Results 141 to 150 of about 871,548 (248)

Modular Access to α‐Tertiary Amines: Electrochemical Tandem Di‐Functionalization of Olefins With Ammonia Surrogates and Amino Acids

open access: yesAngewandte Chemie, EarlyView.
A metal‐ and oxidant‐free electrochemical multicomponent di‐functionalization strategy that rapidly converts 1,1‐disubstituted alkenes into α‐tertiary primary amines with simultaneous installation of bio‐relevant sulfur or selenium motifs was devised for late‐stage functionalization. ABSTRACT Quaternary carbon centers, especially those bearing nitrogen,
Adrija Ghosh   +4 more
wiley   +2 more sources

Nitrogen Radical Photocatalysed Reduction of Nitrous Oxide

open access: yesAngewandte Chemie, EarlyView.
This work offers the first example of reduction of the potent greenhouse gas N2O to the benign products N2 and O(Bpin)2 using a nitrogen‐based catalyst. The active catalyst is shown to be a nitrogen‐based radical which operates under photocatalytic conditions.
Reece Lister‐Roberts   +2 more
wiley   +2 more sources

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

open access: yesAngewandte Chemie, EarlyView.
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo   +14 more
wiley   +2 more sources

A radical-polar crossover approach to complex nitrogen heterocycles via the triplet state. [PDF]

open access: yesChem
Lockhart Z   +6 more
europepmc   +1 more source

Biological and Teratogenic Evaluations of Nitrogen Heterocycles for Anticancer Therapy. [PDF]

open access: yesPharmaceuticals (Basel)
Dos Santos JC   +12 more
europepmc   +1 more source

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