Results 11 to 20 of about 29,634 (298)
Metal Catalysis Acting on Nitriles in Early Earth Hydrothermal Systems
Life, 2023 Hydrothermal systems are areas in which heated fluids and organic molecules rush through basaltic material rich in metals and minerals. By studying malononitrile and acetonitrile, we examine the effects of metal and mineral nanoparticles on nitrile ...
Miranda Sturtz, Christopher House
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Inverse electron-demand 1,3-dipolar cycloaddition of nitrile oxide with common nitriles leading to 3-functionalized 1,2,4-oxadiazoles [PDF]
, 2011 A carbamoyl-substituted nitrile oxide was generated upon treatment of easily available 2-methyl-4-nitro-3-isoxazolin-5(2H)-one with THF (not dried); the reaction proceeded efficiently even in the absence of any special reagents and reaction conditions ...
1020 +15 more
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Synthesis of Spiroisoxazolines by 1,3-Dipolar Cycloaddition
Molecules, 1997 The cycloaddition of the chiral nitrile oxide 1 to 1-R-substituted 3,3-methylene-5,5-dimethyl-2-pyrrolidinones 2 (where R is H, n-butyl-, 1,1-dimethylethoxycarbonyl-, 1-methylethenyl- and acetyl-) proceeds regioselectively under the formation of ...
Peter Ertl +3 more
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Aryl nitrile oxide cycloaddition reactions in the presence of pinacol boronic acid ester
Beilstein Journal of Organic Chemistry, 2012 An aryl substrate with dual functionality consisting of a nitrile oxide and a pinacolyl boronate ester was prepared by mild hypervalent iodine oxidation (diacetoxyiodobenzene) of the corresponding aldoxime, without decomposition of the boronate ...
Sarah L. Harding +2 more
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Molecules, 2020 An architectural polymer containing hydrophobic isoxazole-based dendron and hydrophilic polyethylene glycol linear tail is prepared by a combination of the robust ZnCl2 catalyzed alkyne-nitrile oxide 1,3-dipolar cycloaddition and esterification chemistry.
Hossein Yazdani +4 more
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Selection of elastomeric membranes for the removal of volatile organics from water [PDF]
, 1993 A wide range of homogeneous elastomeric membranes has been prepared using dicumylperoxide as a general cross-linking agent. The membranes have been used for both equilibrium sorption measurements and steady-state pervaporation experiments to study ...
Mulder, M.H.V. +4 more
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A Convenient Synthesis of Novel Isoxazolidine and Isoxazole Isoquinolinones Fused Hybrids
Molecules, 2023 Isoxazolidine, isoxazole, and isoquinolinone rings are present in the structure of several natural products and/or pharmaceutically interesting compounds.
Konstantinos A. Ouzounthanasis +2 more
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Identification of an Active Site-bound Nitrile Hydratase Intermediate through Single Turnover Stopped-flow Spectroscopy [PDF]
, 2013 Stopped-flow kinetic data were obtained for the iron-type nitrile hydratase from Rhodococcus equi TG328-2 (ReNHase) using methacrylonitrile as the substrate.
Gumataotao, Natalie +3 more
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A Comprehensive Analysis of the Metal–Nitrile Bonding in an Organo-Diiron System
Molecules, 2021 Nitriles (N≡CR) are ubiquitous in coordination chemistry, yet literature studies on metal–nitrile bonding based on a multi-technique approach are rare. We selected an easily-available di-organoiron framework, containing both π-acceptor (CO, aminocarbyne)
Giulio Bresciani +5 more
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Hecheng xiangjiao gongye, 2023 Natural rubber (NR), styrene butadiene rubber (SBR), and carboxylated nitrile rubber (XNBR) were reinforced using graphene oxide (GO). The tensile properties and binding energy of three nanocomposites were studied through experiments and molecular ...
YANG Zi-fan1, MA Wen-xiu2, FU Quan-sheng1, WEN Yan-wei2, JIA Hong-bing1?鄢
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