Results 31 to 40 of about 909,766 (269)

Controllable cyanation of carbon-hydrogen bonds by zeolite crystals over manganese oxide catalyst

open access: yesNature Communications, 2017
Sustainable strategies for nitrile synthesis are needed. Here, the authors report an environmentally benign, selective heterogeneous catalyst for the synthesis of nitriles by the oxidative cyanation of carbon and hydrogen (C-H) bonds, which comprises ...
Liang Wang   +5 more
doaj   +1 more source

A Weinreb Nitrile Oxide and Nitrone for Cycloaddition

open access: yes, 2016
The cycloaddition of Weinreb amide functionalized nitrile oxide/nitrones with a range of dipolarophiles has been ...
Richard W. Franck (2704003)   +1 more
core   +1 more source

Site- and Regioselectivity of Nitrile Oxide-Allene Cycloadditions : DFT-Based Semiquantitative Predictions [PDF]

open access: yes, 2017
Nitrile oxide 1,3-dipolar cycloaddition to arylsulfonyl- and dialkylaminoallenes have been investigated within the framework of the Kohn-Sham density functional theory (DFT) at the B3LYP/6-31G(d,p) level. The hitherto-unexplained experimental behavior of
A. Ponti   +3 more
core   +1 more source

The effect of zinc oxide nanoparticle morphology on activity in crosslinking of carboxylated nitrile elastomer

open access: yeseXPRESS Polymer Letters, 2009
The aim of this work was to study the activity of several nanosized zinc oxides in the crosslinking of carboxylated nitrile elastomer (XNBR). In this article, we discuss the effect of zinc oxide nanoparticles with respect to their specific surface area ...
doaj   +1 more source

"Effect of graphene oxide with different oxidation degrees on mechanical properties of carboxylated acrylonitrile-butadiene rubber: Experiment and molecular simulation"

open access: yesHecheng xiangjiao gongye, 2023
Graphene oxide(GO) with different oxidation degree was prepared and was used to strengthen carboxyl nitrile rubber(XNBR). And the tensile properties and binding energy were studied by experiments and molecular simulation.
FU Quan-sheng1, WEN Yan-wei2, LOU Yang2, ZHANG Xu-min1, JIA Hong-bing1 *
doaj   +1 more source

Elastomeric Core-Conductive Shell Slurry Additive Stabilizes High-Voltage NCM811 Cathodes via Mechanical-Electrical Dual Regulation. [PDF]

open access: yesAdv Sci (Weinh)
A core‐shell ASA slurry additive constructs a mosaic‐like interface on high‐voltage NCM811 cathodes. This architecture decouples interfacial functions: the elastomeric core buffers mechanical stress to prevent microcracking, while the conductive shell facilitates rapid ion/electron transport, enabling mechanical‐electrical dual regulation and enhanced ...
Duan J   +16 more
europepmc   +2 more sources

Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions

open access: yes, 2016
We describe examples of highly regio- and enantioselective nitrile oxide cycloadditions to unsaturated alkenes using substoichiometric amounts of a chiral Lewis acid.
Mukund P. Sibi (1633159)   +2 more
core   +1 more source

Synthetic approaches to biologically active sulfonates and sulfonamides [PDF]

open access: yes, 2010
This research describes the scope of 1,3-dipolar cycloaddition between selected 1,3-dipoles (nitrile oxide/nitrone) and dipolarophiles (PFP ethenesulfonate/PFP-1-bromoethenesulfonate). Nitrile oxide cycloaddition with PFP-1-bromoethenesulfonate furnished
Lee, C.C.
core  

Combined experimental and theoretical studies of regio- and stereoselectivity in reactions of β-isoxazolyl- and β-imidazolyl enamines with nitrile oxides

open access: yesBeilstein Journal of Organic Chemistry, 2016
Reactions of β-azolyl enamines and nitrile oxides were studied by both experimental and theoretical methods. (E)-β-(4-Nitroimidazol-5-yl), (5-nitroimidazol-4-yl) and isoxazol-5-yl enamines smoothly react regioselectively at room temperature in dioxane ...
Ilya V. Efimov   +10 more
doaj   +1 more source

Sudden anaerobization in Amphibacillus xylanus increases intracellular labile ferrous iron and inhibits cell growth

open access: yesFEBS Open Bio, EarlyView.
Abruptly changing from aerobic to anaerobic conditions (sudden anaerobization) induced growth inhibition and a significant increase in intracellular labile ferrous iron in the aerotolerant anaerobe Amphibacillus xylanus. We found that free flavins mediate efficient electron transfer from NADH to ferric iron under anaerobic conditions, suggesting that ...
Shinya Kimata   +13 more
wiley   +1 more source

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