Results 81 to 90 of about 8,155 (194)

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

open access: yesChemistry – A European Journal, Volume 32, Issue 39, 22 October 2026.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua   +3 more
wiley   +1 more source

Homogeneous Organocatalysis

open access: yes, 2002
Catalysis plays a pivotal role in providing fuels, commodity and fine chemicals, and pharmaceuticals, as well as providing the means for strengthening environmental safeguards all over the world. More than 60% of all chemical products and 90% of chemical
Taylor, Stuart H.   +12 more
core   +1 more source

Rhodium‐Catalyzed Synthesis of Enantioenriched α‐Substituted Primary Amines Through Asymmetric Transfer Hydrogenation

open access: yesChemistry – A European Journal, Volume 32, Issue 39, 22 October 2026.
Enantioenriched α‐substituted primary amines are efficiently prepared by rhodium‐catalyzed asymmetric transfer hydrogenation of ortho‐hydroxyaryl N─H imines under mild conditions using a low catalyst loading and ammonium formate as the hydrogen source in high yields (up to 99%) and enantioselectivities (up to 99% ee).
Chonghuo Liu   +4 more
wiley   +1 more source

Synthesis of cyclodextrin derivatives for organocatalysis

open access: yes, 2019
Synthesis of cyclodextrin derivatives for organocatalysis This doctoral thesis examines the preparation of new cyclodextrin (CD) derivatives suitable for organocatalysis. The aim of this work is to prepare monosubstituted and disubstituted CD derivatives
Chena Tichá, Iveta
core  

Mechanical force-switchable aqueous organocatalysis

open access: yesCommunications Materials
Control over the catalytic activity of artificial catalytic systems in aqueous media is of high interest for biomimetic artificial catalysts. The activity of catalytic systems can be controlled via introducing stimuli-responsive feature in the structure ...
Nikita Das, Chandan Maity
doaj   +1 more source

A technology platform to chiral amines: selected examples in asymmetric organocatalysis

open access: yes, 2019
Organocatalysis makes use of small organic molecules to activate reaction partners and is nowadays an established catalytic platform; in fact, despite the relatively young age, its potential and powerful impact is widely appreciated.
Valeria Nori   +3 more
core   +1 more source

organocatalysis

open access: yes
Citation: 'organocatalysis' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08193 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +2 more sources

Palladium and Organocatalysis: An Excellent Recipe for Asymmetric Synthesis

open access: yesMolecules, 2013
The dual activation of simple substrates by the combination of organocatalysis and palladium catalysis has been successfully applied in a variety of different asymmetric transformations.
Isidro M. Pastor   +3 more
doaj   +1 more source

Ring-Opening Copolymerization of 4D Polyesters Using Supramolecular Thiourea/Organocatalysis

open access: yes, 2023
Organocatalysis is explored to drive ring-opening copolymerization of anhydrides and epoxides yielding 3D printable ...
Merckle, David
core   +1 more source

A quantitative approach to nucleophilic organocatalysis

open access: yesBeilstein Journal of Organic Chemistry, 2012
The key steps in most organocatalytic cyclizations are the reactions of electrophiles with nucleophiles. Their rates can be calculated by the linear free-energy relationship log k(20 °C) = sN(E + N), where electrophiles are characterized by one parameter
Herbert Mayr   +3 more
doaj   +1 more source

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