The maison europeenne des procedes innovants (MEPI),an example of piloting and industrial demonstration facility for the green process engineering [PDF]
, 2009 . Economical, energy savings and environmental challenges require an actual technological breakthrough in process engineering, aiming with productivity, product quality, safety and reliability objectives.
Caze, Pierre +5 more
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Vibrational signatures of gaseous Meisenheimer complexes bonded at carbon and nitrogen [PDF]
, 2017 Anionic adducts of 1,3,5-trinitrobenzene (TNB) with deprotonated pyrrolidine (Pyr), imidazole (Im), acetone (Ac) and acetylacetone (Acac) have been delivered into the gas phase by electrospray ionization.The so-formed ions, TNB-Nu−(Nu = Pyr, Im, Ac, Acac)
Chiavarino, Barbara +2 more
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International Journal of Electrochemical Science, 2011 Chlorambucil is one of anticancer drug that has been mainly used in the treatment of cancer disease. It is an alkylating agent and can be given orally.
Henry Setiyanto +4 more
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The Human Ntn-Hydrolase Superfamily: Structure, Functions and Perspectives
Cells, 2022 N-terminal nucleophile (Ntn)-hydrolases catalyze the cleavage of amide bonds in a variety of macromolecules, including the peptide bond in proteins, the amide bond in N-linked protein glycosylation, and the amide bond linking a fatty acid to sphingosine ...
Arne Linhorst, Torben Lübke
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Kinetics and Mechanism of Hydrolysis of Benzimidazolylcarbamates [PDF]
, 2007 Synthesis of new 2-aminobenzimidazole-1-carbamates was accomplished by carbamoylation of 2-aminobenzimidazole using different substituted phenyl chloroformates. The aqueous hydrolysis of the new compounds was examined in the pH range 1-13 at 25 oC.
Corte Real, M. +4 more
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Palladium-catalyzed formation of oxazolidinones from biscarbamates: a mechanistic study
Beilstein Journal of Organic Chemistry, 2011 Oxazolidinones can be synthesized starting from cyclic biscarbamates via a palladium-catalyzed reaction. To test the proposed mechanism of this reaction, first, bicyclonorcarene endoperoxides derived from cyano and carbomethoxy cycloheptatrienes were ...
Benan Kilbas, Metin Balci
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Compare and contrast the reaction coordinate diagrams for chemical reactions and cytoskeletal force generators. [PDF]
, 2013 Reaction coordinate diagrams are used to relate the free energy changes that occur during the progress of chemical processes to the rate and equilibrium constants of the process.
Scholey, Jonathan M
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Тонкие химические технологии, 2009 Potential energy surfaces of gas-phased synchronous addition of HF to acetylene and methylacetylene. A non-empirical Harthree-Fock-Ruthane method (Gaussian-03, G-31++G** basis) with electronic correlation consideration in MP2 approximation (Moeller ...
Yu. B. Kirillov, N. M. Klimenko
doaj
Quantitative representation of reactivity, selectivity and site activation concepts in organic chemistry [PDF]
, 2004 Indexación: ScieloReactivity, selectivity and site activation are classical concepts in chemistry which are amenable to quantitative representation, in terms of static global, local and non local density response functions.
Contreras, Renato R. +2 more
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Carbocationoids, a concept for controlling highly reactive cationic species
Communications ChemistryCarbocations, which are positively charged highly electrophilic intermediates, are efficacious for the direct alkylation of low-reactive nucleophiles. The utilization of carbocations in SN1 reactions relies on the activation of their precursors in the ...
Hikaru Fujita +6 more
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