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Cluster Preface: Progress in Organo-Fluorine Chemistry [PDF]
The chance of achieving a successful ‘hit’ in the search for new and improved functional organic molecules can be increased by appropriate fluorination. To this end, many new and exciting methods for the site-selective, controlled fluorination of organic molecules are being developed.
Duncan L Browne
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Recent Innovations of Organo-fluorine Synthesis and Pharmacokinetics
Current Organic Chemistry, 2021The fluorinated compounds have significance in medicinal chemistry and pharmaceutical research. The introduction of fluorine atom in the heterocyclic compounds increases biological activity by favourable physiochemical interactions. The combination of heterocycles with fluorine substituents has a wide range of applications in the study of various ...
Omkar Kamble +2 more
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Journal of Fluorine Chemistry, 2000
Organo-fluorine compounds have become increasingly important in the last 50 years, as synthetic routes to them have been developed; very few occur naturally. Their chemical behavior covers the entire range from inertness to high reactivity and their physical properties show unique features.
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Organo-fluorine compounds have become increasingly important in the last 50 years, as synthetic routes to them have been developed; very few occur naturally. Their chemical behavior covers the entire range from inertness to high reactivity and their physical properties show unique features.
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Safety improvement of lithium ion batteries by organo-fluorine compounds
Journal of Fluorine Chemistry, 2011Abstract Thermal stability, electrochemical oxidation stability and charge/discharge characteristics of natural graphite powder were investigated by mixing of five fluoro-carbonates with 1 mol/L LiClO 4 –EC/DEC/PC (1:1:1 vol.). DSC study revealed that thermal stability of the electrolyte solution was improved by mixing of fluoro-carbonates by 10.0–33.
Yoshimi Ohzawa +2 more
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Investigation into antimony pentafluoride-based catalyst in preparing organo-fluorine compounds
Journal of Molecular Catalysis A, 2005Abstract Antimony pentafluoride (SbF 5 )/porous metal fluorides (PMF) were prepared by impregnating PMF with SbCl 5 , and then fluorinating with anhydrous hydrogen fluoride (AHF). It demonstrates excellent activity in vapor-phase catalytic fluorination and overcomes such drawbacks as hygroscopicity, corrosion and toxicity that appear while SbF 5 was
Masanori Tamura +2 more
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An Organo-Fluorine Compound Mixed Electrolyte for Ultrafast Electric Double Layer Supercapacitors
AbstractFluorine chemistry has gained tremendous attention in the area of electrochemical energy devices such as lithium ion batteries, fuel cells and solar cells. With the advent of novel fluorinating systems, it is interesting to study the effect of fluorine on the electrochemical characteristics of such energy devices.
Ritu Gupta, Pura Ram
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Journal of Power Sources, 2013
Abstract Thermal and oxidation stability of fluorine compound-mixed electrolyte solutions have been investigated. Charge/discharge behavior of natural graphite electrode has been also examined in the same electrolyte solutions. Fluorine compounds demonstrate much lower reactivity with metallic Li than ethylene carbonate/dimethyl carbonate.
Yoshimi Ohzawa +2 more
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Abstract Thermal and oxidation stability of fluorine compound-mixed electrolyte solutions have been investigated. Charge/discharge behavior of natural graphite electrode has been also examined in the same electrolyte solutions. Fluorine compounds demonstrate much lower reactivity with metallic Li than ethylene carbonate/dimethyl carbonate.
Yoshimi Ohzawa +2 more
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Electron Transfer Methodologies to the Synthesis of Organo‐Fluorine Compounds
ChemInform, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
Maurice Medebielle +8 more
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Current approaches to the electrochemical synthesis of organo-fluorine compounds
Journal of Applied Electrochemistry, 2004Recent trends in the synthesis of organo-fluorine compounds using the conventional selective electrochemical fluorination (SEF) route as well as other novel synthetic approaches are presented. In the conventional SEF route, fluorinations of the active methylene group in the side chain as well as unsaturated alkenes have been achieved.
Noel, M., Suryanarayanan, V.
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