Mechanochemistry assisted asymmetric organocatalysis: A sustainable approach
Beilstein Journal of Organic Chemistry, 2012 Ball-milling and pestle and mortar grinding have emerged as powerful methods for the development of environmentally benign chemical transformations. Recently, the use of these mechanochemical techniques in asymmetric organocatalysis has increased.
Pankaj Chauhan, Swapandeep Singh Chimni
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Pursuing Chemical Efficiency by Using Supported Organocatalysts for Asymmetric Reactions under Aqueous Conditions [PDF]
, 2015 Over the past decade, a great effort has been made by the chemical community to improve the efficiency of organic transformations and allow sustainable processes.
Alonso, Diego A. +6 more
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Development of a general, enantioselective organocatalytic Mukaiyama-Michael reaction with α,β-unsaturated aldehydes [PDF]
, 2009 LUMO-lowering organocatalysis has been extended to promote the conjugate addition of S-alkyl and 1-pyrrolyl silylketene acetals to α,β-unsaturated aldehydes, yielding both, syn and anti Mukaiyama–Michael products with high levels of enantioselectivity ...
Borths, Christopher J. +2 more
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Reaction Mechanism of Organocatalytic Michael Addition of Nitromethane to Cinnamaldehyde: A Case Study on Catalyst Regeneration and Solvent Effects [PDF]
, 2017 The Michael addition of nitromethane to cinnamaldehyde has been computationally studied in the absence of a catalyst and the presence of a biotinylated secondary amine by a combined computational and experimental approach. The calculations were performed
Luk, Louis Y. P. +4 more
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ORGANOCATÁLISE ENANTIOSSELETIVA: EVOLUÇÃO E ASPECTOS RECENTES
Química NovaIn the last two decades, enantioselective organocatalysis has established itself as one of the three pillars of asymmetric catalysis. The rapid growth in the area is due to the rationalization of organocatalysis based on the generic modes of catalyst ...
Fernanda G. Finelli +2 more
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Spotting trends in organocatalysis for the next decade
Nature Communications, 2020 After two decades of steady growing, symbiotic merger of organocatalysis with emerging electrochemical and photochemical tools are envisioned as hot topics in the coming decade.
José M. Lassaletta
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Solvent-free synthesis of enantioenriched β-silyl nitroalkanes under organocatalytic conditions
Beilstein Journal of Organic Chemistry, 2021 An enantioselective 1,4-conjugate addition of nitromethane to β-silyl α,β-unsaturated carbonyl compounds catalyzed by bifunctional squaramide catalysts has been developed.
Akhil K. Dubey, Raghunath Chowdhury
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Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes [PDF]
, 2017 The asymmetric conjugate addition of carbon and heteroatom nucleophiles to nitroalkenes is a very interesting tool for the construction of highly functionalized synthetic building blocks.
Alonso, Diego A. +6 more
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Chiral phosphines in nucleophilic organocatalysis
Beilstein Journal of Organic Chemistry, 2014 This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates ...
Yumei Xiao +3 more
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(2R,4R)-2-Hydroxy-4-(2-methoxyphenyl)bicyclo[3.3.1]nonan-9-one
Acta Crystallographica Section E, 2009 The title compound, C16H20O3, contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by intermolecular O—H...O hydrogen bonds.
Shuping Luo +4 more
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