +10 more
wiley   +1 more source

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

Preparation of heterocyclic block copolymer from perfluoroalkylene oxide alpha, omega-diamidoximes [PDF]

open access: yes, 1979
Diamidoxime monomers are intermolecularly and thermally condensed to form a heat and chemical resistant polymer containing 1,2,4-oxadiazole linkages with identical bivalent organic radicals or any combination of bivalent organic radicals selected from ...
Iannone, M., Ross, L. O., Rosser, R. W.
core   +1 more source

A Roadmap for Plasma‐Enabled Electrocatalysis in Urea Production

open access: yesAdvanced Materials, EarlyView.
A modular plasma—electrochemical platform enables fully electrified urea synthesis from air and CO2 under ambient conditions. This Review integrates plasma oxidation, C─N coupling electrolysis, mechanistic insights, and techno‐economic metrics into a roadmap for scalable, distributed, and renewable fertilizer production.
Jingwen Huang   +6 more
wiley   +1 more source

Detection of (15)NNH+ in L1544: non-LTE modelling of dyazenilium hyperfine line emission and accurate (14)N/(15)N values

open access: yes, 2013
Samples of pristine Solar System material found in meteorites and interplanetary dust particles are highly enriched in (15)N. Conspicuous nitrogen isotopic anomalies have also been measured in comets, and the (14)N/(15)N abundance ratio of the Earth is ...
Bizzocchi, Luca   +3 more
core   +1 more source

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