Results 31 to 40 of about 15,455 (233)

Informed Chemical Classification of Organophosphorus Compounds via Unsupervised Machine Learning of X-ray Absorption Spectroscopy and X-ray Emission Spectroscopy [PDF]

open access: yes, 2022
We analyze an ensemble of organophosphorus compounds to form an unbiased characterization of the information encoded in their X-ray absorption near edge structure (XANES) and valence-to-core X-ray emission spectra (VtC-XES).
Samantha, Tetef   +4 more
core   +1 more source

Microbial degradation of organophosphorus compounds [PDF]

open access: yesFEMS Microbiology Reviews, 2006
Synthetic organophosphorus compounds are used as pesticides, plasticizers, air fuel ingredients and chemical warfare agents. Organophosphorus compounds are the most widely used insecticides, accounting for an estimated 34% of world-wide insecticide sales.
Brajesh K, Singh, Allan, Walker
openaire   +2 more sources

Toxic fasciculations–An unusual presentation of organophosphate poisoning

open access: yesClinical Case Reports, 2023
Key Clinical Message The nicotinic symptom in Organo‐Phosphate (OP) poisoning is an unusual presentation in an adult, as in our case of a 38‐year‐old man who also experienced decreased motor power of all limbs and diffuses fasciculation of the tongue and
Lokesh Koumar Sivanandam   +3 more
doaj   +1 more source

Organophosphorus-Catalyzed Direct Dehydroxylative Thioetherification of Alcohols with Hypervalent Organosulfur Compounds [PDF]

open access: yes
A metal-free and thiol-free organophosphorus-catalyzed method for forming thioethers was disclosed, driven by PIII/PVO redox cycling. In this work, one-step dehydroxylative thioetherification of alcohols was fulfilled with various hypervalent ...
Shi-Ping Zhan (17733209)   +9 more
core   +1 more source

Homolytic substitution at phosphorus for C–P bond formation in organic synthesis

open access: yesBeilstein Journal of Organic Chemistry, 2013
Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents
Hideki Yorimitsu
doaj   +1 more source

Molecular Modeling Studies on the Multistep Reactivation Process of Organophosphate-Inhibited Acetylcholinesterase and Butyrylcholinesterase

open access: yesBiomolecules, 2021
Poisoning with organophosphorus compounds used as pesticides or misused as chemical weapons remains a serious threat to human health and life.
Jakub Jończyk   +6 more
doaj   +1 more source

Synthesis and reactivity of new organophosphorus compounds [PDF]

open access: yes, 2020
Synthesis of functionally substituted organophosphorus compounds on the basis of reactions of the tri-n-butylphosphine/carbon disulfide, tri-n-butylphosphine/phenyltsothiocyanate, tris(dimethylamino)phosphine/phenylisothiocyanate adducts with a wide ...
Gavrilov V.   +3 more
core  

A structural, spectroscopic and theoretical study of the triphenylphosphine chalcogenide complexes of tungsten carbonyl, [W(XPPh3)(CO)5], X=O, S, Se [PDF]

open access: yes, 2004
The series [W(XPPh3)(CO)5], X=O, S, Se has been structurally determined by X-ray crystallography and fully characterised spectroscopically to provide data for comparing the bonding of the Ph3PX ligands to the metal.
Nicholson, Brian K.   +2 more
core   +1 more source

ORIGINAL ARTICLE: Acute Poisoning with Organophosphorus Pesticide: Patients Admitted to A Hospital in Bijapur, Karnataka. [PDF]

open access: yesJournal of Krishna Institute of Medical Sciences University, 2012
Background: Organophosphorus compounds are the pesticides most often involved in human poisoning. Toxicity of these compounds is due to the inhibition of acetyl cholinesterase at cholinergic junctions of the nervous system.
Indira A. Hundekari   +3 more
doaj  

Bispyridinium Compounds Inhibit Both Muscle and Neuronal Nicotinic Acetylcholine Receptors in Human Cell Lines. [PDF]

open access: yesPLoS ONE, 2015
Standard treatment of poisoning by organophosphorus anticholinesterases uses atropine to reduce the muscarinic effects of acetylcholine accumulation and oximes to reactivate acetylcholinesterase (the effectiveness of which depends on the specific ...
Avi Ring   +8 more
doaj   +1 more source

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