Results 11 to 20 of about 10,038 (159)

Metal Catalysis Acting on Nitriles in Early Earth Hydrothermal Systems

open access: yesLife, 2023
Hydrothermal systems are areas in which heated fluids and organic molecules rush through basaltic material rich in metals and minerals. By studying malononitrile and acetonitrile, we examine the effects of metal and mineral nanoparticles on nitrile ...
Miranda Sturtz, Christopher House
doaj   +1 more source

Synthesis of Spiroisoxazolines by 1,3-Dipolar Cycloaddition

open access: yesMolecules, 1997
The cycloaddition of the chiral nitrile oxide 1 to 1-R-substituted 3,3-methylene-5,5-dimethyl-2-pyrrolidinones 2 (where R is H, n-butyl-, 1,1-dimethylethoxycarbonyl-, 1-methylethenyl- and acetyl-) proceeds regioselectively under the formation of ...
Peter Ertl   +3 more
doaj   +1 more source

Telodendrimer-Based Macromolecular Drug Design using 1,3-Dipolar Cycloaddition for Applications in Biology

open access: yesMolecules, 2020
An architectural polymer containing hydrophobic isoxazole-based dendron and hydrophilic polyethylene glycol linear tail is prepared by a combination of the robust ZnCl2 catalyzed alkyne-nitrile oxide 1,3-dipolar cycloaddition and esterification chemistry.
Hossein Yazdani   +4 more
doaj   +1 more source

A Convenient Synthesis of Novel Isoxazolidine and Isoxazole Isoquinolinones Fused Hybrids

open access: yesMolecules, 2023
Isoxazolidine, isoxazole, and isoquinolinone rings are present in the structure of several natural products and/or pharmaceutically interesting compounds.
Konstantinos A. Ouzounthanasis   +2 more
doaj   +1 more source

A Comprehensive Analysis of the Metal–Nitrile Bonding in an Organo-Diiron System

open access: yesMolecules, 2021
Nitriles (N≡CR) are ubiquitous in coordination chemistry, yet literature studies on metal–nitrile bonding based on a multi-technique approach are rare. We selected an easily-available di-organoiron framework, containing both π-acceptor (CO, aminocarbyne)
Giulio Bresciani   +5 more
doaj   +1 more source

Effect of graphene oxide on mechanical properties of different rubbers: Experiment and molecular simulation

open access: yesHecheng xiangjiao gongye, 2023
Natural rubber (NR), styrene butadiene rubber (SBR), and carboxylated nitrile rubber (XNBR) were reinforced using graphene oxide (GO). The tensile properties and binding energy of three nanocomposites were studied through experiments and molecular ...
YANG Zi-fan1, MA Wen-xiu2, FU Quan-sheng1, WEN Yan-wei2, JIA Hong-bing1?鄢
doaj   +1 more source

Synthesis of 3,4-Dibenzyltetrahydrofuran Lignans (9,9′-Epoxylignanes)

open access: yesMolecules, 2013
Different strategies for the racemic or enantiospecific total syntheses of plant and mammalian 3,4-dibenzyltetrahydrofuran lignans are reviewed and compared.
Kristiina Wähälä, Monika Pohjoispää
doaj   +1 more source

Preliminary Study on Effect of Chemical Composition Alteration on Elastic Recovery and Stress Recovery of Nitrile Gloves

open access: yesMATEC Web of Conferences, 2018
Nitrile gloves are widely used in the medical and automobile field due to its superiority in hypo-allergic component and chemical resistance over natural latex gloves.
Tan Kai Yang   +6 more
doaj   +1 more source

The Molecular Mechanism of the Formation of Four-Membered Cyclic Nitronates and Their Retro (3 + 2) Cycloaddition: A DFT Mechanistic Study

open access: yesMolecules, 2021
In the present work, the formation of the four-membered cyclic nitronates and the retro (3 + 2) cycloaddition (retro-32CA) reaction of the 4H-[1,2]oxazete 2-oxide were studied using the density functional theory method at the MPWB1K/6-311G(d,p ...
Agnieszka Kącka-Zych
doaj   +1 more source

[3+2] Cycloaddition to a Chiral 5-Methylene-1,3-dioxolan-4-one and Pyrolysis of the Spiro Adducts

open access: yesMolecules
The [3+2] cycloaddition chemistry of (2S)-5-methylene-2-t-butyl-1,3-dioxolan-4-one, derived from lactic acid, has been examined, and spiro adducts have been obtained with benzonitrile oxide, acetonitrile oxide, diazomethane and diphenyldiazomethane.
R. Alan Aitken   +2 more
doaj   +1 more source

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