Reconversion of Parahydrogen Gas in Surfactant-Coated Glass NMR Tubes
The application of parahydrogen gas to enhance the magnetic resonance signals of a diversity of chemical species has increased substantially in the last decade.
Robert V. Chimenti +4 more
doaj +1 more source
Geminal parahydrogen-induced polarization: accumulating long-lived singlet order on methylene proton pairs [PDF]
In the majority of hydrogenative parahydrogen-induced polarization (PHIP) experiments, the hydrogen molecule undergoes pairwise cis addition to an unsaturated precursor to occupy vicinal positions on the product molecule.
L. Dagys +6 more
doaj +1 more source
Local Superfluidity of Parahydrogen Clusters [PDF]
4 pages, 4 ...
Mezzacapo, Fabio, Boninsegni, Massimo
openaire +3 more sources
Pd-based bimetallic catalysts for parahydrogen-induced polarization in heterogeneous hydrogenations [PDF]
Production of hyperpolarized catalyst-free gases and liquids by heterogeneous hydrogenation with parahydrogen can be useful for various technical as well as biomedical applications, including in vivo studies, investigations of mechanisms of industrially ...
D. B. Burueva +4 more
doaj +1 more source
Microscopic Pair Potentials and the Physical Properties of the Condensed Phases of Parahydrogen
Equilibrium physical properties of the solid and liquid phases of parahydrogen, computed by first principle computer simulations, are compared for different choices of pair-wise, spherically symmetric intermolecular potentials.
Jieru Hu, Massimo Boninsegni
doaj +1 more source
Open-source, partially 3D-printed, high-pressure (50-bar) liquid-nitrogen-cooled parahydrogen generator [PDF]
The signal of magnetic resonance imaging (MRI) can be enhanced by several orders of magnitude using hyperpolarization. In comparison to a broadly used dynamic nuclear polarization (DNP) technique that is already used in clinical trials, the parahydrogen (
F. Ellermann +2 more
doaj +1 more source
Hyperpolarized fumarate via parahydrogen [PDF]
We produce hyperpolarized [1-13C]fumarate in the proton nuclear spin singlet state by pairwise trans-addition of parahydrogen to a molecular precursor using a ruthenium-based catalyst in water.
Barbara Ripka +5 more
openaire +6 more sources
Understanding Parahydrogen Hyperpolarized Urine Spectra: The Case of Adenosine Derivatives
Parahydrogen hyperpolarization has emerged as a promising tool for sensitivity-enhanced NMR metabolomics. It allows resolution and quantification of NMR signals of certain classes of low-abundance metabolites that would otherwise be undetectable ...
Kerti Ausmees +2 more
doaj +1 more source
Hyperpolarization techniques increase nuclear spin polarization by more than four orders of magnitude, enabling metabolic MRI. Even though hyperpolarization has shown clear value in clinical studies, the complexity, cost and slowness of current equipment
Luca Nagel +23 more
doaj +1 more source
New measurement of the scattering cross section of slow neutrons on liquid parahydrogen from neutron transmission [PDF]
Liquid hydrogen is a dense Bose fluid whose equilibrium properties are both calculable from first principles using various theoretical approaches and of interest for the understanding of a wide range of questions in many body physics.
Alarcon, R. +27 more
core +3 more sources

