Results 71 to 80 of about 6,799 (217)

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

open access: yesEcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha   +3 more
wiley   +1 more source

Homogeneous Organocatalysis

open access: yes, 2010
Catalysis plays a pivotal role in providing fuels, commodity and fine chemicals, and pharmaceuticals, as well as providing the means for strengthening environmental safeguards all over the world. More than 60% of all chemical products and 90% of chemical
Wells, Richard P. K.   +9 more
core   +1 more source

Organocatalysis inspired chemistry of aldehydes

open access: yes, 2022
The field of organocatalysis developed quickly in the last two decades. The possibilities of organocatalysis working with other catalysis mode are starting to get explored more often in recent years.

core   +1 more source

Isotellurourea‐Catalyzed Enantioselective (4+2)‐Heterocycloadditions of But‐2‐ynoates and Michael Acceptors

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Isotelluroureas allow for the use of alkynoates for asymmetric (4+2)‐heterocycloadditions with different Michael acceptors. Alk‐2‐ynoates are readily available starting materials which, in principle, can be utilized for cycloadditions in analogy to structurally similar allenoates.
Anna Scheucher, Mario Waser
wiley   +1 more source

Catalytic Strategies for Amide-Based Michael Additions: Advances and Perspectives

open access: yesJournal of Chemistry
The Michael addition is a cornerstone transformation in organic synthesis, enabling efficient C–C and C–heteroatom bond formation. Traditionally, α,β-unsaturated carbonyl compounds such as enones and esters have dominated as Michael acceptors, whereas α ...
Muhammad Naufal   +5 more
doaj   +1 more source

Redox Properties of Catalytically Generated Iminium Ions From α,β‐Unsaturated Aldehydes and Chiral Secondary Amines

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
We present a rapid, operationally simple, and broadly applicable protocol for the catalytic formation and in situ electrochemical characterization of chiral a,b‐unsaturated iminium ions by cyclic voltammetry (CV). Using only 5 mol% of the aminocatalyst, we systematically measure the reduction potential of over 50 iminium intermediates, revealing how ...
Martí Gisbert   +2 more
wiley   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

open access: yesAngewandte Chemie, Volume 138, Issue 25, 15 June 2026.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis   +2 more
wiley   +2 more sources

Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities

open access: yes, 2023
International audienceSince the pioneer reports of Akiyama and Terada groups on Brønsted acid organocatalysis, this field never stopped growing with the development of ingenious strategies for the activation of challenging poorly reactive substrates. The
Bastien Michelet   +9 more
core   +1 more source

Mechanical force-switchable aqueous organocatalysis

open access: yesCommunications Materials
Control over the catalytic activity of artificial catalytic systems in aqueous media is of high interest for biomimetic artificial catalysts. The activity of catalytic systems can be controlled via introducing stimuli-responsive feature in the structure ...
Nikita Das, Chandan Maity
doaj   +1 more source

Diaryl Thiourea Catalysts Promote the Formation of Propargyl Enol Ethers in the Claisen Rearrangement Sequence

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The allenyl ketone products of an enol ether formation–propargyl Claisen rearrangement sequence are susceptible to acid‐catalyzed isomerization to yield the corresponding conjugated dienones. A diaryl thiourea catalyst was found to promote the desired reaction sequence while suppressing the competing isomerization.
Veera K. Bruce‐Salmenkivi   +3 more
wiley   +1 more source

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