Results 111 to 120 of about 16,879 (311)
From fleeting intermediates to well‐defined molecular structures, carbenes (neutral divalent carbon) remind us that the most reactive ideas often make a large impact. Despite their wide‐ranging applications, the direct characterization of these reactive species remains a persistent experimental challenge.
Bethany Sawyer+2 more
wiley +1 more source
Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis
The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations.
Isidro M. Pastor+3 more
doaj +1 more source
Fluorohydration of alkynes via I(I)/I(III) catalysis
Substrate specificity is ubiquitous in biological catalysis, but less pervasive in the realm of small-molecule catalysis. Herein, we disclose an intriguing example of substrate specificity that was observed whilst exploring catalysis-based routes to ...
Jessica Neufeld+2 more
doaj +1 more source
1,3-Dicarbonyl compounds in stereoselective domino and multicomponent reactions
International audienceModern organic synthesis focuses on the discovery and the development of stereoselective multiple bond-forming transformations allowing the creation of several covalent bonds in a single operation.
Bonne, Damien+3 more
core +3 more sources
Recent advances in continuous-flow organocatalysis for process intensification
The progresses on continuous-flow organocatalysis from 2016 to early 2020 are reviewed with focus on transition from batch to flow.
C. De Risi+5 more
semanticscholar +1 more source
Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo+4 more
wiley +1 more source
A bifunctional photoaminocatalyst for the alkylation of aldehydes: Design, analysis, and mechanistic studies [PDF]
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright ©2018 American Chemical Society after peer review and technical editing by the publisher.
Alemán, José+6 more
core +5 more sources
The Dihydroindeno[2,1‐c]fluorene Core: from Syntheses to Properties and Potential Applications
In the last decade, substances possessing the dihydroindeno[2,1‐c]fluorene scaffold showed interesting photo‐physical properties and other potential applications in electronics. The afore‐mentioned compounds belong to the family of five regioisomeric dihydroindenofluorenes, but unlike other ones, they possess angular or, in the case of higher congeners,
Timothée Cadart, Martin Kotora
wiley +1 more source
Substrate preorganization is used to overcome the concentration and lifetime constraints of photoredox catalysis. Pt12L24 nanospheres equipped with guanidinium moieties (LGua) are able to preorganize carboxylic acids and act as photocatalysts for the decarboxylative oxygenation reaction.
Rens Ham+2 more
wiley +2 more sources
N-Heterocyclic Carbenes Supported on Vinylic Addition Polynorbornene: A Recyclable and Recoverable Organocatalyst [PDF]
Producción CientíficaA bromoalkyl functionalized vinylic addition polynorbornene has been used as an inert new scaffold to support imidazolium salts by straightforward nucleophilic substitution using different imidazoles ImR (R=Me, mesityl, 2,6-iPr2C6H3).
Albéniz Jiménez, Ana Carmen+1 more
core +3 more sources