Results 61 to 70 of about 86,737 (136)

Consecutive cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate with boronic acids: efficient synthesis of 1,1-diaryl-2,2-difluoroethenes

open access: yesBeilstein Journal of Organic Chemistry, 2013
The cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate (2) with 2 equiv of boronic acids in the presence of catalytic amounts of Pd(OAc)2 and Na2CO3 afforded the mono-coupled products 3 and 5 in high yields.
Ju Hee Kim, Su Jeong Choi, In Howa Jeong
doaj   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, Volume 32, Issue 26, 11 July 2026.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

Syntheses of fluorooxindole and 2-fluoro-2-arylacetic acid derivatives from diethyl 2-fluoromalonate ester

open access: yesBeilstein Journal of Organic Chemistry, 2014
Diethyl 2-fluoromalonate ester is utilised as a building block for the synthesis of 2-fluoro-2-arylacetic acid and fluorooxindole derivatives by a strategy involving nucleophilic aromatic substitution reactions with ortho-fluoronitrobenzene substrates ...
Antal Harsanyi   +3 more
doaj   +1 more source

Redox‐Active Guanidines

open access: yesChemElectroChem, Volume 13, Issue 12, 17 June 2026.
Redox‐active guanidines, comprising guanidino‐functionalized aromatics (GFAs) and redox‐active urea azines (RAAs), are electron donors and strong Lewis and Brønsted bases that are used in several applications. They act as redox‐active ligands in bistable coordination compounds and as reagents in dehydrogenative coupling reactions and proton‐coupled ...
Hans‐Jörg Himmel
wiley   +1 more source

New methodology for the synthesis of fluorinated aromatics [PDF]

open access: yes, 1990
This thesis is concerned with new methodology for the introduction of fluorine atoms, and trifluoromethyl groups into aromatic systems and the following approaches have been adopted: (i) The possibility of selective cleavage of the aryl-silicon bond of ...
Rock, Michael Harold
core  

Regioselective carbon–carbon bond formation of 5,5,5-trifluoro-1-phenylpent-3-en-1-yne

open access: yesBeilstein Journal of Organic Chemistry, 2013
The regioselective carbon–carbon bond formation was studied using 5,5,5-trifluoro-1-phenylpent-3-en-1-yne as a model substrate, and predominant acceptance of electrophiles β to a CF3 group as well as a deuterium trap experiment of the lithiated species ...
Motoki Naka   +2 more
doaj   +1 more source

Three step synthesis of single diastereoisomers of the vicinal trifluoro motif

open access: yesBeilstein Journal of Organic Chemistry, 2009
A three step route to single diastereoisomers of the vicinal trifluoromethyl motif is described. The route starts from either syn- or anti-α,β-epoxy alcohols and takes a direct approach in that each of the three steps introduces a fluorine atom in a ...
Vincent A. Brunet   +2 more
doaj   +1 more source

Crystal design using multipolar electrostatic interactions: A concept study for organic electronics

open access: yesBeilstein Journal of Organic Chemistry, 2013
Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is ...
Peer Kirsch   +2 more
doaj   +1 more source

Estudos de fluorescencia em organo-gel [PDF]

open access: yes, 1997
Dissertação (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.Um novo campo de estudo tem sido aberto com a solubilização de gelatina em microemulsão água em óleo. O sistema MBG é formado por Aerosol-OT, água e
Souza, Donizete de
core  

Electrophilic fluorination at saturated carbon [PDF]

open access: yes, 2000
Chapter 1 - Chapter 1 contains a discussion of the preparation and properties of elemental fluorine. A review of the use of elemental fluorine as a selective fluorinating in organic chemistry is given and the preparation and use of other selective ...
Parsons, Mandy
core  

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