Structure of a Permethylcyclopentadienyl-μ-tetramethylcyclopentadienylmethylene Scandium Dimer [PDF]
, 1992 Bis(η^5-pentamethylcyclopentadienyl)-bis[μ-2,3,4,5-tetramethyl-1-methylene-ScC^1:Sc'(η^5)-cyclopentadienyl]-discandium(III), [Sc_2(C_(10)H_(15))_2-(C_(10)H_(14)_2], M_r = 628.90, triclinic, Pl, ɑ = 8.641 (5), b= 9.478 (2), c = 12.338 (5) Å, ɑ = 75.58 (3),
Bercaw, John E. +2 more
core +1 more source
Bis(η5-pentamethylcyclopentadienyl)cobalt(II)
Acta Crystallographica Section E, 2009 The crystal structure of the title compound, decamethylcobaltocene, [Co(C10H15)2], has been determined. High-quality single crystals were grown from a cold saturated hexamethyldisiloxane solution.
Meghan M. Clark +2 more
doaj +1 more source
Structures of chlorohydroxobis(pentamethylcyclopentadienyl)tantalum(V) trifluoromethanesulfonate (triflate) and dihydroxobis(pentamethylcyclopentadienyl)tantalum(V) triflate [PDF]
, 1991 [Ta(C_(10)H_(15))2(C1)(OH)][CF_3SO_3] (I), Mr = 652.94, monoclinic, P2_1/n, a = 9.965(7), b = 18.796 (5), c = 13.269 (3)Å, β = 94.02 (3)°, V = 2479-2 (19)Å^3, Z = 4, D_x = 1.75 g cm^(-3), λ(Mo Kce) = 0.71073 Å, µ = 46 cm^(-1), F(000) = 1288, room ...
Bercaw, John E. +2 more
core +1 more source
Acta Crystallographica Section E, 2010 In the title compound, [Fe(C10H15)Cl(C26H24P2)]·CH2Cl2, the FeII atom is coordinated by two P atoms from a 1,2-bis(diphenylphosphino)ethane ligand [Fe—P = 2.2130 (7) and 2.2231 (7) Å], a chloride ...
Ya-ping Ou, Dan Feng, Jing-jing Yuan
doaj +1 more source
Mononuclear piano-stool iron 2-ethynylbenzo[b]thiophene complex: crystal structure and reversible oxidation studied by spectro-electrochemical and DFT methods [PDF]
, 2017 A mononuclear iron complex with 2-ethynylbenzo[b]thiophene C-coordinated to the (η5 -Cp*)(η2 -dppe)Fe ( Cp* = pentamethylcyclopentadienyl, dppe = 1,2-diphenylphosphinoethane) framework (1) was successfully prepared and characterized by 1H NMR ...
Hartl, František +7 more
core +1 more source
Acta Crystallographica Section E, 2013 The title compound, [Fe4(C10H15)2(C8H10O4S2)2S4], contains a twisted Fe4S4 cubane-like core. A twofold rotation axis passes through the Fe4S4 core, completing the coordination of the four Fe atoms with two pentamethylcyclopentadienyl ligands and two ...
Shohei Ito +3 more
doaj +1 more source
Heterogenized Iridium Water-Oxidation Catalyst from a Silatrane Precursor [PDF]
, 2016 A pentamethylcyclopentadienyl (Cp*) iridium water-oxidation precatalyst was modified to include a silatrane functional group for covalent attachment to metal oxide semiconductor surfaces.
Batista, Victor S. +9 more
core +2 more sources
(2,2-Bipyridyl)bis(η5-pentamethylcyclopentadienyl)strontium(II)
Acta Crystallographica Section E, 2008 In the title compound, [Sr(C10H15)2(C10H8N2)], the Sr—N distances are 2.624 (3) and 2.676 (3) Å, the Sr...Cp ring centroid distances are 2.571 and 2.561 Å and the N—C—C—N torsion angle in the ...
Sergio Rozenel +4 more
doaj +1 more source
Covalent Organic Frameworks for Photocatalysis
Advanced Materials, Volume 37, Issue 52, December 29, 2025.This review provides an overview of recent advances in covalent organic frameworks (COFs) for photocatalysis, focusing on sustainable energy applications like water splitting, hydrogen peroxide generation, and CO2 and N2 reduction. It discusses design principles, structure‐function relationships, challenges in COF photocatalysis, and strategies to ...
Bikash Mishra +6 more
wiley +1 more source
Speciation of metal complexes of medicinal interest: relationship between solution equilibria and pharmaceutical properties [PDF]
, 2018 Biospeciation of essential and toxic metal ions, metal complexes with biological or medicinal activity are discussed in the paper in order to emphasize the importance of the distribution of metal ions in biological milieu.
Dömötör, Orsolya +3 more
core +2 more sources