Results 71 to 80 of about 12,256 (221)
This minireview highlights recent advances in catalyst development and mechanistic strategies that enable photochemical and photocatalytic reactivity under 700–1000 nm NIR light, emphasizing how long‐wavelength excitation expands opportunities in both synthetic chemistry and biology.
Santosh K. Pagire +3 more
wiley +2 more sources
(2R,4R)-2-Hydroxy-4-(2-methoxyphenyl)bicyclo[3.3.1]nonan-9-one
The title compound, C16H20O3, contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by intermolecular O—H...O hydrogen bonds.
Shuping Luo +4 more
doaj +1 more source
A Crystalline Ylide‐Stabilized Stibenium Cation
The isolation of a stibenium cation stabilized by two thiophosphinoyl‐tethered ylide groups is reported. The cation is accessible via salt metathesis of the metalated ylide with SbCl3 and features CSb single bonds, with lone pairs remaining localized at the ylidic carbon atoms.
Daniel Knyszek +4 more
wiley +1 more source
Spotting trends in organocatalysis for the next decade
After two decades of steady growing, symbiotic merger of organocatalysis with emerging electrochemical and photochemical tools are envisioned as hot topics in the coming decade.
José M. Lassaletta
doaj +1 more source
Amine catalysis for the organocatalytic diboration of challenging alkenes [PDF]
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The generation of in situ sp 2 –sp 3 diboron adducts has revolutionised the synthesis of organoboranes.
Althaus +35 more
core +1 more source
Resin‐supported tripeptide achieved the dynamic kinetic resolution in the catalytic aldol reaction of formylated heterobiaryl N‐oxides with high efficiency and enantioselectivity. The system features a broad substrate scope and a recyclable catalyst.
Jiaqi Tian +3 more
wiley +1 more source
A new photocatalyst for the aerobic photochemical oxidation of sulfides to sulfoxides is described under really low catalyst loading (0.01 mol%) and methanol as the green solvent. The chemoselective oxidation of sulfides to sulfoxides is accomplished using a new family of photocatalysts, namely 1,2,6‐thiadiazin‐4‐ones. Utilizing a low catalyst loading (
Charikleia I. Karaousta +6 more
wiley +1 more source
Solvent-Free Enantioselective Organocatalyzed Aldol Reactions [PDF]
The use of proline as catalyst for the aldol process has given a boost to the development of organocatalysis as a research area. Since then, a plethora of organocatalysts of diverse structures have been developed for this and other organic ...
Bañón Caballero, Abraham +2 more
core +2 more sources
Diverse reactivity of maleimides in polymer science and beyond
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick +2 more
wiley +1 more source
Strategies for the synthesis of enantiopure compounds focused on organocatalysis [PDF]
Podeu consultar el llibre complet a: http://hdl.handle.net/2445/32393The preparation of enantiomerically pure compounds (EPC) is a continuous social demand due to the clinical advantages that enantiopure drugs offer over the racemic forms. Here, the best
Arróniz, Carlos +1 more
core

