Cycloaddition reactions of nitrosoalkenes, azoalkenes and nitrile oxides mediated by hydrotalcite
Americo Lemos, João Paulo Lourenço
doaj +1 more source
Challenges in Elucidating the Free Energy Scheme of the Laccase Catalyzed Reduction of Oxygen
Bioinorganic chemistry: High potential variants of the multicopper enzyme laccase have a remarkably low overpotential for the oxygen reduction reaction (ORR). Understanding the precise underlying principles are potentially of great value in light of the energy transition wherein the ORR plays a crucial role.
Daan den Boer+3 more
wiley +1 more source
Ruthenium-catalyzed cycloadditions of 1-haloalkynes with nitrile oxides and organic azides: synthesis of 4-haloisoxazoles and 5-halotriazoles. [PDF]
Oakdale JS, Sit RK, Fokin VV.
europepmc +1 more source
Enantioselective 1,3-Dipolar Cycloadditions of α-Methylene Lactams to Construct Spirocycles. [PDF]
Nishiura Y+3 more
europepmc +1 more source
Carbocatalysis: The synthesized basic carbocatalyst showed high performance in two different base‐catalyzed reactions namely ϵ‐caprolactone ring‐opening polymerization to biodegradable polycaprolactone, as well as isosorbide transesterification to isosorbide bis(methyl carbonate).
Majd Al‐Naji+3 more
wiley +1 more source
Photocatalytic Generation of a Ground‐State Electron Donor Through Water Activation
This study presents catalytically generated phosphine oxide radical anions, derived from commercial phosphines and water as potent single‐electron reductants capable of reducing electron‐rich aryl chlorides at potentials as low as −3.3 V (vs. SCE). Cyclic voltammetry studies and DFT calculations offer insights into these P‐based ground‐state electron ...
Maxim‐Aleksa Wiethoff+2 more
wiley +1 more source
Isoxazolodihydropyridinones: 1,3-dipolar cycloaddition of nitrile oxides onto 2,4-dioxopiperidines. [PDF]
Coffman KC+3 more
europepmc +1 more source
Allenylidene Phosphonium Ion: An Isoelectronic Phosphorus Analogue of [3]Cumulene
We report the first isolobal and isoelectronic incorporation of a phosphorus atom into a [3]cumulene. This trigonal planar phosphonium allenylidene demonstrates exceptional Lewis acidity via a π* acceptor orbital and exhibits unique reactivity through a reversible intramolecular dearomative [2 + 2] cycloaddition reaction.
Lucas C. Torres+8 more
wiley +1 more source
1,3-Dipolar Cycloadditions of Nitrones and Nitrile Oxides. [PDF]
Chang, Yau-min
core +2 more sources
Advances in isoxazole chemistry and their role in drug discovery. [PDF]
Martis GJ, Gaonkar SL.
europepmc +1 more source