A Bifunctional Spin Label for Ligand Recognition on Surfaces. [PDF]
In situ monitoring of biomolecular recognition, especially at surfaces, still presents a significant technical challenge. Electron paramagnetic resonance (EPR) of biomolecules spin-labeled with nitroxides can offer uniquely sensitive and selective ...
Bartczak +31 more
core +2 more sources
Interplay between lattice, orbital, and magnetic degrees of freedom in the chain-polymer Cu(II) breathing crystals [PDF]
The chain-polymer Cu(II) breathing crystals C21H19CuF12N4O6 were studied using the x-ray diffraction and ab initio band structure calculations. We show that the crystal structure modification at T=146 K, associated with the spin crossover transition ...
G. V. Romanenko +8 more
core +1 more source
Free radicals, particularly reactive oxygen species (ROS), are involved in various pathologies, injuries related to radiation, ischemia-reperfusion or ageing.
Goran Bačić +2 more
doaj +1 more source
The secondary structure of apolipoprotein A-I on 9.6-nm reconstituted high-density lipoprotein determined by EPR spectroscopy. [PDF]
Apolipoprotein A-I (ApoA-I) is the major protein component of high-density lipoprotein (HDL), and is critical for maintenance of cholesterol homeostasis.
Borja, Mark S +5 more
core +1 more source
Charge transfer processes are investigated in p‐type organic electrode materials utilizing stable organic radicals incorporated in a conjugated backbone. Molecular dynamics simulations and time‐dependent density functional theory calculations allow us to evaluate charge transfer states as well as the underlying structure–property relationships. Organic
Clara Zens +3 more
wiley +1 more source
The reactions of 3-isoselenocyanato-2,2,5,5-tetramethylpyrrolidine-1-oxyl, 3-isoselenocyanatomethyl-2,2,5,5-tetramethyl-3-pyrrolidine-1-oxyl, and 4-isoselenocyanato-2,2,6,6-tetramethylpiperidine-1-oxyl with selected amines and alcohols give the ...
Jerzy Zakrzewski +5 more
doaj +1 more source
Can radiosensitivity associated with defects in DNA repair be overcome by mitochondrial-targeted antioxidant radioprotectors [PDF]
Radiation oncologists have observed variation in normal tissue responses between patients in many instances with no apparent explanation. The association of clinical tissue radiosensitivity with specific genetic repair defects (Wegner's syndrome, Ataxia ...
Berhane, H +7 more
core +1 more source
Anticancer Efficacy of a Difluorodiarylidenyl Piperidone (HO-3867) in Human Ovarian Cancer Cells and Tumor Xenografts [PDF]
The purpose of this study was to evaluate the anticancer potency and mechanism of a novel difluorodiarylidenyl piperidone (H-4073) and its N-hydroxypyrroline modification (HO-3867) in human ovarian cancer.
Ahmed, Shabnam +10 more
core +1 more source
Új, diamágneses és paramágneses fluoreszcens molekulák szintézise és alkalmazása = Synthesis and application of new diamagnetic and paramagnetic fluorophores [PDF]
Új, kettősen (spin és fluoreszcens) jelölő reagenseket szintetizáltunk danzil-, BODIPY- kumarin-, pirén és benzodiazafurazán típusú fluorofórokkal. A danzil fluorofórt sikeresen alkalmazták a növényfiziológiai kutatásokban a stresszfolyamatokban képződő
Hideg, Kálmán +5 more
core
Synthesis of nitroxyl radical by direct nucleophilic functionalization of a C-H bond in the azadiene systems [PDF]
Cyclic dinitrones underwent nucleophilic substitution of the hydrogen atom in the reaction with a paramagnetic carbanion, the lithium derivative of 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide, to give polyfunctional nitronyl nitroxyls ...
Bogomyakov, A. S. +8 more
core +1 more source

