Results 51 to 60 of about 86,737 (136)

Prins fluorination cyclisations: Preparation of 4-fluoro-pyran and -piperidine heterocycles

open access: yesBeilstein Journal of Organic Chemistry, 2010
The Prins reaction was investigated using BF3·OEt2 as a Lewis acid. It has been recently demonstrated, that if BF3·OEt2 is used in stoichiometric amounts then these reactions generate fluorinated products where the BF3·OEt2 contributes fluoride ion to ...
Guillaume G. Launay   +2 more
doaj   +1 more source

A Review on Green Synthetic Approaches in the Development of Quinoline Analogues

open access: yesChemistrySelect, Volume 11, Issue 33, 1 September 2026.
This review highlights recent advances in environmentally friendly approaches, including metal‐free systems, solvent‐free approaches, microwave, and ultrasonic‐assisted techniques, organo‐ and biocatalysis, ionic liquids, nanoparticle catalysis, electrochemical, and photocatalytic strategies for the synthesis of quinoline scaffolds.
Demis Zelelew   +3 more
wiley   +1 more source

Chemistry of some model compounds related to fluorinated polymers [PDF]

open access: yes, 1993
The work described in this thesis is concerned with three areas which are the generation of stable carbocations from saturated model compounds related to poly- vinylidenefluoride, the development of synthetic routes to fluoro-organo-phosphazenes with ...
Odello, Paolo
core  

Borylation of Aryl Halides Induced by Visible Light Under Open‐To‐Air Environment

open access: yesChemSusChem, Volume 19, Issue 15, 14 August 2026.
Borylation of aryl halides was successfully achieved by a sustainable protocol which involved a purely organic confined medium, visible light as energy source under an open‐to‐air environment. Experimental and computational investigations evidenced that the reaction occurred through the formation of a ground–state complex generated by hydrogen bonding.
Jorge C. Herrera‐Luna   +5 more
wiley   +1 more source

Organo-sulfur phosphorus chemistry

open access: yes, 1998
P-organo-substituted dithiadiphosphetane disulfides have been prepared by the reaction of ferrocene and arenes with P4S10. Reaction of these compounds and Lawesson's reagent with alkenes, 2,3-dimethylbutadiene and other compounds gave organo-sulfur ...
Mark R. StJ. Foreman (7167302)
core   +3 more sources

Reaction of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane with N-vinyl compounds

open access: yesBeilstein Journal of Organic Chemistry, 2013
The reaction of hexafluorothioacetone dimer (2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane, 1) with vinylamides leads to the rapid formation of [2 + 2] cycloadducts: 4-amino-2,2-bis(trifluoromethyl)thietanes.
Viacheslav A. Petrov, Will Marshall
doaj   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, Volume 32, Issue 28, 25 July 2026.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3H-1λ3,2-benziodaoxol-3-one

open access: yesBeilstein Journal of Organic Chemistry, 2014
The synthesis of 5-nitro-1-(trifluoromethyl)-3H-1λ3,2-benziodaoxol-3-one (3), a hypervalent-iodine-based electrophilic trifluoromethylating reagent, is described.
Nico Santschi   +4 more
doaj   +1 more source

One-pot cross-enyne metathesis (CEYM)–Diels–Alder reaction of gem-difluoropropargylic alkynes

open access: yesBeilstein Journal of Organic Chemistry, 2013
Propargylic difluorides 1 were used as starting substrates in a combination of cross-enyne metathesis and Diels–Alder reactions. Thus, the reaction of 1 with ethylene in the presence of 2nd generation Hoveyda–Grubbs catalyst generates a diene moiety ...
Santos Fustero   +5 more
doaj   +1 more source

Next Generation Organofluorine Containing Blockbuster Drugs [PDF]

open access: yes, 2020
The role of organo-fluorine compounds in modern health, food and energy related industries is widelyappreciated. The unique properties that fluorine imparts to organic molecules, stemming from its high electronegativity and stability when bound to ...
Hiroki Moriwaki   +26 more
core   +1 more source

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