State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production
Chemistry – A European Journal, EarlyView.The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin +3 more
wiley +1 more source
Cyanoacetamidobetaine-A Zwitterionic Nitrile Derivative. [PDF]
ChemistryOpenDuan P +5 more
europepmc +1 more source
Low‐Temperature Initiation Enhances HCN and NH3 Formation From Methane and NO Over Pt/Al2O3
Chemistry – A European Journal, EarlyView.Hydrogen cyanide (HCN) was formed from CH4 and NO over Pt/Al2O3 at low temperatures. Increasing NO concentration and optimizing reaction‐start conditions significantly enhanced HCN yield. In situ FTIR and DXAFS measurements revealed that dynamically balancing Pt‑CO and Pt‑CN surface species, particularly their desorption under temperature‑swing ...
Emika Yamashita +3 more
wiley +1 more source
Controlled transfer-reduction of functional groups with ethanol by their interaction strength with the oxygen vacancies. [PDF]
Nat CommunYuan Z +6 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Over the past decade, the interest in azetidines has continuously risen, by virtue of their highly appealing pharmaceutical properties. Monocyclic, spirocyclic, and bridged azetidines can be accessed by leveraging 1‐azabicyclo[1.1.0]butanes as precursors.
Yuri Gelato +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi +8 more
wiley +1 more source
Synthesis and <i>in silico</i> insights of some tetrahydrobenzothienopyrimidine candidates as multi-target antimicrobial, antiproliferative, and antiviral agents. [PDF]
RSC AdvElgubbi AS +4 more
europepmc +1 more source
Titanium‐Catalyzed Diastereoselective Keto‐ and Iminonitrile Cyclizations
Chemistry – A European Journal, EarlyView.The titanium(III)‐catalyzed diastereoselective cyclization of readily‐available substituted ketonitriles gives cyclopentanones in good yield and stereoselectivity. Subsequent 1,2‐addition allows the preparation of cyclopentyls with three consecutive stereocenters.
Christoph Kern +4 more
wiley +1 more source
Nickel‐Catalyzed Reductive Cross‐Coupling of Xanthate Esters With Aryl and Alkenyl Iodides
Chemistry – A European Journal, EarlyView.A nickel‐catalyzed reductive cross‐coupling of xanthate esters and aryl/alkenyl iodides is reported without the need for separate activators for the xanthate esters. The reaction utilizes a relatively low catalyst loading. Diarylmethanes with a good functional group variety can thus be synthesized indirectly from the corresponding benzylic alcohols ...
Felix Vöhringer +4 more
wiley +1 more source
Synthesis and characterization of Ni-MOF and CoFe<sub>2</sub>O<sub>4</sub>/Ni-MOF as reusable heterogeneous catalysts for the synthesis of 5-substituted 1H-tetrazole. [PDF]
Sci RepFaizy M, Molaei S, Ghadermazi M.
europepmc +1 more source