Results 111 to 120 of about 3,158,128 (352)

Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle

Angewandte Chemie, EarlyView.
This work demonstrates the nontrivial reactivity of pyridine incorporated into a porphyrin framework. The most significant achievement is the contraction of the six‐membered ring to a pyrrole ring, which is a phenomenon of great interest to researchers in this field.
Paulina Krzyszowska, Agata Burska‐Jabłońska, Mateusz Oberski, Michał J. Białek, Lechosław Latos‐Grażyński, Karolina Hurej   +5 more
wiley   +2 more sources

Bioorganometallic derivatives of 4-hydrazino-benzenesulphonamide as carbonic anhydrase inhibitors: synthesis, characterisation and biological evaluation

Journal of Enzyme Inhibition and Medicinal Chemistry, 2020
A series of bio-organometallic-hydrazones of the general formula [{(η5-C5H4)-C(R)=N–N(H)-C6H4-4-SO2NH2}]MLn(MLn = Re(CO)3, Mn(CO)3, FeCp; R=H, CH3) were prepared by reaction of formyl/acetyl organometallic precursors with 4-hydrazino-benzenesulphonamide.
Jeremie Brichet, Rodrigo Arancibia, Emanuela Berrino, Claudiu T. Supuran   +3 more
doaj   +1 more source

Organic Afterglow Vesicles

Advanced Science, EarlyView.
This work constructs organic afterglow vesicles through polymerization‐induced self‐assembly (PISA), integrating thermally activated delayed fluorescence (TADF) type organic afterglow emitters into block copolymer nanostructures. The resulting vesicles exhibited significant room‐temperature afterglow, with an emission lifetime exceeding 200 ...
Siqi Zhu, Biao Xu, Ting Luo, Hui Li, Xinyi Wu, Siqi Zheng, Haodong Li, Yong Gao, Kaka Zhang   +8 more
wiley   +1 more source

Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL

Angewandte Chemie, EarlyView.
Cyclic gallaphosphene 1 undergoes a twofold E─H bond activation with ammonia and water via a beneficial interplay between the polar “GaPGa” unit and the electrophilic nature of the C center in the bridging PCO unit, yielding six‐membered heterocycles 2 and 3, in which both nucleophilic phosphorus atoms are protonated.
Mahendra K. Sharma, Christoph Wölper, Gebhard Haberhauer, Stephan Schulz   +3 more
wiley   +2 more sources

On the existence of collective interactions reinforcing the metal-ligand bond in organometallic compounds. [PDF]

Nat Commun, 2023
Poater J, Vermeeren P, Hamlin TA, Bickelhaupt FM, Solà M.   +4 more
europepmc   +1 more source

Enantioselective Reductive Alkenylation of α‐CF2H (‐CF3) Amino Halides: Rapid Access to Chiral α‐CF2H (‐CF3) Allylamines

Advanced Science, EarlyView.
Difluoromethyl (CF2H) group, the bioisostere of hydroxyl thiol methyl or amide is privileged in medicinal chemistry due to hydrogen‐binding ability and lipophilic, metabolically stable, and chemical inert nature. However, enatioseleceive CF2H introduction remains challenging.
Peng Liu, Kuiliang Li, Yan He, Chen‐Hui Jiang, Ruo‐Xing Jin, Duo‐Duo Hu, Wei‐Cheng Zhao, Xuan Nie, Shang‐Zheng Sun, Xi‐Sheng Wang   +9 more
wiley   +1 more source

Synthesis, Structure, and Reactivity of a Magnesium(0) Complex with a Polarized Mgδ−─Caδ+ Bond

Angewandte Chemie, EarlyView.
Mixing metals: The elusive unsupported two‐center‐two‐electron Mg─Ca bond has been realized by using a combination of β‐diketiminate and amidinate ligands. Due to electronegativity differences (Mg: 1.31, Ca: 1.00) the formal oxidation states are Mg0─CaII.
Sandeep Kumar Thakur, Jens Langer, Nil Roig, A. Ganesh Patro, Marcel A. Schmidt, Mercedes Alonso, Sjoerd Harder   +6 more
wiley   +2 more sources

Reply to: On the existence of collective interactions reinforcing the metal-ligand bond in organometallic compounds. [PDF]

Nat Commun, 2023
Šadek V, Sowlati-Hashjin S, Sadjadi S, Karttunen M, Martín-Pendás A, Foroutan-Nejad C.   +5 more
europepmc   +1 more source

Advances in Thermoelectric Thin Films Grown by Atomic Layer Deposition: A Critical Review of Performance and Challenges

Advanced Energy Materials, EarlyView.
This review highlights the use of atomic layer deposition (ALD) for fabricating thermoelectric thin films with atomic‐scale control. Four material classes—chalcogenides, doped oxides, ternary oxides, and multilayered structures—are compared in terms of growth dynamics, structure–property relationships, and thermoelectric performance. The precise tuning
Jorge Luis Vazquez‐Arce, Dong‐Ho Shin, Shuyue Yao, Shiyang He, Kornelius Nielsch, Amin Bahrami   +5 more
wiley   +1 more source

Characterization of selected organometallic compounds by electrospray ionization- and matrix-assisted laser desorption/ionization-mass spectrometry using different types of instruments: Possibilities and limitations. [PDF]

Rapid Commun Mass Spectrom, 2022
Fleissner S, Pittenauer E, Pecak J, Kirchner K.   +3 more
europepmc   +1 more source