Results 21 to 30 of about 29,634 (298)

The mechanism of pyridine hydrogenolysis on molybdenum-containing catalysts : III. Cracking, hydrocracking, dehydrogenation and disproportionation of pentylamine [PDF]

open access: yes, 1974
The conversion of pentylamine on a MoO3-Al2O3 catalyst was studied between 250 and 350 °C, at various hydrogen pressures. The reactions observed were cracking to pentene and ammonia, hydrocracking to pentane and ammonia, dehydrogenation to pentanimine ...
Mars, P., Sonnemans, J.
core   +2 more sources

Synthesis of 3,4-Dibenzyltetrahydrofuran Lignans (9,9′-Epoxylignanes)

open access: yesMolecules, 2013
Different strategies for the racemic or enantiospecific total syntheses of plant and mammalian 3,4-dibenzyltetrahydrofuran lignans are reviewed and compared.
Kristiina Wähälä, Monika Pohjoispää
doaj   +1 more source

The Molecular Mechanism of the Formation of Four-Membered Cyclic Nitronates and Their Retro (3 + 2) Cycloaddition: A DFT Mechanistic Study

open access: yesMolecules, 2021
In the present work, the formation of the four-membered cyclic nitronates and the retro (3 + 2) cycloaddition (retro-32CA) reaction of the 4H-[1,2]oxazete 2-oxide were studied using the density functional theory method at the MPWB1K/6-311G(d,p ...
Agnieszka Kącka-Zych
doaj   +1 more source

Nitrile-assistant eutectic electrolytes for cryogenic operation of lithium ion batteries at fast charges and discharges [PDF]

open access: yes, 2014
The charge/discharge characteristics of lithium ion batteries at low temperature (LT = -20 ??C) are enhanced by using ethylene carbonate (EC)-based electrolytes with the help of assistant solvents of nitriles. Conventional liquid electrolytes (e.g.
Abu-Lebdeh   +28 more
core   +1 more source

Preliminary Study on Effect of Chemical Composition Alteration on Elastic Recovery and Stress Recovery of Nitrile Gloves

open access: yesMATEC Web of Conferences, 2018
Nitrile gloves are widely used in the medical and automobile field due to its superiority in hypo-allergic component and chemical resistance over natural latex gloves.
Tan Kai Yang   +6 more
doaj   +1 more source

A study on selective transformation of norbornadiene into fluorinated cyclopentane-fused isoxazolines

open access: yesBeilstein Journal of Organic Chemistry, 2021
This work presents an examination of the selective functionalization of norbornadiene through nitrile oxide 1,3-dipolar cycloaddition/ring-opening metathesis (ROM)/cross-metathesis (CM) protocols. Functionalization of commercially available norbornadiene
Zsanett Benke   +2 more
doaj   +1 more source

"Effect of graphene oxide with different oxidation degrees on mechanical properties of carboxylated acrylonitrile-butadiene rubber: Experiment and molecular simulation"

open access: yesHecheng xiangjiao gongye, 2023
Graphene oxide(GO) with different oxidation degree was prepared and was used to strengthen carboxyl nitrile rubber(XNBR). And the tensile properties and binding energy were studied by experiments and molecular simulation.
FU Quan-sheng1, WEN Yan-wei2, LOU Yang2, ZHANG Xu-min1, JIA Hong-bing1 *
doaj   +1 more source

[3+2] Cycloaddition to a Chiral 5-Methylene-1,3-dioxolan-4-one and Pyrolysis of the Spiro Adducts

open access: yesMolecules
The [3+2] cycloaddition chemistry of (2S)-5-methylene-2-t-butyl-1,3-dioxolan-4-one, derived from lactic acid, has been examined, and spiro adducts have been obtained with benzonitrile oxide, acetonitrile oxide, diazomethane and diphenyldiazomethane.
R. Alan Aitken   +2 more
doaj   +1 more source

Conversion of Oximes to Carbonyl Compounds by Triscetylpyridinium Tetrakis(oxodiperoxotungsto) Phosphate (PCWP)-mediated Oxidation with Hydrogen Peroxide

open access: yesMolecules, 2008
Aromatic and aliphatic oximes have been deoximated in chloroform-water to the corresponding aldehydes with dilute hydrogen peroxide and triscetylpyridinium tetrakis (oxodiperoxotungsto) phosphate as catalyst.
Rosa M. Toscano   +4 more
doaj   +1 more source

Controllable cyanation of carbon-hydrogen bonds by zeolite crystals over manganese oxide catalyst

open access: yesNature Communications, 2017
Sustainable strategies for nitrile synthesis are needed. Here, the authors report an environmentally benign, selective heterogeneous catalyst for the synthesis of nitriles by the oxidative cyanation of carbon and hydrogen (C-H) bonds, which comprises ...
Liang Wang   +5 more
doaj   +1 more source

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