Results 41 to 50 of about 82,167 (149)
Beilstein Journal of Organic Chemistry, 2013 In the last few years, transition metal-mediated reactions have joined the toolbox of chemists working in the field of fluorination for Life-Science oriented research.
Grégory Landelle +4 more
doaj +1 more source
Flavin Catalysts in Organic Synthesis
Angewandte Chemie International Edition, EarlyView.Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +1 more source
Elemental fluorine as a valid synthetic reagent [PDF]
, 1994 Chapter I Chapter I reviews the uses of elemental fluorine in selective organic synthesis and its use in the generation of selective electrophilic fluorinating agents.
Skinner, Christopher John
core
Photochemical and Thermal Activation of a Diarylbismuth Azide
Chemistry – A European Journal, EarlyView.We report the synthesis and characterization of a novel diarylbismuth azide and its divergent reactivity upon thermal or photochemical activation. These findings contribute expanding the reactivity landscape of heavy pnictogen compounds and sets the basis for further investigations. ABSTRACT Azides are widely employed in synthesis as convenient nitrene
Giacomo Pugliese +5 more
wiley +1 more source
Aplicações sinteticas de enzimas imobiliadas em organo-gel e gel de agar [PDF]
, 1997 Dissertação (Mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas.As microemulsões água-em-óleo (água + óleo + surfactante) podem ser utilizadas para formar géis elásticos e termoreversíveis pela adição de gelatina.
Queiroz, Neide
core
Multigramme synthesis and asymmetric dihydroxylation of a 4-fluorobut-2E-enoate
Beilstein Journal of Organic Chemistry, 2013 Esters of crotonic acid were brominated on a multigramme scale using a free radical procedure. A phase transfer catalysed fluorination transformed these species to the 4-fluorobut-2E-enoates reproducibly and at scale (48–53%, ca. 300 mmol).
James A. B. Laurenson +4 more
doaj +1 more source
N‐Boron‐Functionalized Anionic N‐Heterocyclic Carbenes (NBA‐NHCs)—A Case Study
Chemistry – A European Journal, EarlyView.The synthesis and characterization of a new family of N‐boron‐functionalized anionic N‐heterocyclic carbenes (NBA‐NHCs), IiPrB(CN)3−, IiPr(C2F5)BF2−, IMesB(CN)3−, and IMes(C2F5)BF2−, is reported. ABSTRACT The synthesis and characterization of a new family of N‐boron‐functionalized anionic NHCs (NBA‐NHCs), IiPrB(CN)3− (5), IiPr(C2F5)BF2− (6), IMesB(CN)3−
Sophie Mann +3 more
wiley +1 more source
On the Ability of Bismuth to Couple Weakly Coordinating Anions
Angewandte Chemie, Volume 138, Issue 29, 13 July 2026.Motivated by the growing number of catalytic processes based on high‐valent Bi, we investigated in silico the reductive elimination step responsible for the coupling of weakly coordinating anions. Relativistic contributions appeared to be decisive to the electronic description of the intermediates involved in this process.
Lucas Mele +3 more
wiley +2 more sources
EcoEnergy, EarlyView.This review summarizes a descriptor‐guided framework for linking theoretical calculations, in situ/operando characterization, synthesis regulation, and application screening in functional materials. Emphasis is placed on dynamic structure–property relationships that enable low‐cost material design with enhanced activity, stability, and environmental ...
Yanyu Jin +9 more
wiley +1 more source
The influence of the C-N⁺ ----- F-C charge dipole interaction in fluoro organic chemistry [PDF]
, 2009 Chapter 1 introduces the discovery of elemental fluorine by H. Moissan and some uses of inorganic fluoride. Organo fluoro compounds and their place in pharmaceuticals and agrochemicals are also introduced.
Gooseman, Natalie Elizabeth Jane
core +2 more sources