Results 51 to 60 of about 909,766 (269)
Solid phase strain promoted “click” modification of DNA via [3+2]-nitrile oxide–cyclooctyne cycloadditions [PDF]
, 2011 Biocompatible, strain promoted cyclooctyne–nitrile oxide click chemistry is demonstrated as a rapid and reliable method for DNA conjugation on the solid ...
Ishwar Singh +3 more
core +3 more sources
Molecules, 2019 The [3 + 2] cycloaddition (32CA) reaction of an α-santonin derivative, which has an exocyclic C⁻C double bond, with p-bromophenyl nitrile oxide yielding only one spiroisoxazoline, has been studied within the molecular electron density theory ...
Luis R. Domingo +2 more
doaj +1 more source
Hydroxyl-directed nitrile oxide cycloaddition reactions with cyclic allylic alcohols.
, 2007 Diastereoselective cycloaddition reactions between a nitrile oxide and cyclic allylic alcohols are reported. The products isolated are densely functionalized building blocks that are not otherwise easily accessed with existing methods and concepts ...
Becker N, Carreira EM
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Optical Detection of Cellular Signals at Material Interfaces
Advanced Healthcare Materials, EarlyView.Emerging functional materials are transforming optical detection of cellular signals. This review highlights optical techniques that exploit the unique optical properties of diverse materials to detect and quantify cellular electrical, chemical, and mechanical signals, and discusses key opportunities and challenges.
Xuchen Ren +5 more
wiley +1 more source
Hecheng xiangjiao gongyeThree types of metal oxide, magnesium oxide(MgO), zinc oxide(ZnO) and aluminium oxide(Al2O3), were added into carboxylated nitrile rubber (XNBR) to prepared XNBR/metal oxide composites, the properties of which, such as interactions between metal ions and
LUO Jiang1, XIE Qing-jun1, YANG Shu-yan2
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STEREOSELECTIVE INTRAMOLECULAR NITRILE OXIDE CYCLOADDITION TO CHIRAL ALLYL ETHERS
, 1987 Intramolecular nitrile oxide cycloaddition reactions on (Z)- and (E)-chiral allyl ethers occur with poor to good stereoselectivity (diastereoisomeric ratios up to 86: 14), which depends on the double bond configuration as well as on steric and ...
M. CINQUINI +3 more
core +1 more source
Bioinspired Adaptive Sensors: A Review on Current Developments in Theory and Application
Advanced Materials, EarlyView.This review comprehensively summarizes the recent progress in the design and fabrication of sensory‐adaptation‐inspired devices and highlights their valuable applications in electronic skin, wearable electronics, and machine vision. The existing challenges and future directions are addressed in aspects such as device performance optimization ...
Guodong Gong +12 more
wiley +1 more source
Ethyl 5-(4-Bromophenyl)-4-methyl-1H-pyrrole-2-carboxylate
Molbank, 2017 This note describes a sequence converting an oxime-substituted pyrrolidine into a trisubstituted pyrrole structure. The synthetic route is based on a double chlorination of the pyrrolidine substrate followed by the base induced formation of both an imine
Marcus Baumann, Ian R. Baxendale
doaj +1 more source
lntramolecular Nitrile Oxide Cycloaddition (INOC)of Substituted Amido-Oximes
, 1996 Functionalized enantiomerically pure 3,4-dehydropyrrolidin-2-one and 1,2-dehydropyrrolizidin-3-one systems have been achieved by intramolecular nitrile oxide cycloaddition, starting from enamido-oximes, and by subsequent reduction of the obtained ...
Librando V. +5 more
core +1 more source
Inverse electron-demand 1,3-dipolar cycloaddition of nitrile oxide with common nitriles leading to 3-functionalized 1,2,4-oxadiazoles [PDF]
, 2011 A carbamoyl-substituted nitrile oxide was generated upon treatment of easily available 2-methyl-4-nitro-3-isoxazolin-5(2H)-one with THF (not dried); the reaction proceeded efficiently even in the absence of any special reagents and reaction conditions ...
Shotaro Hirao +15 more
core +1 more source