Results 91 to 100 of about 78,167 (269)

Dicarba-closo-dodecarborane-containing half-sandwich complexes of ruthenium, osmium, rhodium and iridium : biological relevance and synthetic strategies [PDF]

, 2012
This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination
Barry, Nicolas P. E., Sadler, P. J.
core   +1 more source

Chemical Upcycling of Polyphenylene Sulfide at Room Temperature

Advanced Science, EarlyView.
Poly(phenylene sulfide) (PPS) is a semi‐crystalline super engineering plastic with exceptional properties. An iron‐photocatalyzed strategy is reported for chemical upcycling of PPS plastics at room temperature using 1,2‐dichloroethane. The method demonstrates remarkable efficiency across diverse PPS resins and post‐consumer composites, even within ...
Boning Gu, Chengliang Li, Xuefeng Jiang
wiley   +1 more source

Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes

Angewandte Chemie, EarlyView.
A versatile photoinduced hydro(boryl)silylation and hydro(chloro)silylation of alkenes to construct trisubstituted silylboranes and chlorosilanes was achieved through in situ generation of (boryl)silyl radicals or (chloro)silyl radicals. This mild methodology affords high chemoselectivity and broad functional group tolerance to enable direct access to ...
Mone Suzuki, Yuki Nagashima
wiley   +2 more sources

COLLOID-CHEMICAL PROPERTIES OF SILICONE SURFACTANTS USED IN THE SYNTHESIS OF POLYSTYRENE LATEXES

Тонкие химические технологии, 2016
The synthesis of polymeric suspensions with a narrow particle size distribution is an urgent problem in modern science. The resulting polymeric microspheres are applicable in various fields of chemistry, pharmaceuticals, biology and medicine.
I. A. Gritskova, A. A. Amelichev, O. A. Satskevich, A. V. Shkolnikov, A. A. Ezhova, G. A. Simakova, V. A. Vasnyov, N. A. Lobanova, B. A. Izmaylov   +8 more
doaj   +1 more source

Multimodal Cross‐Attentive Graph‐Based Framework for Predicting In Vivo Endocrine Disruptors

Advanced Science, EarlyView.
A multimodal cross‐attentive graph neural network integrates molecular graphs with androgen and estrogen adverse outcome pathway (AOP)–anchored in vitro assay signals to predict in vivo endocrine disruption. By fusing information on Tier‐1 AOP logits with chemical structures, the framework achieves high accuracy and provides assay‐traceable ...
Eder Soares de Almeida Santos, Gustavo Felizardo Santos Sandes, Artur Christian Garcia da Silva, Holli‐Joi Martin, Eugene N. Muratov, Rodolpho de Campos Braga, Bruno Junior Neves   +6 more
wiley   +1 more source

Natural Antioxidants: Advancing Stability and Performance in Sustainable Biobased and Biodegradable Plastics

Compounds
The depletion of fossil fuels and environmental concerns have driven the development of sustainable materials, including bio-based and biodegradable plastics, as alternatives to conventional plastics.
Norma Mallegni, Francesca Cicogna, Elisa Passaglia, Vito Gigante, Maria-Beatrice Coltelli, Serena Coiai   +5 more
doaj   +1 more source

Therapeutic Gases in Biomedicine: Updates on Nitric Oxide and Beyond

Advanced Science, EarlyView.
Therapeutic gases, including NO, CO, H2S, H2, CO2, O2, and Xe, play vital roles in cellular signaling and repair. This review highlights the emerging carriers and delivery systems that enable controlled, localized gas release for diagnostic and therapeutic applications.
Syed Muntazir Andrabi, Navatha Shree Sharma, Imran Ibn Gani Rather, S. M. Shatil Shahriar, Jingwei Xie   +4 more
wiley   +1 more source

2D Metal‐Organic Frameworks for High‐Performance Solid‐State Electrolytes: A Comprehensive Review

Advanced Science, EarlyView.
In this review, we elucidate the intrinsic advantages, synthetic methodologies, structural characteristics, ion‐transport mechanisms and performance optimization strategies while highlighting representative material systems and applications of 2D MOFs for electrolyte applications.
Changchun Ai, Yuan Tian, Yilei Shu, Peng Hang, Wentao Li, Yiling Yao, Huijuan Guo, Qun Yi, Hongmei Dai   +8 more
wiley   +1 more source

Half-Sandwich Ir(III) and Os(II) Complexes of Pyridyl-Mesoionic Carbenes as Potential Anticancer Agents [PDF]

, 2019
A series of cationic chlorido arene-iridium(III) and arene-osmium(II) complexes with bidentate pyridyl functionalized mesoionic carbenes (MIC) of the 1,2,3-triazol-5-ylidene type have been prepared.
Bolje, Aljoša, Brozović, Anamaria, Gržan, Tena, Hohloch, Stephan, Košmrlj, Janez, Kralj, Juran, Osmak, Maja, Sarkar, Biprajit, Steiner, Ivana, Stojanović, Nikolina, Stupin Polančec, Darija, Tupek, Ana, Urankar, Damijana   +12 more
core   +1 more source

Enantioselective Reductive Alkenylation of α‐CF2H (‐CF3) Amino Halides: Rapid Access to Chiral α‐CF2H (‐CF3) Allylamines

Advanced Science, EarlyView.
Difluoromethyl (CF2H) group, the bioisostere of hydroxyl thiol methyl or amide is privileged in medicinal chemistry due to hydrogen‐binding ability and lipophilic, metabolically stable, and chemical inert nature. However, enatioseleceive CF2H introduction remains challenging.
Peng Liu, Kuiliang Li, Yan He, Chen‐Hui Jiang, Ruo‐Xing Jin, Duo‐Duo Hu, Wei‐Cheng Zhao, Xuan Nie, Shang‐Zheng Sun, Xi‐Sheng Wang   +9 more
wiley   +1 more source