Results 31 to 40 of about 597,655 (179)
Cation Radical Accelerated Nucleophilic Aromatic Substitution via Organic Photoredox Catalysis [PDF]
, 2017 Nucleophilic aromatic substitution (SNAr) is a direct method for arene functionalization; however, it can be hampered by low reactivity of arene substrates and their availability.
Tay, Nicholas E. S., Nicewicz, David A.
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, 2021 Arylthiophene derivatives are potential components of functional materials, including organic electronics. Herein, we describe a nucleophilic aromatic substitution reaction of polyfluoroarenes using silylthiophenes as nucleophiles in the presence of a ...
Yoneda, Yuna +6 more
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Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions
Beilstein Journal of Organic Chemistry, 2020 The allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions is described. The synergistic palladium/copper-catalyzed reaction of aromatic aldehydes, allylic carbonates, and a silylboronate produces the corresponding homoallylic alcohol ...
Akihiro Yuasa +2 more
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Molecules, 2006 The nitro group of methyl 3-nitropyridine-4-carboxylate (1) has successfully been replaced by fluoride anion via nucleophilic aromatic substitution to give the 3-fluoro- pyridine-4-carboxylate 2.
Anne Fiksdahl, Freddy Tjosaas
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Molecules, 2020 In this study, we present a complete description of the addition of a model nucleophile to the nitroaromatic ring in positions occupied either by hydrogen (the first step of the SNAr-H reaction) or a leaving group (SNAr-X reaction) using theoretical ...
Kacper Błaziak +2 more
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Frontiers in Chemistry, 2018 Nucleophilic aromatic substitution reactions of 4-chloroquinazoline toward aniline and hydrazine were used as a model system to experimentally show that a substrate bearing heteroatoms on the aromatic ring as substituent is able to establish ...
Bruno Sánchez +4 more
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Beilstein Journal of Organic Chemistry, 2014 Three new porphyrin aminoalkyl dibenzylphosphoramidates were synthesized by nucleophilic aromatic substitution of one p-fluorine atom of 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TPPF20) by primary aminoalkyl dibenzylphosphoramidates.
Marcos C. de Souza +5 more
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Dehalogenation of Aromatics by Nucleophilic Aromatic Substitution
, 2016 Nucleophilic aromatic substitution has been implicated as a mechanism for both the biotic and abiotic hydrodehalogenation of aromatics. Two mechanisms for the aqueous dehalogenation of aromatics involving nucleophilic aromatic substitution with hydride ...
Daniel Sadowsky (1750234) +2 more
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Crystal structure of 4-(4-methoxyphenoxy)benzaldehyde
Acta Crystallographica Section E: Crystallographic Communications, 2015 The title compound, C14H12O3, was synthesized via the nucleophilic addition of 4-methoxyphenol to 4-fluorobenzaldehyde. The dihedral angle between the least-squares planes of the benzene rings is 71.52 (3)° and the C—O—C angle at the central O atom is ...
Andreas Schäfer +5 more
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Three-Component Condensation of β-Ketonitriles, 4-Fluorobenzaldehyde, and Secondary Cyclic Amines
Reactions, 2022 A new three-component condensation of β-ketonitriles, 4-fluorobenzaldehyde, and secondary cyclic amines was developed. A possible reaction mechanism has been proposed including Knoevenagel condensation followed by aromatic nucleophilic substitution.
Dmitry V. Osipov +2 more
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