N-Heterocyclic-Carbene-Catalyzed Domino Reactions via Two or More Activation Modes
Summary: Organocatalytic domino processes have become a rapidly growing area of research. N-heterocyclic carbenes (NHCs) have emerged as powerful organocatalysts for various transformations and continue to have widespread application. In the last decade,
Xiang-Yu Chen +4 more
doaj +1 more source
How mobile are dye adsorbates and acetonitrile molecules on the surface of TiO2 nanoparticles? A quasi-elastic neutron scattering study [PDF]
Motions of molecules adsorbed to surfaces may control the rate of charge transport within monolayers in systems such as dye sensitized solar cells.
Barnes, PRF +5 more
core +1 more source
Cell wall target fragment discovery using a low‐cost, minimal fragment library
LoCoFrag100 is a fragment library made up of 100 different compounds. Similarity between the fragments is minimized and 10 different fragments are mixed into a single cocktail, which is soaked to protein crystals. These crystals are analysed by X‐ray crystallography, revealing the binding modes of the bound fragment ligands.
Kaizhou Yan +5 more
wiley +1 more source
On the Stabilizing Action of Protein Denaturants: Acetonitrile Effect on Stability of Lysozyme in Aqueous Solutions [PDF]
Stability of hen lysozyme in the presence of acetonitrile (MeCN) at different pH values of the medium was studied by scanning microcalorimetry with a special emphasis on determination of reliable values of the denaturational heat capacity change.
Kovriguine, Evgueni, Potekhin, Sergey A.
core +2 more sources
At low cell density, SETDB1 and YAP1 accumulate in the nucleus. As cell density increases, the Hippo pathway is gradually activated, and SETDB1 is associated with increased YAP1 phosphorylation. At high cell density, phosphorylated YAP1 is sequestered in the cytoplasm, while SETDB1 becomes polyubiquitinated and degraded by the ubiquitin–proteasome ...
Jaemin Eom +3 more
wiley +1 more source
Vladimir Prelog i organska kemija u proteklom stoljeću [PDF]
Organic chemistry in the past century has undergone several profound changes and Vlado Prelog, as the great organic chemist of our time, was actively involved in these changes. During the first half of the 20th century, synthesis of new organic compounds
Sunko, D.
doaj
Metal–organic framework nanosheets (MONs): a new dimension in materials chemistry
Metal–organic framework nanosheets (MONs) are emerging as a novel class of two-dimensional materials with a distinct set of design principles, synthetic approaches, characterisation techniques and applications.
David J. Ashworth, Jonathan A. Foster
semanticscholar +1 more source
Variability in concentrations of potentially toxic elements in urban parks from six European cities [PDF]
Use of a harmonised sampling regime has allowed comparison of concentrations of copper, chromium, nickel, lead and zinc in six urban parks located in different European cities differing markedly in their climate and industrial history.
Ajmone-Marsanb, F. +15 more
core +2 more sources
We reconstituted Synechocystis glycogen synthesis in vitro from purified enzymes and showed that two GlgA isoenzymes produce glycogen with different architectures: GlgA1 yields denser, highly branched glycogen, whereas GlgA2 synthesizes longer, less‐branched chains.
Kenric Lee +3 more
wiley +1 more source
Big Data meets Quantum Chemistry Approximations: The $\Delta$-Machine Learning Approach
Chemically accurate and comprehensive studies of the virtual space of all possible molecules are severely limited by the computational cost of quantum chemistry.
Dral, Pavlo O. +3 more
core

