Results 11 to 20 of about 63,731 (192)

DNA-Binding Properties of Iridium(III) Complexes Encompassing Design, Function and Biophysical Assessments. [PDF]

open access: yesChemphyschem
This review describes the biophysical techniques used to investigate DNA‐binding phenomena and the progress made so far in the application of iridium(III) complexes for this purpose. Ir(III) complexes offer myriad opportunities in the design and study of DNA‐binding agents and discussed examples are contextualised with complementary studies in ...
Alkhaibari IS, Buurma NJ, Pope SJA.
europepmc   +2 more sources

4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)

open access: yesMolbank, 2023
The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS,
Katelyn D. Thompson   +3 more
doaj   +1 more source

Chemical diffusion of fluorine in melts in the system Na2OAl2O3SiO2 [PDF]

open access: yes, 1985
The volatilization of fluorine from three melts in the system Na2OAl2O3SiO2 has been investigated at 1 atm pressure and 1200–1400°C. The melts chosen have base compositions corresponding to albite, jadeite and a peraluminous melt with 75 mole % SiO2 ...
Scarfe, Christopher M.   +1 more
core   +1 more source

The effect of fluorine on viscosities in the system Na2O-Al2O3-SiO2: implications for phonolites, trachytes and rhyolites [PDF]

open access: yes, 1985
The effect of fluorine on melt viscosities of five compositions in the system Na2O-Al2O3- SiO2h as been investigateda t one atmospherea nd 1000-1600'Cb y concentric-cylinder viscometry.
Scarfe, Christopher M.   +2 more
core   +1 more source

4-(4-(2-Bromoethyl)phenoxy)-2,3,5,6-tetrafluoropyridine

open access: yesMolbank, 2023
The title compound was synthesized in near quantitative yields via initial nucleophilic aromatic substitution of pentafluoropyridine (PFP) with 4-(2-bromoethyl)phenol as a versatile precursor for ionic liquids (ILs).
Tiffany H. Li   +4 more
doaj   +1 more source

Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide

open access: yesBeilstein Journal of Organic Chemistry, 2013
The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts ...
Sébastien Alazet   +2 more
doaj   +1 more source

Effects of water and fluorine on the viscosity of albite melt at high pressure: a preliminary investigation [PDF]

open access: yes, 1985
The viscosities of fluorine- and water-bearing melts based on albite composition have been determined at 7.5, 15 and 22.5 kbar by the falling-sphere method. All melt viscosities decrease isothermally with increasing pressure.
Mysen, Bjørn O., Dingwell, Donald B.
core   +1 more source

Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3

open access: yesBeilstein Journal of Organic Chemistry, 2013
A Cu-mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3 was developed for the first time. This method offers a convenient and economical approach to various trifluoroethyl-containing compounds.
Xueliang Jiang, Feng-Ling Qing
doaj   +1 more source

A one-pot synthesis of 3-trifluoromethyl-2-isoxazolines from trifluoromethyl aldoxime

open access: yesBeilstein Journal of Organic Chemistry, 2013
Functionalized 3-trifluoromethyl-2-isoxazolines and 3-trifluoromethylisoxazoles were easily prepared from trifluoromethyl aldoxime 2 under mild conditions by using DIB as oxidant.
Raoni S. B. Gonçalves   +4 more
doaj   +1 more source

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