Results 11 to 20 of about 5,305 (117)
Advanced Science, EarlyView.We present a mechanochemical, radical‐mediated hydroselenation of alkenes under ambient conditions. This method modularly generates alkyl selenyl radicals from elemental selenium and alkyl (pseudo)halides, utilizing PhSiH3 and H2O as hydrogen atom donors, with the water likely originating from the air and/or trace water present in the reagents ...
Xiaochun He +8 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.A straightforward one‐step protocol enables the synthesis of bio‐based and biologically active isochromans through the Oxa‐Pictet cyclization involving diverse aldehydes, including vanillin in combination with lignin‐derivable homovanillyl alcohol, a prominent aromatic platform chemical obtainable via diol‐assisted fractionation of lignocellulose ...
Anjali Kottayi +6 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.This review summarizes recent advances in copper‐ and silver‐catalyzed reactions of active methylene isocyanides for the synthesis of highly substituted five‐ and six‐membered heterocycles. Emphasis is placed on [3+n] cycloadditions, annulations, and asymmetric strategies, highlighting current limitations and future opportunities in heterocycle ...
Jimil George, Kyungsoo Oh
wiley +1 more source
ChemistryOpen, EarlyView.2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley +1 more source
The Chemical Record, EarlyView.The scalable synthesis of target molecules is crucial for applications such as biological evaluation in medicinal chemistry and even industrial production. We described recent advances in chiral Brønsted acid–catalyzed asymmetric allylboration, which enables access to previously elusive chiral building blocks, and highlight its application to the ...
Shigenobu Umemiya, Masahiro Terada
wiley +1 more source
Metal‐Free Electrophilic Borylative Cyclizations of Alkynes
The Chemical Record, EarlyView.Metal‐free borylative cyclizations based on electrophilic alkyne activation by boron Lewis acids provide efficient access to borylated hetero‐ and carbocycles. Early studies using B(C6F5)3 displayed limited scope and application, whereas recent ClBcat‐ and BCl3‐based methods enable mild CB and CC/CX bond formation for the synthesis of cycles ...
Jaime Mateos‐Gil +3 more
wiley +1 more source
Frame‐Shifted Synthesis of Oligoheterocycles as a Platform for Molecular Design
Angewandte Chemie, Volume 138, Issue 2, 9 January 2026.Modern chemistry seeks to turn the simple raw materials into complex molecules that matter in health, agriculture, and technology. Among these, oligoheterocycles stand out for their versatility, yet they are most often built by cross‐coupling reactions that often rely on expensive metal catalysts.
Kane A. C. Bastick +6 more
wiley +2 more sources
AlkaPlorer: A database‐driven explorer for natural alkaloids and derivatives
Journal of Integrative Plant Biology, EarlyView.The alkaloid database AlkaPlorer integrates over 130,000 compounds across 12,250 species. By linking chemical structures with biological and evolutionary data, it reveals how these molecules evolve and function. This platform serves as a vital resource for AI‐driven discovery in plant metabolism and modern drug development. ABSTRACT Alkaloids, renowned
Jiahao Li +5 more
wiley +1 more source
One‐Dimensional Covalent Organic Framework: Synthesis and Photoelectronic Applications
Advanced Energy and Sustainability Research, Volume 7, Issue 3, March 2026.The functional monomer structures, synthetic strategies, and the related applications of one‐dimensional covalent organic frameworks, as well as their current challenges and future development directions, have been summarized and prospected. One‐dimensional covalent organic frameworks (1D COFs) are linear porous materials constructed from organic units
Xuxin Fan +7 more
wiley +1 more source
Angewandte Chemie International Edition, Volume 65, Issue 7, 9 February 2026.Gold(I) chloride complexes are excellent precatalysts to activate unsaturated C─C bonds but typically require problematic silver salts for chloride scavenging. A supramolecular chloride receptor embedded in a phosphine ligand removes the need for inorganic chloride scavengers.
Riccardo Parolin +2 more
wiley +1 more source