A metal‐ and oxidant‐free electrochemical multicomponent di‐functionalization strategy that rapidly converts 1,1‐disubstituted alkenes into α‐tertiary primary amines with simultaneous installation of bio‐relevant sulfur or selenium motifs was devised for late‐stage functionalization. ABSTRACT Quaternary carbon centers, especially those bearing nitrogen,
Adrija Ghosh +4 more
wiley +2 more sources
Energetic and Geometric Characteristics of the Substituents: Part 2: The Case of NO2, Cl, and NH2 Groups in Their Mono-Substituted Derivatives of Simple Nitrogen Heterocycles. [PDF]
Wieczorkiewicz PA +2 more
europepmc +1 more source
Nitrogen Radical Photocatalysed Reduction of Nitrous Oxide
This work offers the first example of reduction of the potent greenhouse gas N2O to the benign products N2 and O(Bpin)2 using a nitrogen‐based catalyst. The active catalyst is shown to be a nitrogen‐based radical which operates under photocatalytic conditions.
Reece Lister‐Roberts +2 more
wiley +2 more sources
Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo +14 more
wiley +2 more sources
Prescribed drugs containing nitrogen heterocycles: an overview. [PDF]
Heravi MM, Zadsirjan V.
europepmc +1 more source
A radical-polar crossover approach to complex nitrogen heterocycles via the triplet state. [PDF]
Lockhart Z +6 more
europepmc +1 more source
Microwave assisted synthesis of five membered nitrogen heterocycles. [PDF]
Meera G +3 more
europepmc +1 more source
Biological and Teratogenic Evaluations of Nitrogen Heterocycles for Anticancer Therapy. [PDF]
Dos Santos JC +12 more
europepmc +1 more source
An unusual formal migrative cycloaddition of aurone-derived azadienes: synthesis of benzofuran-fused nitrogen heterocycles. [PDF]
Feng Q, Wu A, Zhang X, Song L, Sun J.
europepmc +1 more source
Privileged nitrogen heterocycles in anticancer drug discovery: recent advances on imidazole, indole, and pyrimidine scaffolds. [PDF]
Govindarajan M +6 more
europepmc +1 more source

