Aryl nitrile oxide cycloaddition reactions in the presence of pinacol boronic acid ester
Beilstein Journal of Organic Chemistry, 2012 An aryl substrate with dual functionality consisting of a nitrile oxide and a pinacolyl boronate ester was prepared by mild hypervalent iodine oxidation (diacetoxyiodobenzene) of the corresponding aldoxime, without decomposition of the boronate ...
Sarah L. Harding +2 more
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, 2021 In recent years, polymers bearing reactive groups have received significant interest for biomedical applications. Numerous functional polymer platforms have been introduced, which allow for the preparation of materials with tailored properties via post ...
Kristian Kempe (1308939) +9 more
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Metal Catalysis Acting on Nitriles in Early Earth Hydrothermal Systems
Life, 2023 Hydrothermal systems are areas in which heated fluids and organic molecules rush through basaltic material rich in metals and minerals. By studying malononitrile and acetonitrile, we examine the effects of metal and mineral nanoparticles on nitrile ...
Miranda Sturtz, Christopher House
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Synthesis of Spiroisoxazolines by 1,3-Dipolar Cycloaddition
Molecules, 1997 The cycloaddition of the chiral nitrile oxide 1 to 1-R-substituted 3,3-methylene-5,5-dimethyl-2-pyrrolidinones 2 (where R is H, n-butyl-, 1,1-dimethylethoxycarbonyl-, 1-methylethenyl- and acetyl-) proceeds regioselectively under the formation of ...
Peter Ertl +3 more
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Elastomeric Core-Conductive Shell Slurry Additive Stabilizes High-Voltage NCM811 Cathodes via Mechanical-Electrical Dual Regulation. [PDF]
Adv Sci (Weinh)A core‐shell ASA slurry additive constructs a mosaic‐like interface on high‐voltage NCM811 cathodes. This architecture decouples interfacial functions: the elastomeric core buffers mechanical stress to prevent microcracking, while the conductive shell facilitates rapid ion/electron transport, enabling mechanical‐electrical dual regulation and enhanced ...
Duan J +16 more
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Solid phase strain promoted “click” modification of DNA via [3+2]-nitrile oxide–cyclooctyne cycloadditions [PDF]
, 2011 Biocompatible, strain promoted cyclooctyne–nitrile oxide click chemistry is demonstrated as a rapid and reliable method for DNA conjugation on the solid ...
Ishwar Singh +3 more
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A Convenient Synthesis of Novel Isoxazolidine and Isoxazole Isoquinolinones Fused Hybrids
Molecules, 2023 Isoxazolidine, isoxazole, and isoquinolinone rings are present in the structure of several natural products and/or pharmaceutically interesting compounds.
Konstantinos A. Ouzounthanasis +2 more
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Stereoselective Syntheses of Epothilones A and B via Directed Nitrile Oxide Cycloaddition1
, 2016 Stereoselective Syntheses of Epothilones A and B via Directed Nitrile Oxide ...
Jeffrey W. Bode (1331538) +1 more
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Site- and Regioselectivity of Nitrile Oxide-Allene Cycloadditions : DFT-Based Semiquantitative Predictions [PDF]
, 2017 Nitrile oxide 1,3-dipolar cycloaddition to arylsulfonyl- and dialkylaminoallenes have been investigated within the framework of the Kohn-Sham density functional theory (DFT) at the B3LYP/6-31G(d,p) level. The hitherto-unexplained experimental behavior of
A. Ponti +5 more
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Rapid Metal -free Macromolecular Coupling via in situ Nitrile Oxide-Activated Alkene Cycloaddition. [PDF]
J Polym Sci A Polym Chem, 2014 Nitrile oxide 1,3 dipolar cycloaddition is a simple and powerful coupling methodology. However, the self-dimerization of nitrile oxides has prevented the widespread use of this strategy for macromolecular coupling.
Isaacman MJ, Cui W, Theogarajan LS.
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