NV Center Electron Paramagnetic Resonance of a Single Nanodiamond Attached to an Individual Biomolecule [PDF]
A key limitation of electron paramagnetic resonance (EPR), an established and powerful tool for studying atomic-scale biomolecular structure and dynamics is its poor sensitivity, samples containing in excess of 10^12 labeled biomolecules are required in typical experiments.
arxiv +1 more source
High-field optically detected nuclear magnetic resonance in GaAs [PDF]
A method for high-field optically detected nuclear magnetic resonance (ODNMR) is developed sensitive to 10**8 nuclei. Nuclear spin transitions are induced using a radio frequency coil and detected through Faraday rotation spectroscopy. Unlike conventional ODNMR, which is limited to low fields and relies on the measurement of time-averaged luminescence ...
arxiv +1 more source
Utility of methyl side chain probes for solution NMR studies of large proteins
Selective isotopic labeling of methyl side chain groups in proteins and other biomolecules, combined with advances in perdeuteration, new pulse sequences, and high field spectrometers with cryogenic probes, has revolutionized the field of solution ...
Andrew C. McShan
doaj
Artificial Receptor in Synthetic Cells Performs Transmembrane Activation of Proteolysis
Transmembrane signaling is the hallmark of living cells and is among the highest challenges for the design of synthetic cells. Herein, an artificial receptor based on the chemistry of self‐immolative linkers is used to communicate information across the lipid bilayer, for transmembrane activation of enzymatic activity. Abstract The design of artificial,
Ane Bretschneider Søgaard+7 more
wiley +1 more source
lrSVD: An efficient imputation algorithm for incomplete high‐throughput compositional data
Abstract Compositional methods have been successfully integrated into the chemometric toolkit to analyse and model different types of data generated by modern high‐throughput technologies. Within this compositional framework, the focus is put on the relative information conveyed in the data by using log‐ratio coordinate representations.
Javier Palarea‐Albaladejo+3 more
wiley +1 more source
Hydrolyzed protein diets are extensively used to treat chronic enteropathy (CE) in cats. However, the biochemical effects of such a diet on feline CE have not been characterized.
Aarti Kathrani+3 more
doaj +1 more source
Spatial Imaging and Mechanical Control of Spin Coherence in Strained GaAs Epilayers [PDF]
The effect of uniaxial tensile strain on spin coherence in n-type GaAs epilayers is probed using time-resolved Kerr rotation, photoluminescence, and optically-detected nuclear magnetic resonance spectroscopies. The bandgap, electron spin lifetime, electron g-factor, and nuclear quadrupole splitting are simultaneously imaged over millimeter scale areas ...
arxiv +1 more source
Two-dimensional terahertz magnetic resonance spectroscopy of collective spin waves [PDF]
Nonlinear manipulation of nuclear and electron spins is the basis for all advanced methods in magnetic resonance including multidimensional nuclear magnetic and electron spin resonance spectroscopies, magnetic resonance imaging, and in recent years, quantum control over individual spins.
arxiv +1 more source
Chiral Engineered Biomaterials: New Frontiers in Cellular Fate Regulation for Regenerative Medicine
Chiral engineered biomaterials can selectively influence cell behaviors in regenerative medicine. This review covers chiral engineered biomaterials in terms of their fabrication methods, cellular response mechanisms, and applications in directing stem cell differentiation and tissue function.
Yuwen Wang+5 more
wiley +1 more source
E‐selective Semi‐hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex
Two do the job: Diruthenium hydrido carbonyl complexes bound to a PNNP expanded pincer ligand are described. Deprotonation of the methylene linkers enables cooperative activation of H2 allowing for the E‐selective semi‐hydrogenation of internal alkynes under mild conditions. Initial insights into the mechanism and the isolation of a deactivated species
Cody B. van Beek+7 more
wiley +1 more source