Results 41 to 50 of about 23,008 (222)

Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices

Advanced Functional Materials, EarlyView.
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies, Bin Han, Paolo Samorì   +2 more
wiley   +1 more source

Engineering Metal‐Pocket Cooperativity in Single‐Atom COF Nanozymes for Selective Cascade Catalysis

Advanced Materials, EarlyView.
A multilevel programming strategy is developed to engineer single‐atom COF nanozymes with tunable metal centers and chiral pockets inspired by heme–pocket cooperativity. This approach enables controlled metal–pocket interplay for asymmetric cascade catalysis, delivering high activity, selectivity, and recyclability in an asymmetric oxidation–aldol ...
Ziping Li, Qijun Sun, Yawen Hao, Haotian Wen, Shery Chang, Fengwang Li, Jiangtao Xu, Kang Liang   +7 more
wiley   +1 more source

UM MÉTODO EFICIENTE PARA A OBTENÇÃO DE DERIVADOS DE 1-ALQUILAMINO-2,4-DINITROBENZENO E A REDUÇÃO REGIOSSELETIVA PARA A OBTENÇÃO DE DERIVADOS DE 1-ALQUILAMINO-2-AMINO-4-NITROBENZENO

Química Nova, 2016
Both primary and secondary amines react with 2,4-dinitrochlorobenzene to give derivatives of 1-alkylamino-2,4-dinitrobenzene. These compounds are important intermediates for the synthesis of a diverse range of products.
Cíntia de A. Custódio, Simon J. Garden
doaj   +1 more source

4-(4-(2-Bromoethyl)phenoxy)-2,3,5,6-tetrafluoropyridine

Molbank, 2023
The title compound was synthesized in near quantitative yields via initial nucleophilic aromatic substitution of pentafluoropyridine (PFP) with 4-(2-bromoethyl)phenol as a versatile precursor for ionic liquids (ILs).
Tiffany H. Li, Lucas C. Messer, Nathan J. Weeks, Timothy J. Fuhrer, Scott T. Iacono   +4 more
doaj   +1 more source

Intramolecular Direct Arylation Enables Access to Diverse Photophysical Properties for π‐Expanded 1,4‐Dihydropyrrolo[3,2‐b]pyrroles

Advanced Optical Materials, EarlyView.
The unique combination of photophysical properties for π‐expanded 1,4‐dihydropyrrolo[3,2‐b]pyrroles (DHPPs) can be reached via a new synthetic approach. π‐Expanded DHPPs possessing electron‐withdrawing functionalities with emission reaching 700 nm, as well as large double helical systems were prepared and investigated.
Damian Kusy, Krzysztof Górski, Carmelo Naim, Francesco Bertocchi, Nicolas Vanthuyne, Krzysztof Noworyta, Bartosz Szymański, Radosław Kamiński, Francesca Terenziani, Denis Jacquemin, Daniel T. Gryko   +10 more
wiley   +1 more source

Bioengineered Exosome‐Loaded Immunomodulatory Bioadhesive Spray Reverses Liver Fibrosis and Metabolic Dysfunction That Triggers Beneficial Gut‐Liver Crosstalk in Chronic Fatty Liver Disease

Advanced Science, EarlyView.
Umbilical cord stem cell‐derived exosomes encapsulated in an immunomodulatory bioadhesive hydrogel spray enable localized therapy, sustained vesicle delivery, macrophage polarization, suppress systemic inflammation, and mitigate glucose and insulin homeostasis impairments in MAFLD.
Triya Saha, Ayushi Mairal, Shreya Mehrotra, Shiv K. Sarin, Ashok Kumar   +4 more
wiley   +1 more source

On the Frontier Between Nucleophilic Aromatic Substitution and Catalysis [PDF]

Chemistry – A European Journal, 2014
AbstractA study on the arylation of heteroatom nucleophiles by using activated haloarenes, with or without metal catalysts, is reported. A discussion concerning the involvement of traces of metals is presented, supported by an unexpected ''ligand'' effect in the absence of added metal catalysts.
Martin, Pichette Drapeau, Thierry, Ollevier, Marc, Taillefer   +2 more
openaire   +2 more sources

Charting the Future of Stereoselective Carbohydrate Synthesis: The Essential Role of Cross‐Disciplinary Innovation

Advanced Science, EarlyView.
Cross‐disciplinary endeavors are blossoming across the broad chemical sciences. This perspective provides a glimpse into the rewarding interdisciplinary journey taken by the Charles Loh research group in pioneering the σ‐hole based catalytic glycosylation strategy.
Charles C. J. Loh
wiley   +1 more source

A Novel and Efficient Synthesis of New Dixanthones [PDF]

Iranian Journal of Chemistry & Chemical Engineering, 2000
The facile and high yield synthesis of a new series of dibenzophenones in the presence of polyphosphoric acid (PPA) together with their cyclization to corresponding moni and dixanthones are described.
Hashem Sharghi, Fatemeh Tamaddon, Hossein Eshghi   +2 more
doaj  

C(aryl)-O Bond Formation from Aryl Methanesulfonates via Consecutive Deprotection and SNAr Reactions with Aryl Halides in an Ionic Liquid

Molecules, 2007
An efficient K3PO4-mediated synthesis of unsymmetrical diaryl ethers using the ionic liquid [Bmim]BF4 (1-butyl-3-methylimidazolium tetrafluoroborate) as solvent has been developed.
Hui Xu, Yang Chen
doaj   +1 more source