(S)-N-[(1S,2S)-2-Benzylamino-1-(4-hydroxyphenyl)-3-methylbutyl]-1,1-dimethylethane-2-sulfinamide
The title compound, C22H32N2O2S, was obtained by dehydroxylation and deacetylation of 4-{(1S,2S)-2-(benzylhydroxyamino)-3-methyl-1-[(S)-2-methylpropane-2-sulfinylamino]butyl}phenyl acetate, which was derived from reductive crosslinking of nitrone with N ...
Chun Shen
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Reaction of enantiopure 3,4-dialkoxy-pyrroline N-oxides with benzyne affords the expected tetrahydrobenzo[d]pyrrolo[1,2-b]isoxazoles along with an unexpected 2,3-disubstitued-N-phenyl-pyrrole derived from an unprecedented rearrangement of the adduct of ...
Franca M. Cordero +3 more
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Theoretical analysis of mechanism, regio- and stereoselectivity of 1, 3-dipolar cycloaddition of cyclic nitrone and substituted alkenes by DFT method. [PDF]
Samir Bouacha
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Polyalkoxy Nitrones as Chiral Building Blocks in Asymmetric Synthesis
Optically active nitrones derived from both aldoses and dialdoses add metallated heterocycles in a stereocontrolled way depending on the nature of the Lewis acid used as a precomplexing agent of the nitrone.
Tomás Tejero, Pedro Merino
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An N-Allylglyoxylamide Based Bioorthogonal Nitrone Trap [PDF]
Daniel J. Lee +6 more
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Selective and Reversible 1,3-Dipolar Cycloaddition of 2-(2-Oxoindoline-3-ylidene)acetates with Nitrones in the Synthesis of Functionalized Spiroisoxazolidines [PDF]
Dmitriy D. Karcev +6 more
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Nitrone Cycloaddition Route to the 1β-Methylcarbapenem Key Intermediate [PDF]
Yoshio Ito +2 more
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Neurodegenerative diseases affect millions worldwide, posing significant challenges to public health. Oxidative stress and increased caspase-3 activity are key features in the development and progression of neurological disorders leading to neuronal ...
Saira Cancela +5 more
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Anionic Inverse Electron‐Demand 1,3‐Dipolar Cycloaddition of Nitrones with Ynolates. Facile Stereoselective Synthesis of 5‐Isoxazolidinones Leading to β‐Amino Acids. [PDF]
Mitsuru Shindo +3 more
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Electronic properties of the nitrone substituent. Stabilization of benzylic carbocations [PDF]
Xavier Creary, Kresna Hartandi
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