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A Crystalline Ylide‐Stabilized Stibenium Cation
European Journal of Inorganic Chemistry, Volume 29, Issue 17, 17 June 2026.The isolation of a stibenium cation stabilized by two thiophosphinoyl‐tethered ylide groups is reported. The cation is accessible via salt metathesis of the metalated ylide with SbCl3 and features CSb single bonds, with lone pairs remaining localized at the ylidic carbon atoms.
Daniel Knyszek +4 more
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2.8 Recent Advances in N-Heterocyclic Carbene Organocatalysis
, 2018 In recent years, organocatalysis has seen a rapid rise in popularity and this has led to a subsequent increase in the research output of the area, with organocatalysis by N-heterocyclic carbenes (NHCs) playing a significant role.
A. Davies, A. D. Smith
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Beilstein Journal of Organic Chemistry, 2016 Hydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N–H and O–H moieties have been effectively used for electrophile activation, activation based on other types of non ...
Pavel Nagorny, Zhankui Sun
doaj +1 more source
Enantioselective homogeneous catalysts for the synthesis of fluorinated organic compounds
, 2012 This thesis is divided into three main results chapters that reflect the path my research took. In the first results chapter, the first organocatalyst for the carbonyl-ene reaction was discovered and found to give high conversion using 1,3-bis(3,5-bis ...
Jones, Charlotte E. S.
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Asymmetric synthesis of tetrahydroquinolines through supramolecular organocatalysis
, 2014 Functionalized chiral tetrahydroquinolines were synthesized through supramolecular organocatalysis using quinidine-NH-thiourea 3c/L-phenylalanine 4i followed by reductive amination from the simple ...
Ramachary, Dhevalapally B. +1 more
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Advanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.A substrate‐dependent, regio‐ and stereocontrolled diversity‐oriented organocatalytic vinylogous Michael addition/cyclization cascade of γ, γ’‐alkylidene indane‐1,3‐diones with enals, using secondary amines as the catalyst, has been developed. A substrate‐dependent, regio‐ and stereo‐controlled diversity‐oriented organocatalytic vinylogous Michael ...
Jen‐Yu Kuan +2 more
wiley +1 more source
Chiral benzylamines in organocatalysis
, 2011 Hirālie benzilamīni organokatalīzē. Kalniņš T., zinātniskais vadītājs Dr. ķīm., asoc. prof. Sūna E. Bakalaura darbs, 84 lappuses, 42 attēli, 9 tabulas, 65 literatūras avoti. Latviešu valodā.
Kalniņš, Toms
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Annual Reports Section "B" (Organic Chemistry), 2011 Benjamin R. Buckley, Mohamed M. Farah
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Advanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.Herein, an organocatalytic asymmetric synthesis of dihydroquinoline/hydantoin hybrids is described. The synthetic protocol involves a tandem reaction comprising a phosphoric acid–catalyzed initial Povarov dimerization of in situ generated imine/enamine mixtures under tautomeric equilibrium, followed by a Urech–Read reaction of the 1,2‐dihydroquinoline ...
Zuriñe Serna‐Burgos +5 more
wiley +1 more source
Citation: 'organocatalysis' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08193 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
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