Results 21 to 30 of about 15,415 (237)

New Enzymatic Targets for Organophosphorus Compounds

open access: yesВестник войск РХБ защиты, 2023
It is known that several decarboxylases (aromatic amino acid decarboxylase (AAD), histidine decarboxylase (HD) and glutamate decarboxylase (GD) with different molecular weights catalyze the most important reactions of neurotransmitter and neuromodulator ...
E. N. Efremenko   +2 more
doaj   +1 more source

New Trends in Biosensors for Organophosphorus Pesticides

open access: yesSensors, 2001
Biosensors are sensitive and can be used as disposable sensors for environmental control. These biosensors are based either on inhibition of acyl cholinesterases acetylcholinesterase or butyrylcholinesterase) by organophosphorus compounds or on ...
Nicole Jaffrezic-Renault
doaj   +1 more source

Zero-field NMR J-Spectroscopy of Organophosphorus Compounds

open access: yes, 2020
In this paper, we report the results of theoretical and experimental studies on basic organophosphorus compounds using zero-field NMR, where spin dynamics are investigated in the absence of a magnetic field with the dominant heteronuclear J-coupling. We
Piotr, Put   +3 more
core   +1 more source

Lipase-Catalyzed Phospha-Michael Addition Reactions under Mild Conditions

open access: yesMolecules, 2022
Organophosphorus compounds are the core structure of many active natural products. The synthesis of these compounds is generally achieved by metal catalysis requiring specifically functionalized substrates or harsh conditions.
Yuelin Xu   +7 more
doaj   +1 more source

A sweet emergency due to bitter poisoning—A case report

open access: yesJournal of Family Medicine and Primary Care, 2023
Organophosphorus compounds (OPC) are major components of pesticides and nerve gas agents. Self-harm by ingestion of OPC pesticides is one of the common problems encountered in the emergency room (ER), especially in developing countries such as India.
Jenny Joseph   +3 more
doaj   +1 more source

Chemical weapon in the 20th and 21st centuries. Part 3. Organophosphorus chemical warfare agents used until the year 1970. V-group [PDF]

open access: yesBiuletyn Wojskowej Akademii Technicznej, 2020
The article contains the knowledge about the V-group of organophosphorus chemical warfare agents, named nerve agents, used since their discovery until the year 1970.
Marcin Kloske, Zygfryd Witkiewicz
doaj   +1 more source

Substrate‐Controlled Enantiodivergence in Ni‐Catalyzed Access to Phosphorylated Oxindoles With Quaternary Stereocenters

open access: yesAngewandte Chemie, EarlyView.
An efficient, enantiodivergent synthesis of phosphorylated oxindoles with quaternary stereocenters is achieved via a nickel‐catalyzed intermolecular Heck‐phosphorylation cascade. Employing a single chiral catalyst, either product enantiomer is selectively accessed simply by changing the alkene leaving group. DFT calculations trace this stereodivergence
Haimeng Zhu   +4 more
wiley   +2 more sources

Phosphoryl Radicals from Trivalent Iminyl Phosphines: A Photocatalytic Approach to N‐Phosphoryl Azetidines

open access: yesAngewandte Chemie, EarlyView.
Photochemically generated phosphoryl radicals from iminyl phosphines enable strain‐release addition to azabicyclobutanes, providing access to elusive N‐phosphoryl azetidines. Combined experimental, computational, and EPR studies reveal an unconventional water‐assisted photoredox pathway.
Chandu G. Krishnan   +4 more
wiley   +2 more sources

Microbial degradation of organophosphorus compounds [PDF]

open access: yesFEMS Microbiology Reviews, 2006
Synthetic organophosphorus compounds are used as pesticides, plasticizers, air fuel ingredients and chemical warfare agents. Organophosphorus compounds are the most widely used insecticides, accounting for an estimated 34% of world-wide insecticide sales.
Brajesh K, Singh, Allan, Walker
openaire   +2 more sources

Homolytic substitution at phosphorus for C–P bond formation in organic synthesis

open access: yesBeilstein Journal of Organic Chemistry, 2013
Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents
Hideki Yorimitsu
doaj   +1 more source

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