Results 231 to 240 of about 21,106 (308)

Fundamental Understanding of Oxidative Stability in Fluorinated Asymmetric Ethers for Li Batteries

open access: yesAngewandte Chemie, EarlyView.
To improve Li‐metal battery electrolytes, we analyze fluorinated 1‐ethoxy‐2‐methoxyethane (FxEME) oxidative stability via density functional theory (DFT) and molecular dynamics (MD). Fluorination strengthens ethoxy C–H bonds and alters solvent orientation at the cathode, weakening interfacial interactions.
Liang‐Ting Wu   +3 more
wiley   +1 more source

Molecular and Phenotypic Characterization of Fluid-Derived Patient-Derived Cell and Organoid Models in Advanced Gastric Cancer. [PDF]

open access: yesJ Gastric Cancer
Moon YJ   +12 more
europepmc   +1 more source

Upcycling Water Pollutants Into Long‐Chain Polymers via Synergistic Interfacial Dechlorination and Organic Radical Stabilization

open access: yesAngewandte Chemie, EarlyView.
HEO‐regulated electronic structure drives nonradical PI activation, promoting ETP‐mediated polymerization of 4CP into high‐molecular‐weight products with enhanced surface enrichment. Concurrent dechlorination occurs via radical coupling and •OHads attack, enabling efficient carbon retention and selective product evolution at the liquid–solid interface.
Ziwei Yao   +8 more
wiley   +1 more source

Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia

open access: yesAngewandte Chemie, EarlyView.
A wrinkled 2D PdFeCoNiCuIn high‐entropy metallene overcomes the low atom utilization of high‐entropy alloys. Indium‐induced strain and p‐d hybridization enable a cross‐site tandem pathway for nitrate reduction to ammonia. It achieves 99.3% Faradaic efficiency and an NH3 yield rate of 4.55 mmol h−1 mgcat−1.
Tianfang Yang   +6 more
wiley   +1 more source

Ketazine‐Linked Covalent Organic Framework for Metal‐Free Electrocatalytic Nitrate‐to‐Ammonia Conversion

open access: yesAngewandte Chemie, EarlyView.
A metal‐free fluorinated ketazine‐linked COF is introduced as an efficient electrocatalyst for nitrate reduction to ammonia under neutral conditions. Fluorine substitution enhances π–π stacking and crystallinity, enabling a Faradaic efficiency of 59.9% and an NH3 yield rate of 1639.9 µmol h−1 mgCOF−1 at −0.9 V versus RHE. This establishes an unexplored
Islam E. Khalil   +12 more
wiley   +1 more source

Ordered Pt3Mn Intermetallic Nanoparticles Supported on Atomically Dispersed Mn–N–C as Electrocatalysts for Fuel Cells

open access: yesAngewandte Chemie, EarlyView.
Ordered L12‐Pt3Mn intermetallic alloys are uniformly deposited onto atomically dispersed Mn–N–C supports. The synergistic effect between MnN4 sites and Pt3Mn elevates interfacial binding strength and dissolution barriers while favorably weakening *OH adsorption. It delivers exceptional catalytic activity and stability in fuel cells, serving as an ideal
Gongjin Chen   +8 more
wiley   +1 more source

Ancestrally Diverse Autologous Patient-Derived Organoid-Immune Cell Coculture Platform for Addressing Immunotherapeutic Outcome Disparities in High-Grade Endometrial Cancer. [PDF]

open access: yesCancer Res Commun
Chung C   +14 more
europepmc   +1 more source

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