Results 51 to 60 of about 14,073 (324)
Advanced Materials, EarlyView.Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje +7 more
wiley +1 more source
Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers
Advanced Materials, EarlyView.Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez +9 more
wiley +1 more source
Hecheng xiangjiao gongyeThree types of metal oxide, magnesium oxide(MgO), zinc oxide(ZnO) and aluminium oxide(Al2O3), were added into carboxylated nitrile rubber (XNBR) to prepared XNBR/metal oxide composites, the properties of which, such as interactions between metal ions and
LUO Jiang1, XIE Qing-jun1, YANG Shu-yan2
doaj +1 more source
Inverse electron-demand 1,3-dipolar cycloaddition of nitrile oxide with common nitriles leading to 3-functionalized 1,2,4-oxadiazoles [PDF]
, 2011 A carbamoyl-substituted nitrile oxide was generated upon treatment of easily available 2-methyl-4-nitro-3-isoxazolin-5(2H)-one with THF (not dried); the reaction proceeded efficiently even in the absence of any special reagents and reaction conditions ...
Shotaro Hirao +15 more
core +1 more source
Nanomaterial Integration at Liquid–Liquid Interfaces for Green Catalysis
Advanced Materials, EarlyView.Functional nanomaterials assembled at liquid–liquid interfaces create dual‐role platforms serving as emulsion stabilizers and catalytic sites, offering enhanced reaction kinetics with improved catalyst recovery and recyclability. This review examines design strategies, structure‐performance relationships, and industrial implementation prospects of ...
Bokgi Seo +6 more
wiley +1 more source
Ethyl 5-(4-Bromophenyl)-4-methyl-1H-pyrrole-2-carboxylate
Molbank, 2017 This note describes a sequence converting an oxime-substituted pyrrolidine into a trisubstituted pyrrole structure. The synthetic route is based on a double chlorination of the pyrrolidine substrate followed by the base induced formation of both an imine
Marcus Baumann, Ian R. Baxendale
doaj +1 more source
Advanced Materials, EarlyView.By designing a P/N‐ and π–π interacting biphenyl‐containing diol as hard segments but side groups, a strong, tough, fire‐extinguishing and self‐healing elastomer is developed, demonstrating a break strain of ∼2500%, a toughness of 379 MJ/m3 and a tensile strength of 46 MPa, as well as a healing efficiency of 95% (tensile strength) and 99% (break strain)
Yijiao Xue +11 more
wiley +1 more source
, 2016 The expedient and fully stereocontrolled synthesis of epothilones A and B are described. The routes described make extensive study of nitrile oxide cycloadditions as surrogates for aldol addition reactions and have led to the realization of a highly ...
Jeffrey W. Bode (1331538) +1 more
core +1 more source
Advanced Materials, EarlyView.A dual‐additive electrolyte strategy is developed to address the hydrolysis of I+ in the aqueous electrolytes. The steric‐hindrance effect of TES− effectively shields I+ from nucleophilic attacks by hydroxyl groups, facilitating the reversible I−/I0/I+ conversion with four‐electron transfer.
Shuai Wang +8 more
wiley +1 more source
Atropisomerism-Induced Facial Selectivity in Nitrile Oxide Cycloadditions with 5-Methylenehydantoins
, 2016 N-Aryl 5-methylenehydantoins underwent nitrile oxide cycloaddition with benzonitrile oxide to give 5-spiro isoxazoline adducts with complete regioselectivity.
Anna M. Said (2175616) +1 more
core +2 more sources