Esterase 2 as a Fluorescent Biosensor for the Detection of Organophosphorus Compounds: Docking and Electronic Insights from Molecular Dynamics [PDF]
, 2019 Organophosphorus compounds (OP) are mainly used in agriculture as pesticides. Unfortunately, each year many rural workers die intoxicated by those compounds. Sometimes the diagnosis of the exact molecule that caused the intoxication can be tardy. In this
Tanos C.C., França +2 more
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New Trends in Biosensors for Organophosphorus Pesticides
Sensors, 2001 Biosensors are sensitive and can be used as disposable sensors for environmental control. These biosensors are based either on inhibition of acyl cholinesterases acetylcholinesterase or butyrylcholinesterase) by organophosphorus compounds or on ...
Nicole Jaffrezic-Renault
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Novel fluorinated phosphorus–sulfur heteroatom compounds : synthesis and characterization of ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters [PDF]
, 2015 A series of novel ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters has been prepared. The reaction of 2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide {[FcP(μ-S)S]2, FcLR} with dry KF or tetrabutylammonium fluoride (TBAF)
Junyi Du +12 more
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Lipase-Catalyzed Phospha-Michael Addition Reactions under Mild Conditions
Molecules, 2022 Organophosphorus compounds are the core structure of many active natural products. The synthesis of these compounds is generally achieved by metal catalysis requiring specifically functionalized substrates or harsh conditions.
Yuelin Xu +7 more
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A sweet emergency due to bitter poisoning—A case report
Journal of Family Medicine and Primary Care, 2023 Organophosphorus compounds (OPC) are major components of pesticides and nerve gas agents. Self-harm by ingestion of OPC pesticides is one of the common problems encountered in the emergency room (ER), especially in developing countries such as India.
Jenny Joseph +3 more
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Chemical weapon in the 20th and 21st centuries. Part 3. Organophosphorus chemical warfare agents used until the year 1970. V-group [PDF]
Biuletyn Wojskowej Akademii Technicznej, 2020 The article contains the knowledge about the V-group of organophosphorus chemical warfare agents, named nerve agents, used since their discovery until the year 1970.
Marcin Kloske, Zygfryd Witkiewicz
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Microbial degradation of organophosphorus compounds [PDF]
FEMS Microbiology Reviews, 2006 Synthetic organophosphorus compounds are used as pesticides, plasticizers, air fuel ingredients and chemical warfare agents. Organophosphorus compounds are the most widely used insecticides, accounting for an estimated 34% of world-wide insecticide sales.
Brajesh K, Singh, Allan, Walker
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NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus
Angewandte Chemie, EarlyView.White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie +4 more
wiley +2 more sources
Toxic fasciculations–An unusual presentation of organophosphate poisoning
Clinical Case Reports, 2023 Key Clinical Message The nicotinic symptom in Organo‐Phosphate (OP) poisoning is an unusual presentation in an adult, as in our case of a 38‐year‐old man who also experienced decreased motor power of all limbs and diffuses fasciculation of the tongue and
Lokesh Koumar Sivanandam +3 more
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Homolytic substitution at phosphorus for C–P bond formation in organic synthesis
Beilstein Journal of Organic Chemistry, 2013 Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents
Hideki Yorimitsu
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