Results 31 to 40 of about 909,766 (269)
Controllable cyanation of carbon-hydrogen bonds by zeolite crystals over manganese oxide catalyst
Sustainable strategies for nitrile synthesis are needed. Here, the authors report an environmentally benign, selective heterogeneous catalyst for the synthesis of nitriles by the oxidative cyanation of carbon and hydrogen (C-H) bonds, which comprises ...
Liang Wang +5 more
doaj +1 more source
A Weinreb Nitrile Oxide and Nitrone for Cycloaddition
The cycloaddition of Weinreb amide functionalized nitrile oxide/nitrones with a range of dipolarophiles has been ...
Richard W. Franck (2704003) +1 more
core +1 more source
Site- and Regioselectivity of Nitrile Oxide-Allene Cycloadditions : DFT-Based Semiquantitative Predictions [PDF]
Nitrile oxide 1,3-dipolar cycloaddition to arylsulfonyl- and dialkylaminoallenes have been investigated within the framework of the Kohn-Sham density functional theory (DFT) at the B3LYP/6-31G(d,p) level. The hitherto-unexplained experimental behavior of
A. Ponti +3 more
core +1 more source
The aim of this work was to study the activity of several nanosized zinc oxides in the crosslinking of carboxylated nitrile elastomer (XNBR). In this article, we discuss the effect of zinc oxide nanoparticles with respect to their specific surface area ...
doaj +1 more source
Graphene oxide(GO) with different oxidation degree was prepared and was used to strengthen carboxyl nitrile rubber(XNBR). And the tensile properties and binding energy were studied by experiments and molecular simulation.
FU Quan-sheng1, WEN Yan-wei2, LOU Yang2, ZHANG Xu-min1, JIA Hong-bing1 *
doaj +1 more source
Elastomeric Core-Conductive Shell Slurry Additive Stabilizes High-Voltage NCM811 Cathodes via Mechanical-Electrical Dual Regulation. [PDF]
A core‐shell ASA slurry additive constructs a mosaic‐like interface on high‐voltage NCM811 cathodes. This architecture decouples interfacial functions: the elastomeric core buffers mechanical stress to prevent microcracking, while the conductive shell facilitates rapid ion/electron transport, enabling mechanical‐electrical dual regulation and enhanced ...
Duan J +16 more
europepmc +2 more sources
Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions
We describe examples of highly regio- and enantioselective nitrile oxide cycloadditions to unsaturated alkenes using substoichiometric amounts of a chiral Lewis acid.
Mukund P. Sibi (1633159) +2 more
core +1 more source
Synthetic approaches to biologically active sulfonates and sulfonamides [PDF]
This research describes the scope of 1,3-dipolar cycloaddition between selected 1,3-dipoles (nitrile oxide/nitrone) and dipolarophiles (PFP ethenesulfonate/PFP-1-bromoethenesulfonate). Nitrile oxide cycloaddition with PFP-1-bromoethenesulfonate furnished
Lee, C.C.
core
Reactions of β-azolyl enamines and nitrile oxides were studied by both experimental and theoretical methods. (E)-β-(4-Nitroimidazol-5-yl), (5-nitroimidazol-4-yl) and isoxazol-5-yl enamines smoothly react regioselectively at room temperature in dioxane ...
Ilya V. Efimov +10 more
doaj +1 more source
Abruptly changing from aerobic to anaerobic conditions (sudden anaerobization) induced growth inhibition and a significant increase in intracellular labile ferrous iron in the aerotolerant anaerobe Amphibacillus xylanus. We found that free flavins mediate efficient electron transfer from NADH to ferric iron under anaerobic conditions, suggesting that ...
Shinya Kimata +13 more
wiley +1 more source

