Results 91 to 100 of about 14,073 (324)

Enhancing Biogenic Formic Acid Production in the Modified OxFA Process by Acetonitrile Addition

Advanced Science, EarlyView.
In this study, the beneficial effect of using acetonitrile as a co‐solvent in the modified OxFA process is shown, outperforming methanol, demonstrating improved reaction kinetics combined with high selectivity for the HPA‐2 (H5PV2Mo10O40) catalyzed oxidation of xylose to FA.
Jan‐Dominik H. Krueger, Pegah Saedi, Maximilian J. Poller, Alberto Collauto, Jason P. Hallett, David Robinson, Maxie M. Roessler, Jakob Albert   +7 more
wiley   +1 more source

Ion–molecule reactions between ionized nitrile oxides and neutral nitrile

International Journal of Mass Spectrometry, 2002
Abstract The ion–molecule reactions of ionized nitrile oxide, RCN + O , with several neutral nitriles have been studied using both tandem mass spectrometric techniques and ab initio molecular orbital calculations. Ionized oxygen atom transfer as well as a formal substitution of nitric oxide by the neutral reagent in the radical cation were the ...
Gerbaux, Pascal, Barbieux-Flammang, Monique, Flammang, Robert, Bouchoux, Guy   +3 more
openaire   +2 more sources

Orchestrated Engineered Polyphenol‐Peptide Condensates Coupled With β‐GP Reverses Diabetic Osteoporosis by Remodeling Mitophagy

Advanced Science, EarlyView.
A multifunctional β‐GP@EGCG‐E7 nanoplatform is engineered by polyphenol–peptide condensation and phosphate loading. Bone‐targeted delivery, antioxidant and anti‐inflammatory activity, and mitophagy restoration are integrated in one system, enabling protection of osteoblasts and endothelial cells and promoting bone regeneration under diabetic ...
Xiuyun Xu, Meiqin Zhang, Ting Wu, Erfan Wei, Andrei Y. Hancharou, Zeying Wang, Zijuan Wang, Letian Lv, Likun Wu, Xingtong Pan, Qiyue Zhu, Xinyi Dong, Hao Liu, Yongsheng Zhou   +13 more
wiley   +1 more source

Investigation of Nitrile Oxide-Alkyne 1,3-Dipolar Cycloadditions and Their Potential Viability for Synthesis of Stapled Peptides

, 2020
The nitrile oxide-alkyne 1,3-dipolar cycloaddition reaction is a concerted reaction between a nitrile oxide, which is usually generated in situ, and an alkyne to afford an isoxazole. This reaction has been previously used in post-synthetic modification
Teeples, Charles
core  

Deep Eutectic Polymer Electrolyte with Competitive Hydrogen‐Bonding Coordination for High‐Voltage Nickel‐rich Lithium Metal Batteries

Advanced Science, EarlyView.
To stabilize high‐voltage Li||NCM811 batteries, we develop an in situ polymerized deep‐eutectic electrolyte (p‐DEPE) featuring competitive hydrogen‐bonding coordination. This design weakens Ni4+ adsorption, suppresses oxygen release, and enhances interfacial stability.
Yuxin Fan, Miao He, Yin Hu, Wei Chen, Yichao Yan, Tianyu Lei, Dongjiang Chen   +6 more
wiley   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

Angewandte Chemie, EarlyView.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis, Matteo Damian, Francesco G. Mutti   +2 more
wiley   +2 more sources

A [3+2] nitrile oxide cycloaddition approach to retinoids

, 1988
The C-20 retinoid carbon skeleton was assembled through a C(14) + C(6) approach by interception of the nitrile oxide derived from the C(14) aldehyde component with a C(6) diene dipolarophile followed by Mo(CO)6 -promoted ring opening of the derived 3,5 ...
Pier Giovanni Baraldi, Gian Piero Pollini, Stefano Manfredini, Daniele Simoni, SIMONI, Daniele, Simonetta Benetti, BENETTI, Simonetta, POLLINI, Gian Piero, BARALDI, Pier Giovanni, BARCO, Achille, Achille Barco, GUARNERI, Mario, Mario Guarneri, MANFREDINI, Stefano   +13 more
core   +1 more source

Multi‐Targeting Carnosic Acid Kills Drug‐Resistant Helicobacter pylori With Narrow‐Spectrum Activity

Advanced Science, EarlyView.
Carnosic acid selectively eradicates drug‐resistant Helicobacter pylori through a multi‐targeted mechanism involving urease inhibition, membrane disruption, and biofilm eradication. It exhibits no detectable resistance, potent in vivo efficacy, and minimal impact on gut microbiota, positioning it as a promising narrow‐spectrum lead compound against ...
Yuefan Bai, Hongming Huang, Xudong Hang, Shanwei Hu, Qian Tong, Jingchen Xu, Jia Jia, Hongkai Bi   +7 more
wiley   +1 more source

Incorporation of Organic Counter‐Cations Into Poly(Heptazine Imide) Networks for Promoting Proton‐Coupled Electron Transfer During Photocatalytic H2O2 Evolution

Angewandte Chemie, EarlyView.
Incorporation of N‐based onium ions into the ionic framework of poly(heptazine imide) was obtained via protonation‐deprotonation of PHI frameworks arising from a parent Na‐containing analogue. Particularly, methylammonium moieties, through their small molecular size, hydrogen bonding capabilities and rotational mobility, appear to stabilize ...
Dingqiao Ji, Hikmat Binyaminov, Desiree Leistenschneider, Martin Oschatz, Paolo Giusto, Markus Antonietti, Horațiu Szalad   +6 more
wiley   +2 more sources

An Insight into Selective Olefin Bond Functionalization of Cyclodienes through Nitrile Oxide 1,3-Dipolar Cycloadditions

, 2019
Selective functionalizations of the ring olefin bond of various commercial cyclodienes through nitrile oxide dipolar cycloaddition is described. Nitrile oxides were generated from primary nitroalkanes by Mukaiyama’s method.
Fülöp Ferenc, Nonn Melinda, Kiss Loránd, Benke Zsanett Amália, Kiss, Loránd, Nonn, Melinda, Benke, Zsanett Amália, Fülöp, Ferenc   +7 more
core   +1 more source